Pressure Shifts in High-Precision Hydrogen Spectroscopy: I. Long-Range Atom-Atom and Atom-Molecule Interactions

We study the theoretical foundations for the pressure shifts in high-precision atomic beam spectrosopy of hydrogen, with a particular emphasis on transitions involving higher excited P states. In particular, the long-range interaction of an excited hydrogen atom in a 4P state with a ground-state and metastable hydrogen atom is studied, with a full resolution of the hyperfine structure. It is found that the full inclusion of the 4P_1/2 and 4P_3/2 manifolds becomes necessary in order to obtain reliable theoretical predictions, because the 1S ground state hyperfine frequency is commensurate with the 4P fine-structure splitting. An even more complex problem is encountered in the case of the 4P-2S interaction, where the inclusion of quasi-degenerate 4S-2P_1/2 state becomes necessary in view of the dipole couplings induced by the van der Waals Hamiltonian. Matrices of dimension up to 40 have to be treated despite all efforts to reduce the problem to irreducible submanifolds within the quasi-degenerate basis. We focus on the phenomenologically important second-order van der Waals shifts, proportional to 1/R^6 where R is the interatomic distance, and obtain results with full resolution of the hyperfine structure. The magnitude of van der Waals coefficients for hydrogen atom-atom collisions involving excited P states is drastically enhanced due to energetic quasi-degeneracy; we find no such enhancement for atom-molecule collisions involving atomic nP states, even if the complex molecular spectrum involving ro-vibrational levels requires a deeper analysis.Comment: 32 pages; 2 figures; this is part 1 of a series of two papers; part 1 carries article number 075005, while part 2 carries article number 075006 in the journal (online journal version has been rectified). arXiv admin note: text overlap with arXiv:1711.1003

Associations between Fitness Measures and Change of Direction Speeds with and without Occupational Loads in Female Police Officers

Female police officers may be required to pursue offenders on foot while wearing occupational loads. The aim of this study was to determine relationships between fitness measures and change of direction speed (CODS) in female police officers and the influence of their occupational loads. Retrospective data were provided for 27 female police officers (age = 32.19 ± 5.09 y, height = 162.78 ± 5.01 cm, and mass = 71.31 ± 13.42 kg) and included fitness measures of: lower-body power (standing long jump (SLJ)), upper-body and trunk muscle endurance (push-up (PU) and sit-up (SU)), aerobic power (estimated VO2max), and CODS (Illinois agility test). The CODS test was performed without and with occupational load (10 kg). Paired sample t-tests (between-load conditions) and Pearson's correlations (relationships between measures) were performed with linear regression analysis used to account for the contribution of measures to unloaded and loaded CODS performance. CODS was significantly slower when loaded (unloaded = ~23.17 s, loaded = ~24.14 s, p < 0.001) with a strong, significant relationship between load conditions (r = 0.956, p < 0.001). Moderate to strong, significant relationships were found between all fitness measures ranging from estimated VO2max (r = -0.448) to SU (r = -0.673) in the unloaded condition, with the strength of these relationships increasing in the loaded condition accounting for 61% to 67% of the variance, respectively. While unloaded agility test performance was strongly associated with loaded performance, female police officer CODS was significantly reduced when carrying occupational loads. A variety of fitness measures that influence officer CODS performances become increasingly important when occupational loads are carried

Curved Gratings as Plasmonic Lenses for Linearly Polarised Light

The ability of curved gratings as sectors of concentric circular gratings to couple linearly polarized light into focused surface plasmons is investigated by theory, simulation and experiment. Curved gratings, as sectors of concentric circular gratings with four different sector angles, are etched into a 30-nm thick gold layer on a glass coverslip and used to couple linearly-polarised free space light at nm into surface plasmons. The experimental and simulation results show that increasing the sector angle of the curved gratings decreases the lateral spotsize of the excited surface plasmons, resulting in focussing of surface plasmons which is analogous to the behaviour of classical optical lenses. We also show that two faced curved gratings, with their groove radius mismatched by half of the plasmon wavelength (asymmetric configuration), can couple linearly-polarised light into a single focal spot of concentrated surface plasmons with smaller depth of focus and higher intensity in comparison to single-sided curved gratings. The major advantage of these structures is the coupling of linearly-polarised light into focused surface plasmons with access to and control of the plasmon focal spot, which facilitates potential applications in sensing, detection and nonlinear plasmonics.Comment: 15 pages and 12 figure

Time Spent Working in Custody Influences Work Sample Test Battery Performance of Deputy Sheriffs Compared to Recruits

This study determined the influence of years spent working in custody on fitness measured by a state-specific testing battery (Work Sample Test Battery; WSTB) in deputy sheriffs. Retrospective analysis was conducted on one patrol school class (51 males, 13 females) divided into three groups depending on time spent working in custody: DS24 (&lt;24 months; n = 20); DS2547 (25&#8211;47 months; n = 23); and DS48+ (&#8805;48 months; n = 21). These groups were compared to a recruit class (REC; 219 males, 34 females) in the WSTB, which comprised five tasks completed for time: 99-yard (90.53-m) obstacle course (99OC); 165-pound (75-kg) dummy drag; six-foot (1.83-m) chain link fence (CLF) and solid wall (SW) climb; and 500-yard (457.2-m) run (500R). A univariate analysis of covariance (ANCOVA) (controlling for sex and age) with Bonferroni post hoc determined significant between-group differences. DS48+ were slower in the 99OC compared to the REC (p = 0.007) and performed the CLF and SW slower than all groups (p &#8804; 0.012). DS24, DS2547, and DS48+ were all slower than REC in the 500R (p &#8804; 0.002). Physical training should be implemented to maintain fitness and job-specific task performance in deputy sheriffs working custody, especially considering the sedentary nature of this work