348 research outputs found
A new interpretation of dielectric data in molecular glass formers
Literature dielectric data of glycerol, propylene carbonate and
ortho-terphenyl (OTP) show that the measured dielectric relaxation is a decade
faster than the Debye expectation, but still a decade slower than the breakdown
of the shear modulus. From a comparison of time scales, the dielectric
relaxation seems to be due to a process which relaxes not only the molecular
orientation, but the entropy, the short-range order and the density as well. On
the basis of this finding, we propose an alternative to the
Gemant-DiMarzio-Bishop extension of the Debye picture.Comment: 7 pages, 4 figures, 68 references; 3. version extended following
referee advic
A new view of the Lindemann criterion
The Lindemann criterion is reformulated in terms of the average shear modulus
of the melting crystal, indicating a critical melting shear strain which
is necessary to form the many different inherent states of the liquid. In glass
formers with covalent bonds, one has to distinguish between soft and hard
degrees of freedom to reach agreement. The temperature dependence of the
picosecond mean square displacements of liquid and crystal shows that there are
two separate contributions to the divergence of the viscosity with decreasing
temperature: the anharmonic increase of the shear modulus and a diverging
correlation length .Comment: 4 pages, 3 figure
Interaction of quasilocal harmonic modes and boson peak in glasses
The direct proportionality relation between the boson peak maximum in
glasses, , and the Ioffe-Regel crossover frequency for phonons,
, is established. For several investigated materials . At the frequency the mean free path of the
phonons becomes equal to their wavelength because of strong resonant
scattering on quasilocal harmonic oscillators. Above this frequency phonons
cease to exist. We prove that the established correlation between
and holds in the general case and is a direct consequence of
bilinear coupling of quasilocal oscillators with the strain field.Comment: RevTex, 4 pages, 1 figur
High frequency sound waves in vitreous silica
We report a molecular dynamics simulation study of the sound waves in
vitreous silica in the mesoscopic exchanged momentum range. The calculated
dynamical structure factors are in quantitative agreement with recent
experimental inelastic neutron and x-ray scattering data. The analysis of the
longitudinal and transverse current spectra allows to discriminate between
opposite interpretations of the existing experimental data in favour of the
propagating nature of the high frequency sound waves.Comment: 4 pages, Revtex, 4 ps figures; to be published in Phys. Rev. Lett.,
February 198
Scaling the Temperature-dependent Boson Peak of Vitreous Silica with the high-frequency Bulk Modulus derived from Brillouin Scattering Data
The position and strength of the boson peak in silica glass vary considerably
with temperature . Such variations cannot be explained solely with changes
in the Debye energy. New Brillouin scattering measurements are presented which
allow determining the -dependence of unrelaxed acoustic velocities. Using a
velocity based on the bulk modulus, scaling exponents are found which agree
with the soft-potential model. The unrelaxed bulk modulus thus appears to be a
good measure for the structural evolution of silica with and to set the
energy scale for the soft potentials.Comment: Accepted for publication in Physical Review Letter
Phonons from neutron powder diffraction
The spherically averaged structure function \soq obtained from pulsed
neutron powder diffraction contains both elastic and inelastic scattering via
an integral over energy. The Fourier transformation of \soq to real space, as
is done in the pair density function (PDF) analysis, regularizes the data, i.e.
it accentuates the diffuse scattering. We present a technique which enables the
extraction of off-center phonon information from powder diffraction experiments
by comparing the experimental PDF with theoretical calculations based on
standard interatomic potentials and the crystal symmetry. This procedure
(dynamics from powder diffraction(DPD)) has been successfully implemented for
two systems, a simple metal, fcc Ni, and an ionic crystal, CaF. Although
computationally intensive, this data analysis allows for a phonon based
modeling of the PDF, and additionally provides off-center phonon information
from powder neutron diffraction
Dielectric and thermal relaxation in the energy landscape
We derive an energy landscape interpretation of dielectric relaxation times
in undercooled liquids, comparing it to the traditional Debye and
Gemant-DiMarzio-Bishop pictures. The interaction between different local
structural rearrangements in the energy landscape explains qualitatively the
recently observed splitting of the flow process into an initial and a final
stage. The initial mechanical relaxation stage is attributed to hopping
processes, the final thermal or structural relaxation stage to the decay of the
local double-well potentials. The energy landscape concept provides an
explanation for the equality of thermal and dielectric relaxation times. The
equality itself is once more demonstrated on the basis of literature data for
salol.Comment: 7 pages, 3 figures, 41 references, Workshop Disordered Systems,
Molveno 2006, submitted to Philosophical Magazin
Observation of Umklapp processes in non-crystalline materials
Umklapp processes are known to exist in cristalline materials, where they
control important properties such as thermal conductivity, heat capacity and
electrical conductivity. In this work we report the provocative observation of
Umklapp processes in a non-periodical system, namely liquid Lithium. The lack
of a well defined periodicity seems then not to prevent the existence of these
scattering processes mechanisms provided that the local order of the systems
i.e. the maxima of the static structure factor supply the equivalent of a
reciprocal lattice vector in the case of cristalline materials.Comment: 13 pages P
Fragility and compressibility at the glass transition
Isothermal compressibilities and Brillouin sound velocities from the
literature allow to separate the compressibility at the glass transition into a
high-frequency vibrational and a low-frequency relaxational part. Their ratio
shows the linear fragility relation discovered by x-ray Brillouin scattering
[1], though the data bend away from the line at higher fragilities. Using the
concept of constrained degrees of freedom, one can show that the vibrational
part follows the fragility-independent Lindemann criterion; the fragility
dependence seems to stem from the relaxational part. The physical meaning of
this finding is discussed. [1] T. Scopigno, G. Ruocco, F. Sette and G. Monaco,
Science 302, 849 (2003)Comment: 4 pages, 2 figures, 2 tables, 33 references. Slightly changed after
refereein
- …