807 research outputs found
In Vivo Liquid Solution ENDOR and TRIPLE Resonance of Bacterial Photosynthetic Reaction Centers of Rhodopseudomonas sphaeroides R-26
Non-ergodic effects in the Coulomb glass: specific heat
We present a numerical method for the investigation of non-ergodic effects in
the Coulomb glass. For that, an almost complete set of low-energy many-particle
states is obtained by a new algorithm. The dynamics of the sample is mapped to
the graph formed by the relevant transitions between these states, that means
by transitions with rates larger than the inverse of the duration of the
measurement. The formation of isolated clusters in the graph indicates
non-ergodicity. We analyze the connectivity of this graph in dependence on
temperature, duration of measurement, degree of disorder, and dimensionality,
studying how non-ergodicity is reflected in the specific heat.Comment: Submited Phys. Rev.
ESR, ENDOR and TRIPLE resonance studies of the primary donor radical cation P960+ in the photosynthetic bacterium Rhodopseudomonas viridis
The light-induced radical cation of the primary electron donor P960+• in photosynthetic reaction centers from Rhodopseudomonas viridis has been investigated by ESR, ENDOR and TRIPLE techniques. Both the comparison with the cation radical of monomeric bacteriochlorophyll b (BChl b) and with molecular-orbital calculations performed on P960+• using the results of an X-ray structure analysis, consistently show an asymmetric distribution of the unpaired electron over the two BChl b molecules which constitute P960+•. The possible relevance of this result for the primary electron transfer step in the reaction center is briefly discussed
Proton endor study of the photoexcited triplet state PT in Rps. sphaeroides R-26 photosynthetic reaction centres
The photoexcited triplet state PT of Rhodopseudomonas sphaeroides R-26 has been investigated by ENDOR measurements performed on frozen photosynthetic reaction centre solutions. For the first time hyperfine data could be obtained for PT. These data indicate a delocalisation of the triplet state over two bacteriochlorophyll a molecules
The radical cation of bacteriochlorophyll b. A liquid-phase endor and triple resonance study
The previous termradical cationnext term of bacterioehlorophyll b (BChl b) is investigated by ENDOR and TRIPLE resonance in liquid solution. The experimental hyperfine coupling constants, ten proton and three nitrogen couplings, are compared with the predictions from advanced molecular-orbital calculations (RHF INDO/SP). The detailed picture obtained of the spin density distribution is a prerequisite for the investigation of the primary electron donor previous termradical cationnext term in BChl b containing photosynthetic bacteria
The Effect of Air on Granular Size Separation in a Vibrated Granular Bed
Using high-speed video and magnetic resonance imaging (MRI) we study the
motion of a large sphere in a vertically vibrated bed of smaller grains. As
previously reported we find a non-monotonic density dependence of the rise and
sink time of the large sphere. We find that this density dependence is solely
due to air drag. We investigate in detail how the motion of the intruder sphere
is influenced by size of the background particles, initial vertical position in
the bed, ambient pressure and convection. We explain our results in the
framework of a simple model and find quantitative agreement in key aspects with
numerical simulations to the model equations.Comment: 14 pages, 16 figures, submitted to PRE, corrected typos, slight
change
Optimization by thermal cycling
Thermal cycling is an heuristic optimization algorithm which consists of
cyclically heating and quenching by Metropolis and local search procedures,
respectively, where the amplitude slowly decreases. In recent years, it has
been successfully applied to two combinatorial optimization tasks, the
traveling salesman problem and the search for low-energy states of the Coulomb
glass. In these cases, the algorithm is far more efficient than usual simulated
annealing. In its original form the algorithm was designed only for the case of
discrete variables. Its basic ideas are applicable also to a problem with
continuous variables, the search for low-energy states of Lennard-Jones
clusters.Comment: Submitted to Proceedings of the Workshop "Complexity, Metastability
and Nonextensivity", held in Erice 20-26 July 2004. Latex, 7 pages, 3 figure
Near-Resonant Nonlinear Optical Properties of Pseudoisocyanine J-Aggregates in Langmuir-Blodgett Layers
Critical behavior of the Coulomb-glass model in the zero-disorder limit: Ising universality in a system with long-range interactions
The ordering of charges on half-filled hypercubic lattices is investigated
numerically, where electroneutrality is ensured by background charges. This
system is equivalent to the Ising lattice model with
antiferromagnetic interaction. The temperature dependences of specific
heat, mean staggered occupation, and of a generalized susceptibility indicate
continuous order-disorder phase transitions at finite temperatures in two- and
three-dimensional systems. In contrast, the susceptibility of the
one-dimensional system exhibits singular behavior at vanishing temperature. For
the two- and three-dimensional cases, the critical exponents are obtained by
means of a finite-size scaling analysis. Their values are consistent with those
of the Ising model with short-range interaction, and they imply that the
studied model cannot belong to any other known universality class. Samples of
up to 1400, , and sites are considered for dimensions 1 to 3,
respectively.Comment: revtex-file + 14 figures -> 10 pages; two references added, typos
correcte
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