764 research outputs found
Antiferromagnetism and Superconductivity in UPt_3
The short ranged antiferromagnetism recently seen in UPt_3 is proved
incompatible with two dimensional (2D) order parameter models that take the
antiferromagnetism as a symmetry breaking field. To adjust to the local moment
direction, the order parameter twists over very long length scales as per the
Imry-Ma argument. A variational solution to the Ginzburg-Landau equations is
used to study the nature of the short ranged order. Although there are still
two transitions, the lower one is of first order -- in contradiction to
experiments. It is shown that the latent heat predicted by the 2D models at the
lower transition is too large not to have been seen. A simple periodic model is
numerically studied to show that the lower transition can not be a crossover
either.Comment: To appear in Journal of Physics: Condensed Matter. 9 pages, 2 figure
A family of thermostable fungal cellulases created by structure-guided recombination
SCHEMA structure-guided recombination of 3 fungal class II cellobiohydrolases (CBH II cellulases) has yielded a collection of highly thermostable CBH II chimeras. Twenty-three of 48 genes sampled from the 6,561 possible chimeric sequences were secreted by the Saccharomyces cerevisiae heterologous host in catalytically active form. Five of these chimeras have half-lives of thermal inactivation at 63°C that are greater than the most stable parent, CBH II enzyme from the thermophilic fungus Humicola insolens, which suggests that this chimera collection contains hundreds of highly stable cellulases. Twenty-five new sequences were designed based on mathematical modeling of the thermostabilities for the first set of chimeras. Ten of these sequences were expressed in active form; all 10 retained more activity than H. insolens CBH II after incubation at 63°C. The total of 15 validated thermostable CBH II enzymes have high sequence diversity, differing from their closest natural homologs at up to 63 amino acid positions. Selected purified thermostable chimeras hydrolyzed phosphoric acid swollen cellulose at temperatures 7 to 15°C higher than the parent enzymes. These chimeras also hydrolyzed as much or more cellulose than the parent CBH II enzymes in long-time cellulose hydrolysis assays and had pH/activity profiles as broad, or broader than, the parent enzymes. Generating this group of diverse, thermostable fungal CBH II chimeras is the first step in building an inventory of stable cellulases from which optimized enzyme mixtures for biomass conversion can be formulated
An Effective Theory for Midgap States in Doped Spin Ladder and Spin-Peierls Systems: Liouville Quantum Mechanics
In gapped spin ladder and spin-Peierls systems the introduction of disorder,
for example by doping, leads to the appearance of low energy midgap states. The
fact that these strongly correlated systems can be mapped onto one dimensional
noninteracting fermions provides a rare opportunity to explore systems which
have both strong interactions and disorder. In this paper we show that the
statistics of the zero energy midgap wave functions in these models can be
effectively described by Liouville Quantum Mechanics. This enables us to
calculate the disorder averaged N-point correlation functions of these states
(the explicit calculation is performed for N=2,3). We find that whilst these
midgap states are typically weakly correlated, their disorder averaged
correlation are power law. This discrepancy arises because the correlations are
not self-averaging and averages of the wave functions are dominated by
anomalously strongly correlated configurations.Comment: 13 page latex fil
Identification of Non-unitary triplet pairing in a heavy Fermion superconductor UPt_3
A NMR experiment recently done by Tou et al. on a heavy Fermion
superconductor UPt is interpreted in terms of a non-unitary spin-triplet
pairing state which we have been advocating. The proposed state successfully
explains various aspects of the seemingly complicated Knight shift behaviors
probed for major orientations, including a remarkable d-vector rotation under
weak fields. This entitles UPt as the first example that a charged many
body system forms a spin-triplet odd-par ity pairing at low temperatures and
demonstrates unambiguously that the putative spin-orbit coupling in UPt is
weak.Comment: 4 pages, 2 eps figures, to be published in J. Phys. Soc. Jpn. 67
(1998) No.
Insights into analogy completion from the biomedical domain
Analogy completion has been a popular task in recent years for evaluating the semantic properties of word embeddings, but the standard methodology makes a number of assumptions about analogies that do not always hold, either in recent benchmark datasets or when expanding into other domains. Through an analysis of analogies in the biomedical domain, we identify three assumptions: that of a Single Answer for any given analogy, that the pairs involved describe the Same Relationship, and that each pair is Informative with respect to the other. We propose modifying the standard methodology to relax these assumptions by allowing for multiple correct answers, reporting MAP and MRR in addition to accuracy, and using multiple example pairs. We further present BMASS, a novel dataset for evaluating linguistic regularities in biomedical embeddings, and demonstrate that the relationships described in the dataset pose significant semantic challenges to current word embedding methods
A single chain analysis of doped quasi one dimensional spin 1 compounds: paramagnetic versus spin 1/2 doping
We present a numerical study of single chain models of doped spin 1
compounds. We use low energy effective one-dimensional models for both the
cases of paramagnetic and spin-1/2 doping. In the case of paramagnetic doping,
the effective model is equivalent to the bond disordered spin-1/2 chain model
recently analyzed by means of real space renormalization group by Hyman and
Yang. By means of exact diagonalizations in the XX limit, we confirm the
stability of the Haldane phase for weak disorder. Above a critical amount of
disorder, the effective model flows to the so called random singlet fixed
point. In the case of spin-1/2 doping, we argue that the Haldane phase should
be destabilized even for weak disorder. This picture is not in contradiction
with existing experimental data. We also discuss the possible occurrence of
(unobserved) antiferromagnetically ordered phases.Comment: 13 pages, 7 included figure
Universal Heat Conduction in YBa_2Cu_3O_6.9
The thermal conductivity of YBa_2Cu_3O_6.9 was measured at low temperatures
in untwinned single crystals with concentrations of Zn impurities from 0 to 3%
of Cu. A linear term kappa_0/T = 0.19 mW/K^2.cm is clearly resolved as T -> 0,
and found to be virtually independent of Zn concentration. The existence of
this residual normal fluid strongly validates the basic theory of transport in
unconventional superconductors. Moreover, the observed universal behavior is in
quantitative agreement with calculations for a gap function of d-wave symmetry.Comment: Latex file, 4 pages, 3 EPS figures, to appear in Physical Review
Letter
Study of impurities in spin-Peierls systems including lattice relaxation
The effects of magnetic and non-magnetic impurities in spin-Peierls systems
are investigated allowing for lattice relaxation and quantum fluctuations. We
show that, in isolated chains, strong bonds form next to impurities, leading to
the appearance of magneto-elastic solitons. Generically, these solitonic
excitations do not bind to impurities. However, interchain elastic coupling
produces an attractive potential at the impurity site which can lead to the
formation of bound states. In addition, we predict that small enough chain
segments do not carry magnetic moments at the ends
Electron-spin-resonance in the doped spin-Peierls compound Cu(1-x)Ni(x)GeO3
ESR-study of the Ni-doped spin-Peierls compound CuGeO3 has been performed in
the frequency range 9-75 GHz. At low temperatures the g-factor is smaller than
the value expected for Cu- and Ni-ions. This anomaly is explained by the
formation of magnetic clusters around the Ni-ions within a nonmagnetic
spin-Peierls matrix. The transition into the AFM-state detected earlier by
neutron scattering for doped samples was studied by means of ESR. For x=0.032 a
gap in the magnetic resonance spectrum is found below the Neel temperature and
the spectrum is well described by the theory of antiferromagnetic resonance
based on the molecular field approximation. For x=0.017 the spectrum below the
Neel point remained gapless. The gapless spectrum of the antiferromagnetic
state in weekly doped samples is attributed to the small value of the Neel
order parameter and to the magnetically disordered spin-Peierls background.Comment: 16 pages, LATEX, 12 figures, submitted to Journal of Physics :
Condensed Matte
- …