Il processo Pellico-Maroncelli secondo gli atti officiali segreti / per Alessandro Luzio Milano : Tip. L.F. Cogliati, 1903

Il processo Pellico-Maroncelli secondo gli atti officiali segreti / per Alessandro Luzio Milano : Tip. L.F. Cogliati, 1903 569 p., [4] c. di tav. : ritr., facs. ; 25 cm

Antonio Salvotti e i processi del Ventuno / Alessandro Luzio

Antonio Salvotti e i processi del Ventuno / Alessandro Luzio Roma : Società editrice Dante Alighieri, 1901 327 p., [2] c. di tav. ; 20 cm

Coset Cosmology

We show that the potential of Nambu-Goldstone bosons can have two or more local minima e.g. at antipodal positions in the vacuum manifold. This happens in many models of composite Higgs and of composite Dark Matter. Trigonometric potentials lead to unusual features, such as symmetry non-restoration at high temperature. In some models, such as the minimal $\rm SO(5)/SO(4)$ composite Higgs with fermions in the fundamental representation, the two minima are degenerate giving cosmological domain-wall problems. Otherwise, an unusual cosmology arises, that can lead to supermassive primordial black holes; to vacuum or thermal decays; to a high-temperature phase of broken $\mathrm{SU}(2)_L$, possibly interesting for baryogenesis.Comment: 30 pages, 6 figures; published versio

Highly Planarized Naphthalene Diimide-Bifuran Copolymers with Unexpected Charge Transport Performance

The synthesis, characterization, and charge transport performance of novel copolymers PNDIFu2 made from alternating naphthalene diimide (NDI) and bifuran (Fu2) units are reported. Usage of potentially biomass-derived Fu2 as alternating repeat unit enables flattened polymer backbones due to reduced steric interactions between the imide oxygens and Fu2 units, as seen by density functional theory (DFT) calculations and UV-vis spectroscopy. Aggregation of PNDIFu2 in solution is enhanced if compared to the analogous NDI-bithiophene (T2) copolymers PNDIT2, occurring in all solvents and temperatures probed. PNDIFu2 features a smaller π-π stacking distance of 0.35 nm compared to 0.39 nm seen for PNDIT2. Alignment of aggregates in films is achieved by using off-center spin coating, whereby PNDIFu2 exhibits a stronger dichroic ratio and transport anisotropy in field-effect transistors (FET) compared to PNDIT2, with an overall good electron mobility of 0.21 cm2/(V s). Despite an enhanced backbone planarity, the smaller π-π stacking and the enhanced charge transport anisotropy, the electron mobility of PNDIFu2 is about three times lower compared to PNDIT2. Density functional theory calculations suggest that charge transport in PNDIFu2 is limited by enhanced polaron localization compared to PNDIT2

Self-Powered Edible Defrosting Sensor

Improper freezing of food causes food waste and negatively impacts the environment. In this work, we propose a device that can detect defrosting events by coupling a temperature-activated galvanic cell with an ionochromic cell, which is activated by the release of ions during current flow. Both the components of the sensor are fabricated through simple and low-energy-consuming procedures from edible materials. The galvanic cell operates with an aqueous electrolyte solution, producing current only at temperatures above the freezing point of the solution. The ionochromic cell exploits the current generated during the defrosting to release tin ions, which form complexes with natural dyes, causing the color change. Therefore, this sensor provides information about defrosting events. The temperature at which the sensor reacts can be tuned between 0 and -50 °C. The device can thus be flexibly used in the supply chain: as a sensor, it can measure the length of exposure to above-the-threshold temperatures, while as a detector, it can provide a signal that there was exposure to above-the-threshold temperatures. Such a device can ensure that frozen food is handled correctly and is safe for consumption. As a sensor, it could be used by the workers in the supply chain, while as a detector, it could be useful for end consumers, ensuring that the food was properly frozen during the whole supply chain

Axion quality from the (anti)symmetric of SU(N)

We propose two models where a U(1) Peccei-Quinn global symmetry arises accidentally and is respected up to high-dimensional operators, so that the axion solution to the strong CP problem is successful even in the presence of Planck-suppressed operators. One model is SU$(N)$ gauge interactions with fermions in the fundamental and a scalar in the symmetric. The axion arises from spontaneous symmetry breaking to SO$(N)$, that confines at a lower energy scale. Axion quality in the model needs $N \gtrsim 10$. SO bound states and possibly monopoles provide extra Dark Matter candidates beyond the axion. In the second model the scalar is in the anti-symmetric: SU$(N)$ broken to Sp$(N)$ needs even $N \gtrsim 20$. The cosmological DM abundance, consisting of axions and/or super-heavy relics, can be reproduced if the PQ symmetry is broken before inflation (Boltzmann-suppressed production of super-heavy relics) or after (super-heavy relics in thermal equilibrium get partially diluted by dark glue-ball decays).Comment: 26 pages, 5 figures. v3: extra application mentioned; dilution factor in eq. (27) corrected, qualitative conclusions unchange

Effects of PNDIT2 end groups on aggregation, thin film structure, alignment and electron transport in field-effect transistors

To develop greener protocols toward the sustainable production of conjugated polymers, we combine the advantages of atom-economic direct arylation polycondensation (DAP) with those of the green solvent 2-methyltetrahydrofuran (MeTHF). The n-type copolymer PNDIT2 is synthesized from unsubstituted bithiophene (T2) and 2,6-dibromonapthalene diimide (NDIBr2) under simple DAP conditions in MeTHF. Extensive optimization is required to suppress nucleophilic substitution of NDIBr end groups, which severely limits molar mass. Different carboxylic acids, bases, palladium precursors and ligands are successfully screened to enable quantitative yield and satisfyingly high molar masses up to Mn,SEC ∼ 20 kDa. In contrast to PNDIT2 made via DAP in toluene with tolyl-chain termini, nucleophilic substitution of NDIBr chain ends in MeTHF finally leads to NDI-OH termination. The influence of different chain termini on the optical, thermal, structural and electronic properties of PNDIT2 is investigated. For samples with identical molecular weight, OH-termination leads to slightly reduced aggregation in solution and bulk crystallinity, a decreased degree of alignment in directionally deposited films, and a consequently reduced, but not compromised, electron mobility with promising values still close to 0.9 cm2 V−1 s−1

Geophysical study of the hydrothermal reservoir in the Panza area (Ischia, Italy)

The aim of the present work is the reconstruction of the main geometric pattern and the characterisation with geophysical parameters of geological structures lying at small and medium depths in an area of the Ischia island (Italy), where a sensible hydrothermal activity is present

Electrospun Polymer Fibers for Electronic Applications

Nano- and micro- fibers of conjugated polymer semiconductors are particularly interesting both for applications and for fundamental research. They allow an investigation into how electronic properties are influenced by size confinement and chain orientation within microstructures that are not readily accessible within thin films. Moreover, they open the way to many applications in organic electronics, optoelectronics and sensing. Electro-spinning, the technique subject of this review, is a simple method to effectively form and control conjugated polymer fibers. We provide the basics of the technique and its recent advancements for the formation of highly conducting and high mobility polymer fibers towards their adoption in electronic applications