Characterising the fruiting dynamics of commercial cotton varieties

This paper reports the results of an experiment to quantify the fruiting characteristics of eight cotton varieties to enable crop simulation models to more accurately reflect yield and maturity of current varieties. Characteristics measured were time to first square, square period, and boll period, and their subsequent effects on crop maturity. Thennaltime to first square and bll period were correlated to the maturity ranking of the varieties. However, differences in the length of these periods compared with other reports indicates the need to pursue better methods to quantify these characteristic

Direct Detection of Singlet-Triplet Interconversion in OLED Magnetoelectroluminescence with a Metal-Free Fluorescence-Phosphorescence Dual Emitter

We demonstrate that a simple phenazine derivative can serve as a dual emitter for organic light-emitting diodes, showing simultaneous luminescence from the singlet and triplet excited states at room temperature without the need of heavy-atom substituents. Although devices made with this emitter achieve only low quantum efficiencies of < 0.2%, changes in fluorescence and phosphorescence intensity on the subpercent scale caused by an external magnetic field of up to 30 mT are clearly resolved with an ultra-low-noise optical imaging technique. The results demonstrate the concept of using simple reporter molecules, available commercially, to optically detect the spin of excited states formed in an organic light-emitting diode and thereby probe the underlying spin statistics of recombining electron-hole pairs. A clear anticorrelation of the magnetic-field dependence of singlet and triplet emission shows that it is the spin interconversion between singlet and triplet which dominates the magnetoluminescence response: the phosphorescence intensity decreases by the same amount as the fluorescence intensity increases. The concurrent detection of singlet and triplet emission as well as device resistance at cryogenic and room temperature constitute a useful tool to disentangle the effects of spin-dependent recombination from spin-dependent transport mechanisms

The Aegean Sea as a source of atmospheric nitrous oxide and methane

During the EGAMES (Evasion of GAses from the MEditerranean Sea) expedition in July 1993 we determined the concentrations of nitrous oxide and methane in the atmosphere and in the surface waters of the Aegean Sea, the northwestern Levantine Basin, the eastern Ionian Sea and the Amvrakikos Bay. Both gases were found to be supersaturated in all sampled areas. Nitrous oxide was homogeneously distributed with a mean saturation of 105 ± 2%, showing no differences between shelf and open ocean areas, whereas methane saturation values ranged from about 1.2 times (northwestern Levantine Basin) to more than 5 times solubility equilibrium (Amvrakikos Bay estuary). Therefore the Aegean Sea and the adjacent areas were sources of atmospheric nitrous oxide and methane during the study period

Preliminary observation on response of waterlogged cotton to different doses of AVG application

The obvious symptoms of waterlogging response in cotton are leaf chlorosis (yellowing) and dropping squares & bolls. In addition, Huck (1970) showed that tap root growth stopped within 30 min of reducing the oxygen in the soils, and that the growing point of the root was completely dead within 3 hrs. In other plant species, these responses have been associated with the effect of ethylene, produced in response to lack of oxygen (Pratt, 1953; Jackson, 1984; 1985; Jackson & Drew, 1984; Raskin & Konde, 1984; Stead, 1985; Voesenek & Blom, 1989; Osborne, 1991;Reid & Wu, 1991; Brady & Speirs, 1991; Voesenek et al, 1992; Drew, 1997). Ethylene is known to accelerate premature senescence, defoliation and boll dehiscence in cotton (Hall et al, 1957; Kirzek, 1986), but the involvement of ethylene in cotton's response to waterlogging has not been demonstrated. AVG (aminoethoxyvinylglycine)is an inhibitor of ethylene production. It can be used to indicate the involvement of ethylene production in physiological processes. Improvements in commercial production of AVG provide an exciting opportunity to explore the importance of ethylene production in plant responses to waterlogging in the field. To achieve meaningful results, dose-response tests are necessary to establish the concentration of AVG that is high enough to inhibit ethylene formation while low enough to minimise nonspecific and possibly toxic effects to the plants from AVG itself(Jackson, 1991)

Spontaneous fluctuations of transition dipole moment orientation in OLED triplet emitters

The efficiency of an organic light-emitting diode (OLED) depends on the microscopic orientation of transition dipole moments of the molecular emitters. The most effective materials used for light generation have threefold symmetry, which prohibit a priori determination of dipole orientation due to the degeneracy of the fundamental transition. Single-molecule spectroscopy reveals that the model triplet emitter tris(2-phenylisoquinoline)iridium(III) (Ir(piq)3) does not behave as a linear dipole, radiating with lower polarization anisotropy than expected. Spontaneous symmetry breaking occurs in the excited state, leading to a random selection of one of the three ligands to form a charge transfer state with the metal. This non-deterministic localization is revealed in switching of the degree of linear polarization of phosphorescence. Polarization scrambling likely raises out-coupling efficiency and should be taken into account when deriving molecular orientation of the guest emitter within the OLED host from ensemble angular emission profiles

Interplay between J- and H-type coupling in aggregates of π-conjugated polymers: a single-molecule perspective

Strong dipole–dipole coupling within and between π‐conjugated segments shifts electronic transitions, and modifies vibronic coupling and excited‐state lifetimes. Since J‐type coupling between monomers along the conjugated‐polymer (CP) chain and H‐type coupling of chromophores between chains of a CP compete, a superposition of the spectral modifications arising from each type of coupling emerges, making the two couplings hard to discern in the ensemble. We introduce a single‐molecule H‐type aggregate of fixed spacing and variable length of up to 10 nm. HJ‐type aggregate formation is visualized intuitively in the scatter of single‐molecule spectra

Effective deep brain stimulation co-modulate cross-frequency coupling [Abstract]

Objective: The disruption of pathological signals in the cortico-basal ganglia- network has been hypothesized as a mechanism of action of deep brain stimulation (DBS). However, a comprehensive model for DBS modulating oscillations is still missing. Background: Besides considering gamma as physiologic and pro-kinetic, it has been suggested that finely tuned gamma oscillations between 60-90Hz reflect dynamic processing, possibly by inducing local inhibition or facilitation. Most studies investigating gamma focused on oscillations within the STN, motor cortex (M1), supplementary motor area (SMA), and the pallidum (Allert et al., 2018). Furthermore, elements of the BG-thalamocortical network like the premotor (PMC) or prefrontal cortices (PFC) and the sub-cortical network of cerebellum (CB) have been neglected to date. Method: We recorded resting state high-density 256-channels EEG of 31 PD-patients during DBS at the clinically most effective frequency (i.e 130Hz or 160Hz). We compared spectral power and cross-frequency coupling (frequency to power) of cortical and subcortical regions using a beamformer algorithm for coherent sources (Muthuraman et al., 2018). Two clinically ineffective frequencies have been tested as control conditions. Results: We demonstrated that clinically effective STN-DBS alters oscillatory activity in a wide-spread network of cortical and subcortical regions. A reduction of beta and increase of gamma power is attested in the cortical (M1, SMA, PMC, PFC) and sub-cortical network nodes (STN, CB). Additionally, we found increased cross-frequency coupling of narrowband gamma frequencies to the stimulation frequency in the same nodes of the cortico-subcortical network. No such dynamics were revealed within control regions (i.e. posterior parietal cortex). Furthermore, stimulating at lower or higher frequencies did not significantly alter the networks’ source power spectra or cross-frequency coupling. Conclusion: We were able to show a modulation of beta- and gamma-power and cross-frequency coupling during DBS with HD-EEG in a cortical-sub cortical network. DBS does not exclusively influence motor-function but also the physiological processing related to facilitation and dynamic adaptation, in line with the proposed function of gamma oscillations

Interannual variation in summer N2O concentration in the hypoxic region of the northern Gulf of Mexico, 1985–2007

Microbial nitrous oxide (N2O) production in the ocean is enhanced under low-oxygen (O2) conditions. This is especially important in the context of increasing hypoxia (i.e., oceanic zones with extremely reduced O2 concentrations). Here, we present a study on the interannual variation in summertime nitrous oxide (N2O) concentrations in the bottom waters of the northern Gulf of Mexico (nGOM), which is well-known as the site of the second largest seasonally occurring hypoxic zone worldwide. To this end we developed a simple model that computes bottom-water N2O concentrations with a tri-linear 1N2O/O2 relationship based on water-column O2 concentrations, derived from summer (July) Texas–Louisiana shelf-wide hydrographic data between 1985 and 2007. 1N2O (i.e., excess N2O) was computed including nitrification and denitrification as the major microbial production and consumption pathways of N2O. The mean modeled bottom-water N2O concentration for July in the nGOM was 14.5±2.3 nmol L−1 (min: 11.0±4.5 nmol L−1 in 2000 and max: 20.6±11.3 nmol L−1 in 2002). The mean bottom-water N2O concentrations were significantly correlated with the areal extent of hypoxia in the nGOM. Our modeling analysis indicates that the nGOM is a persistent summer source of N2O, and nitrification is dominating N2O production in this region. Based on the ongoing increase in the areal extent of hypoxia in the nGOM, we conclude that N2O production (and its subsequent emissions)from this environmentally stressed region will probably continue to increase into the future

Nitrous oxide emissions from the Arabian Sea: A synthesis

We computed high-resolution (1º latitude x 1º longitude) seasonal and annual nitrous oxide (N2O) concentration fields for the Arabian Sea surface layer using a database containing more than 2400 values measured between December 1977 and July 1997. N2O concentrations are highest during the southwest (SW) monsoon along the southern Indian continental shelf. Annual emissions range from 0.33 to 0.70 Tg N2O and are dominated by fluxes from coastal regions during the SW and northeast monsoons. Our revised estimate for the annual N2O flux from the Arabian Sea is much more tightly constrained than the previous consensus derived using averaged in-situ data from a smaller number of studies. However, the tendency to focus on measurements in locally restricted features in combination with insufficient seasonal data coverage leads to considerable uncertainties of the concentration fields and thus in the flux estimates, especially in the coastal zones of the northern and eastern Arabian Sea. The overall mean relative error of the annual N2O emissions from the Arabian Sea was estimated to be at least 65%