1,187 research outputs found
Controls of dissolved organic matter quality: Evidence from a large-scale boreal lake survey
Inland waters transport large amounts of dissolved organic matter (DOM) from terrestrial environments to the oceans, but DOM also reacts en route, with substantial water column losses by mineralization and sedimentation. For DOM transformations along the aquatic continuum, lakes play an important role as they retain waters in the landscape allowing for more time to alter DOM. We know DOM losses are significant at the global scale, yet little is known about how the reactivity of DOM varies across landscapes and climates. DOM reactivity is inherently linked to its chemical composition. We used fluorescence spectroscopy to explore DOM quality from 560 lakes distributed across Sweden and encompassed a wide climatic gradient typical of the boreal ecozone. Six fluorescence components were identified using parallel factor analysis (PARAFAC). The intensity and relative abundance of these components were analyzed in relation to lake chemistry, catchment, and climate characteristics. Land cover, particularly the percentage of water in the catchment, was a primary factor explaining variability in PARAFAC components. Likewise, lake water retention time influenced DOM quality. These results suggest that processes occurring in upstream water bodies, in addition to the lake itself, have a dominant influence on DOM quality. PARAFAC components with longer emission wavelengths, or red-shifted components, were most reactive. In contrast, protein-like components were most persistent within lakes. Generalized characteristics of PARAFAC components based on emission wavelength could ease future interpretation of fluorescence spectra. An important secondary influence on DOM quality was mean annual temperature, which ranged between −6.2 and +7.5 °C. These results suggest that DOM reactivity depends more heavily on the duration of time taken to pass through the landscape, rather than temperature. Projected increases in runoff in the boreal region may force lake DOM toward a higher overall amount and proportion of humic-like substances
Isotopic Scaling of Heavy Projectile Residues from the collisions of 25 MeV/nucleon 86Kr with 124Sn, 112Sn and 64Ni, 58Ni
The scaling of the yields of heavy projectile residues from the reactions of
25 MeV/nucleon 86Kr projectiles with 124Sn,112Sn and 64Ni, 58Nitargets is
studied. Isotopically resolved yield distributions of projectile fragments in
the range Z=10-36 from these reaction pairs were measured with the MARS recoil
separator in the angular range 2.7-5.3 degrees. The velocities of the residues,
monotonically decreasing with Z down to Z~26-28, are employed to characterize
the excitation energy. The yield ratios R21(N,Z) for each pair of systems are
found to exhibit isotopic scaling (isoscaling), namely, an exponential
dependence on the fragment atomic number Z and neutron number N. The isoscaling
is found to occur in the residue Z range corresponding to the maximum observed
excitation energies. The corresponding isoscaling parameters are alpha=0.43 and
beta=-0.50 for the Kr+Sn system and alpha=0.27 and beta=-0.34 for the Kr+Ni
system. For the Kr+Sn system, for which the experimental angular acceptance
range lies inside the grazing angle, isoscaling was found to occur for Z<26 and
N<34. For heavier fragments from Kr+Sn, the parameters vary monotonically,
alpha decreasing with Z and beta increasing with N. This variation is found to
be related to the evolution towards isospin equilibration and, as such, it can
serve as a tracer of the N/Z equilibration process. The present heavy-residue
data extend the observation of isotopic scaling from the intermediate mass
fragment region to the heavy-residue region. Such high-resolution mass
spectrometric data can provide important information on the role of isospin in
peripheral and mid-peripheral collisions, complementary to that accessible from
modern large-acceptance multidetector devices.Comment: 8 pages, 6 figures, submitted to Phys. Rev.
Relativistic mean-field study of neutron-rich nuclei
A relativistic mean-field model is used to study the ground-state properties
of neutron-rich nuclei. Nonlinear isoscalar-isovector terms, unconstrained by
present day phenomenology, are added to the model Lagrangian in order to modify
the poorly known density dependence of the symmetry energy. These new terms
soften the symmetry energy and reshape the theoretical neutron drip line
without compromising the agreement with existing ground-state information. A
strong correlation between the neutron radius of 208Pb and the binding energy
of valence orbitals is found: the smaller the neutron radius of 208Pb, the
weaker the binding energy of the last occupied neutron orbital. Thus, models
with the softest symmetry energy are the first ones to drip neutrons. Further,
in anticipation of the upcoming one-percent measurement of the neutron radius
of 208Pb at the Thomas Jefferson Laboratory, a close relationship between the
neutron radius of 208Pb and neutron radii of elements of relevance to atomic
parity-violating experiments is established.Comment: 14 pages, 5 figure
Spaces of finite element differential forms
We discuss the construction of finite element spaces of differential forms
which satisfy the crucial assumptions of the finite element exterior calculus,
namely that they can be assembled into subcomplexes of the de Rham complex
which admit commuting projections. We present two families of spaces in the
case of simplicial meshes, and two other families in the case of cubical
meshes. We make use of the exterior calculus and the Koszul complex to define
and understand the spaces. These tools allow us to treat a wide variety of
situations, which are often treated separately, in a unified fashion.Comment: To appear in: Analysis and Numerics of Partial Differential
Equations, U. Gianazza, F. Brezzi, P. Colli Franzone, and G. Gilardi, eds.,
Springer 2013. v2: a few minor typos corrected. v3: a few more typo
correction
Comparison of usefulness of computer assisted continuous 48-h 3-lead with 12-lead ECG ischaemia monitoring for detection and quantitation of ischaemia in patients with unstable angina
AIMS: The selection of ECG leads used for ST monitoring may influence detection and quantitation of ischaemia. METHODS: We compared on-line continuous 48-h 12-lead against 3-lead ST monitoring in 130 unstable angina patients (Mortara. ELI-100). Onset and offset of ST episodes were defined by the lead with the first > or = 100 microV ST change relative to baseline and the lead with the latest return to baseline ST level, respectively. ST episodes were calculated for 12 leads and 3 leads (V2, V5, III) separately. RESULTS: ST episodes were detected in 88 patients (77%) by 12-lead and in 71 patients (62%) by 3-lead ST monitoring (P < 0.02). The median number (25.75%) of episodes/patient was 1 (0.3) for 3-lead and 2 (1.6) for 12-lead (P < 0.0001). The total duration of ischaemia detected during 12-lead far exceeded 3-lead monitoring: 12.3 (1, 58.2) and 1.7 (0, 23.3) min respectively (P < 0.0001). The probability of recurrent ischaemia declined most during the first 24 h of monitoring. After a period without ST changes of 1, 12, 24 and 36 h, the probabilities of recurrent ischaemia were 63, 31, 14 and 9%, respectively. CONCLUSIONS: Continuous 12-lead ST monitoring increases detection rate and duration of ST episodes compared to 3-lead ST monitoring. The use of continuous 12-lead ECG monitoring devices on emergency wards and coronary care units is recommended
-Spectral theory of locally symmetric spaces with -rank one
We study the -spectrum of the Laplace-Beltrami operator on certain
complete locally symmetric spaces with finite volume and
arithmetic fundamental group whose universal covering is a
symmetric space of non-compact type. We also show, how the obtained results for
locally symmetric spaces can be generalized to manifolds with cusps of rank
one
Techno-economic assessment guidelines for CO2 utilization
Carbon Capture and Utilization (CCU) is an emerging technology field that can replace fossil carbon value chains, and that has a significant potential to achieve emissions mitigation or even “negative emissions”—however in many cases with challenging technology feasibility and economic viability. Further challenges arise in the decision making for CCU technology research, development, and deployment, in particular when allocating funding or time resources. No generally accepted techno-economic assessment (TEA) standard has evolved, and assessment studies often result in “apples vs. oranges” comparisons, a lack of transparency and a lack of comparability to other studies. A detailed guideline for systematic techno-economic (TEA) and life cycle assessment (LCA) for CCU technologies was developed; this paper shows a summarized version of the TEA guideline, which includes distinct and prioritized (shall and should) rules and which allows conducting TEA in parallel to LCA. The TEA guideline was developed in a co-operative and creative approach with roughly 50 international experts and is based on a systematic literature review as well as on existing best practices from TEA and LCA from the areas of industry, academia, and policy. To the best of our knowledge, this guideline is the first TEA framework with a focus on CCU technologies and the first that is designed to be conducted in parallel to LCA due to aligned vocabulary and assessment steps, systematically including technology maturity. Therefore, this work extends current literature, improving the design, implementation, and reporting approaches of TEA studies for CCU technologies. Overall, the application of this TEA guideline aims at improved comparability of TEA studies, leading to improved decision making and more efficient allocation of funds and time resources for the research, development, and deployment of CCU technologies
Serum Angiotensin-Converting Enzyme as a Marker of Dialyzer Membrane Biocompatibility?
Onset of magnetism in B2 transition metals aluminides
Ab initio calculation results for the electronic structure of disordered bcc
Fe(x)Al(1-x) (0.4<x<0.75), Co(x)Al(1-x) and Ni(x)Al(1-x) (x=0.4; 0.5; 0.6)
alloys near the 1:1 stoichiometry, as well as of the ordered B2 (FeAl, CoAl,
NiAl) phases with point defects are presented. The calculations were performed
using the coherent potential approximation within the Korringa-Kohn-Rostoker
method (KKR-CPA) for the disordered case and the tight-binding linear
muffin-tin orbital (TB-LMTO) method for the intermetallic compounds. We studied
in particular the onset of magnetism in Fe-Al and Co-Al systems as a function
of the defect structure. We found the appearance of large local magnetic
moments associated with the transition metal (TM) antisite defect in FeAl and
CoAl compounds, in agreement with the experimental findings. Moreover, we found
that any vacancies on both sublattices enhance the magnetic moments via
reducing the charge transfer to a TM atom. Disordered Fe-Al alloys are
ferromagnetically ordered for the whole range of composition studied, whereas
Co-Al becomes magnetic only for Co concentration >0.5.Comment: 11 pages with 9 embedded postscript figures, to be published in
Phys.Rev.
Collective modes of asymmetric nuclear matter in Quantum HadroDynamics
We discuss a fully relativistic Landau Fermi liquid theory based on the
Quantum Hadro-Dynamics () effective field picture of Nuclear Matter
({\it NM}).
From the linearized kinetic equations we get the dispersion relations of the
propagating collective modes. We focus our attention on the dynamical effects
of the interplay between scalar and vector channel contributions. A beautiful
``mirror'' structure in the form of the dynamical response in the
isoscalar/isovector degree of freedom is revealed, with a complete parallelism
in the role respectively played by the compressibility and the symmetry energy.
All that strongly supports the introduction of an explicit coupling to the
scalar-isovector channel of the nucleon-nucleon interaction. In particular we
study the influence of this coupling (to a -meson-like effective field)
on the collective response of asymmetric nuclear matter (). Interesting
contributions are found on the propagation of isovector-like modes at normal
density and on an expected smooth transition to isoscalar-like oscillations at
high baryon density. Important ``chemical'' effects on the neutron-proton
structure of the mode are shown. For dilute we have the isospin
distillation mechanism of the unstable isoscalar-like oscillations, while at
high baryon density we predict an almost pure neutron wave structure of the
propagating sounds.Comment: 18 pages (LATEX), 8 Postscript figures, uses "epsfig
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