443 research outputs found

    On Parametrization of the Linear GL(4,C) and Unitary SU(4) Groups in Terms of Dirac Matrices

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    Parametrization of 4×44\times 4-matrices GG of the complex linear group GL(4,C)GL(4,C) in terms of four complex 4-vector parameters (k,m,n,l)(k,m,n,l) is investigated. Additional restrictions separating some subgroups of GL(4,C)GL(4,C) are given explicitly. In the given parametrization, the problem of inverting any 4×44\times 4 matrix GG is solved. Expression for determinant of any matrix GG is found: detG=F(k,m,n,l)\det G = F(k,m,n,l). Unitarity conditions G+=G1G^{+} = G^{-1} have been formulated in the form of non-linear cubic algebraic equations including complex conjugation. Several simplest solutions of these unitarity equations have been found: three 2-parametric subgroups G1G_{1}, G2G_{2}, G3G_{3} - each of subgroups consists of two commuting Abelian unitary groups; 4-parametric unitary subgroup consisting of a product of a 3-parametric group isomorphic SU(2) and 1-parametric Abelian group. The Dirac basis of generators Λk\Lambda_{k}, being of Gell-Mann type, substantially differs from the basis λi\lambda_{i} used in the literature on SU(4) group, formulas relating them are found - they permit to separate SU(3) subgroup in SU(4). Special way to list 15 Dirac generators of GL(4,C)GL(4,C) can be used {Λk}={αiβj(αiVβj=KLM)}\{\Lambda_k\} = \{\alpha_i\oplus\beta_j\oplus(\alpha_iV\beta_j = {\boldsymbol K} \oplus {\boldsymbol L}\oplus{\boldsymbol M})\}, which permit to factorize SU(4) transformations according to S = e^{i\vec{a}\vec{\alpha}} e^{i\vec{b}\vec\beta}} e^{i{\boldsymbol k}{\boldsymbol K}} e^{i{\boldsymbol l}{\boldsymbol L}} e^{i\boldsymbol m}{\boldsymbol M}}, where two first factors commute with each other and are isomorphic to SU(2) group, the three last ones are 3-parametric groups, each of them consisting of three Abelian commuting unitary subgroups.Comment: This is a contribution to the Proc. of the Seventh International Conference ''Symmetry in Nonlinear Mathematical Physics'' (June 24-30, 2007, Kyiv, Ukraine), published in SIGMA (Symmetry, Integrability and Geometry: Methods and Applications) at http://www.emis.de/journals/SIGMA

    Effect of organic matter release from natural cork used on bisphenol a removal from aqueous solution

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    The paper presents an experimental study aimed at investigating the mechanism responsible for Bisphenol A adsorption on natural cork, and the role played on process kinetics by the organic matter released from the cork. Obtained data show that natural cork has a good affinity toward Bisphenol A, with removal efficiency being as high as 75% in less than 24 h. The adsorption process is characterized by a fast-initial rate which tends to reduce progressively, and follows a pseudo second order model equation. Statistical physics analysis allows for obtaining a molecular description of the adsorption, which is shown to take place through a single anchorage point, perpendicularly to the adsorbent surface. Nuclear magnetic resonance spectroscopy and fluorescence analysis reveal that the colloidal organic matter released from the cork interacts with Bisphenol A; it also plays a relevant role in the slowing down of the adsorption rate, as it competes with cork adsorption sites for Bisphenol A. Organic matter is found to be highly heterogenous, presenting at the same time carbohydrates, aromatic and aliphatic domains. Such moieties interact stably with the contaminant in the solution probably due the establishment of dispersive forces (e.g. π-stacking) which sequestrate Bisphenol A into the inner hydrophobic core of the organic matter three-dimensional structure
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