53 research outputs found
The electrorheology of suspensions consisting of Na-Fluorohectorite synthetic clay particles in silicon oil
Under application of an electric field greater than a triggering electric
field kV/mm, suspensions obtained by dispersing particles of the
synthetic clay fluoro-hectorite in a silicon oil, aggregate into chain- and/or
column-like structures parallel to the applied electric field. This
micro-structuring results in a transition in the suspensions' rheological
behavior, from a Newtonian-like behavior to a shear-thinning rheology with a
significant yield stress. This behavior is studied as a function of particle
volume fraction and strength of the applied electric field, . The steady
shear flow curves are observed to scale onto a master curve with respect to
, in a manner similar to what was recently found for suspensions of laponite
clay [42]. In the case of Na-fluorohectorite, the corresponding dynamic yield
stress is demonstrated to scale with respect to as a power law with an
exponent , while the static yield stress inferred from
constant shear stress tests exhibits a similar behavior with . The suspensions are also studied in the framework of thixotropic fluids:
the bifurcation in the rheology behavior when letting the system flow and
evolve under a constant applied shear stress is characterized, and a
bifurcation yield stress, estimated as the applied shear stress at which
viscosity bifurcation occurs, is measured to scale as with to 0.6. All measured yield stresses increase with the particle
fraction of the suspension. For the static yield stress, a scaling law
, with , is found. The results are found to be
reasonably consistent with each other. Their similarities with-, and
discrepancies to- results obtained on laponite-oil suspensions are discussed
Intercalation-enhanced electric polarization and chain formation of nano-layered particles
Microscopy observations show that suspensions of synthetic and natural
nano-layered smectite clay particles submitted to a strong external electric
field undergo a fast and extended structuring. This structuring results from
the interaction between induced electric dipoles, and is only possible for
particles with suitable polarization properties. Smectite clay colloids are
observed to be particularly suitable, in contrast to similar suspensions of a
non-swelling clay. Synchrotron X-ray scattering experiments provide the
orientation distributions for the particles. These distributions are understood
in terms of competing (i) homogenizing entropy and (ii) interaction between the
particles and the local electric field; they show that clay particles polarize
along their silica sheet. Furthermore, a change in the platelet separation
inside nano-layered particles occurs under application of the electric field,
indicating that intercalated ions and water molecules play a role in their
electric polarization. The resulting induced dipole is structurally attached to
the particle, and this causes particles to reorient and interact, resulting in
the observed macroscopic structuring. The macroscopic properties of these
electro-rheological smectite suspensions may be tuned by controlling the nature
and quantity of the intercalated species, at the nanoscale.Comment: 7 pages, 5 figure
Structure-dependent mobility of a dry aqueous foam flowing along two parallel channels
The velocity of a two-dimensional aqueous foam has been measured as it flows
through two parallel channels, at a constant overall volumetric flow rate. The
flux distribution between the two channels is studied as a function of the
ratio of their widths. A peculiar dependence of the velocity ratio on the width
ratio is observed when the foam structure in the narrower channel is either
single staircase or bamboo. In particular, discontinuities in the velocity
ratios are observed at the transitions between double and single staircase and
between single staircase and bamboo. A theoretical model accounting for the
viscous dissipation at the solid wall and the capillary pressure across a film
pinned at the channel outlet predicts the observed non-monotonic evolution of
the velocity ratio as a function of the width ratio. It also predicts
quantitatively the intermittent temporal evolution of the velocity in the
narrower channel when it is so narrow that film pinning at its outlet
repeatedly brings the flow to a near stop
Strengthening the health surveillance of marine mammals in the waters of metropolitan France by monitoring strandings
peer reviewedMonitoring the health status of marine mammals is a priority theme that France aims to develop with the other European Union Member States in the next two years, in the context of the Marine Strategy Framework Directive. With approximately 5,000 km of coastline and for nearly ten years, France has been recording an average of 2,000 strandings per year, which are monitored by the National Stranding Network, managed by Pelagis, the observatory for the conservation of marine mammals from La Rochelle University and the French National Center for Scientific Research. Since 1972, this network has successively evolved from spatial and temporal faunistic description to, nowadays, the detection of major causes of mortality. It now aims to carry out epidemiological studies on a population scale. Thus, a strategy to strengthen the monitoring of marine mammals’ health status based on stranding data has been developed. This strategy will allow for a more accurate detection of anthropogenic cause of death as well as those of natural origin. It will allow the monitoring of time trends and geographical differences of diseases associated with conservation and public health issues while ensuring the early detection of emerging and/or zoonotic diseases of importance. It will also allow a better assessment of the consequences of human activities on these animal populations and on the environment. Thus, this strategy is fully in line with the “One Health” approach which implies an integrated vision of public, animal and environmental health. It is broken down into four surveillance modalities: (1) general event-based surveillance (GES); (2) programmed surveillance (PS); (3) specific event-based surveillance (SES); (4) and in the longer term, syndromic surveillance (SyS). This article describes the French strategy as well as these different surveillance modalities, the levels of examinations and the associated sampling protocols and finally, the method of standardisation of the data collected. The objective is to present the strategy developed at the French level in order to integrate it into a future strategy shared at the European level to standardise practices and especially complementary analysis, necessary for a better evaluation of the health status of these mobile marine species
Clades of huge phages from across Earth's ecosystems
Bacteriophages typically have small genomes and depend on their bacterial hosts for replication. Here we sequenced DNA from diverse ecosystems and found hundreds of phage genomes with lengths of more than 200 kilobases (kb), including a genome of 735 kb, which is-to our knowledge-the largest phage genome to be described to date. Thirty-five genomes were manually curated to completion (circular and no gaps). Expanded genetic repertoires include diverse and previously undescribed CRISPR-Cas systems, transfer RNAs (tRNAs), tRNA synthetases, tRNA-modification enzymes, translation-initiation and elongation factors, and ribosomal proteins. The CRISPR-Cas systems of phages have the capacity to silence host transcription factors and translational genes, potentially as part of a larger interaction network that intercepts translation to redirect biosynthesis to phage-encoded functions. In addition, some phages may repurpose bacterial CRISPR-Cas systems to eliminate competing phages. We phylogenetically define the major clades of huge phages from human and other animal microbiomes, as well as from oceans, lakes, sediments, soils and the built environment. We conclude that the large gene inventories of huge phages reflect a conserved biological strategy, and that the phages are distributed across a broad bacterial host range and across Earth's ecosystems
Electrorheological Suspensions of Laponite in Oil: Rheometry Studies
International audienceWe have studied the effect of an external direct current (DC) electric field (1 kV/mm) on the rheological properties of colloidal suspensions consisting of aggregates of laponite particles in a silicone oil. Microscopy observations show that, under application of an electric field greater than a triggering electric field Ec 0.6 kV/mm, laponite aggregates assemble into chain- and/or columnlike structures in the oil. Without an applied electric field, the steady-state shear behavior of such suspensions is Newtonian-like. Under application of an electric field larger than Ec, it changes dramatically as a result of the changes in the microstructure: a significant yield stress is measured, and under continuous shear the fluid is shear-thinning. The rheological properties, in particular the dynamic and static shear stress, were studied as a function of particle volume fraction for various strengths (including null) of the applied electric field. The flow curves at constant shear rate can be scaled with respect to both the particle fraction and electric field strength onto a master curve. This scaling is consistent with simple scaling arguments. The shape of the master curve accounts for the system's complexity; it approaches a standard power-law model at high Mason numbers. Both dynamic and static yield stresses are observed to depend on the particle fraction — and electric field E as —âER, with R 1.85 and â 1 and 1.70 for the dynamic and static yield stresses, respectively. The yield stress was also determined as the critical stress at which there occurs a bifurcation in the rheological behavior of suspensions that are submitted to a constant shear stress; a scaling law with R 1.84 and â 1.70 was obtained. The effectiveness of the latter technique confirms that such electrorheological (ER) fluids can be studied in the framework of thixotropic fluids. The method is very reproducible; we suggest that it could be used routinely for studying ER fluids. The measured overall yield stress behavior of the suspensions may be explained in terms of standard conduction models for electrorheological systems. Interesting prospects include using such systems for guided self-assembly of clay nanoparticles
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