2,572 research outputs found
Semiconducting-to-metallic photoconductivity crossover and temperature-dependent Drude weight in graphene
We investigated the transient photoconductivity of graphene at various
gate-tuned carrier densities by optical-pump terahertz-probe spectroscopy. We
demonstrated that graphene exhibits semiconducting positive photoconductivity
near zero carrier density, which crosses over to metallic negative
photoconductivity at high carrier density. Our observations are accounted for
by considering the interplay between photo-induced changes of both the Drude
weight and the carrier scattering rate. Notably, we observed multiple sign
changes in the temporal photoconductivity dynamics at low carrier density. This
behavior reflects the non-monotonic temperature dependence of the Drude weight,
a unique property of massless Dirac fermions
Effect of next-nearest neighbor coupling on the optical spectra in bilayer graphene
We investigate the dependence of the optical conductivity of bilayer graphene
(BLG) on the intra- and inter-layer interactions using the most complete model
to date. We show that the next nearest-neighbor intralayer coupling introduces
new features in the low-energy spectrum that are highly sensitive to sample
doping, changing significantly the ``universal'' conductance. Further, its
interplay with interlayer couplings leads to an anisotropy in conductance in
the ultraviolet range. We propose that experimental measurement of the optical
conductivity of intrinsic and doped BLG will provide a good benchmark for the
relative importance of intra- and inter-layer couplings at different doping
levels.Comment: 5 pages, 5 figure
Competing Ultrafast Energy Relaxation Pathways in Photoexcited Graphene
For most optoelectronic applications of graphene a thorough understanding of
the processes that govern energy relaxation of photoexcited carriers is
essential. The ultrafast energy relaxation in graphene occurs through two
competing pathways: carrier-carrier scattering -- creating an elevated carrier
temperature -- and optical phonon emission. At present, it is not clear what
determines the dominating relaxation pathway. Here we reach a unifying picture
of the ultrafast energy relaxation by investigating the terahertz
photoconductivity, while varying the Fermi energy, photon energy, and fluence
over a wide range. We find that sufficiently low fluence ( 4
J/cm) in conjunction with sufficiently high Fermi energy (
0.1 eV) gives rise to energy relaxation that is dominated by carrier-carrier
scattering, which leads to efficient carrier heating. Upon increasing the
fluence or decreasing the Fermi energy, the carrier heating efficiency
decreases, presumably due to energy relaxation that becomes increasingly
dominated by phonon emission. Carrier heating through carrier-carrier
scattering accounts for the negative photoconductivity for doped graphene
observed at terahertz frequencies. We present a simple model that reproduces
the data for a wide range of Fermi levels and excitation energies, and allows
us to qualitatively assess how the branching ratio between the two distinct
relaxation pathways depends on excitation fluence and Fermi energy.Comment: Nano Letters 201
Trion induced negative photoconductivity in monolayer MoS2
Optical excitation typically enhances electrical conduction and low-frequency
radiation absorption in semiconductors. We have, however, observed a pronounced
transient decrease of conductivity in doped monolayer molybdenum disulfide
(MoS2), a two-dimensional (2D) semiconductor, under femtosecond laser
excitation. In particular, the conductivity is reduced dramatically down to
only 30% of its equilibrium value with high pump fluence. This anomalous
phenomenon arises from the strong many-body interactions in the system, where
photoexcited electron-hole pairs join the doping-induced charges to form
trions, bound states of two electrons and one hole. The resultant increase of
the carrier effective mass substantially diminishes the carrier conductivity
Nitrogen-Functionalized Graphene Nanoflakes (GNFs:N): Tunable Photoluminescence and Electronic Structures
This study investigates the strong photoluminescence (PL) and X-ray excited
optical luminescence observed in nitrogen-functionalized 2D graphene nanoflakes
(GNFs:N), which arise from the significantly enhanced density of states in the
region of {\pi} states and the gap between {\pi} and {\pi}* states. The
increase in the number of the sp2 clusters in the form of pyridine-like N-C,
graphite-N-like, and the C=O bonding and the resonant energy transfer from the
N and O atoms to the sp2 clusters were found to be responsible for the blue
shift and the enhancement of the main PL emission feature. The enhanced PL is
strongly related to the induced changes of the electronic structures and
bonding properties, which were revealed by the X-ray absorption near-edge
structure, X-ray emission spectroscopy, and resonance inelastic X-ray
scattering. The study demonstrates that PL emission can be tailored through
appropriate tuning of the nitrogen and oxygen contents in GNFs and pave the way
for new optoelectronic devices.Comment: 8 pages, 6 figures (including toc figure
Magnetic properties of Mn doped ZnO tetrapod structures
Author name used in this publication: C. Surya2003-2004 > Academic research: refereed > Publication in refereed journalVersion of RecordPublishe
Observation of out-of-plane vibrations in few-layer graphene
We report the observation of layer breathing mode (LBM) vibrations in
few-layer graphene (FLG) samples of thickness from 2 to 6 layers, exhibiting
both Bernal (AB) and rhombohedral (ABC) stacking order. The LBM vibrations are
identified using a Raman combination band lying around 1720 cm-1. From double
resonance theory, we identify the feature as the LOZO' combination mode of the
out-of-plane LBM (ZO') and the in-plane longitudinal optical mode (LO). The
LOZO' Raman band is found to exhibit multiple peaks, with a unique line shape
for each layer thickness and stacking order. These complex line shapes of the
LOZO'-mode arise both from the material-dependent selection of different
phonons in the double-resonance Raman process and from the detailed structure
of the different branches of LBM in FLG.Comment: 17 pages, 7 figures, supplemental material include
Individual prognosis at diagnosis in nonmetastatic prostate cancer: Development and external validation of the PREDICT Prostate multivariable model.
BACKGROUND: Prognostic stratification is the cornerstone of management in nonmetastatic prostate cancer (PCa). However, existing prognostic models are inadequate-often using treatment outcomes rather than survival, stratifying by broad heterogeneous groups and using heavily treated cohorts. To address this unmet need, we developed an individualised prognostic model that contextualises PCa-specific mortality (PCSM) against other cause mortality, and estimates the impact of treatment on survival. METHODS AND FINDINGS: Using records from the United Kingdom National Cancer Registration and Analysis Service (NCRAS), data were collated for 10,089 men diagnosed with nonmetastatic PCa between 2000 and 2010 in Eastern England. Median follow-up was 9.8 years with 3,829 deaths (1,202 PCa specific). Totals of 19.8%, 14.1%, 34.6%, and 31.5% of men underwent conservative management, prostatectomy, radiotherapy (RT), and androgen deprivation monotherapy, respectively. A total of 2,546 men diagnosed in Singapore over a similar time period represented an external validation cohort. Data were randomly split 70:30 into model development and validation cohorts. Fifteen-year PCSM and non-PCa mortality (NPCM) were explored using separate multivariable Cox models within a competing risks framework. Fractional polynomials (FPs) were utilised to fit continuous variables and baseline hazards. Model accuracy was assessed by discrimination and calibration using the Harrell C-index and chi-squared goodness of fit, respectively, within both validation cohorts. A multivariable model estimating individualised 10- and 15-year survival outcomes was constructed combining age, prostate-specific antigen (PSA), histological grade, biopsy core involvement, stage, and primary treatment, which were each independent prognostic factors for PCSM, and age and comorbidity, which were prognostic for NPCM. The model demonstrated good discrimination, with a C-index of 0.84 (95% CI: 0.82-0.86) and 0.84 (95% CI: 0.80-0.87) for 15-year PCSM in the UK and Singapore validation cohorts, respectively, comparing favourably to international risk-stratification criteria. Discrimination was maintained for overall mortality, with C-index 0.77 (95% CI: 0.75-0.78) and 0.76 (95% CI: 0.73-0.78). The model was well calibrated with no significant difference between predicted and observed PCa-specific (p = 0.19) or overall deaths (p = 0.43) in the UK cohort. Key study limitations were a relatively small external validation cohort, an inability to account for delayed changes to treatment beyond 12 months, and an absence of tumour-stage subclassifications. CONCLUSIONS: 'PREDICT Prostate' is an individualised multivariable PCa prognostic model built from baseline diagnostic information and the first to our knowledge that models potential treatment benefits on overall survival. Prognostic power is high despite using only routinely collected clinicopathological information.The Urology Foundatio
The Static and Dynamic Lattice Changes Induced by Hydrogen Adsorption on NiAl(110)
Static and dynamic changes induced by adsorption of atomic hydrogen on the
NiAl(110) lattice at 130 K have been examined as a function of adsorbate
coverage. Adsorbed hydrogen exists in three distinct phases. At low coverages
the hydrogen is itinerant because of quantum tunneling between sites and
exhibits no observable vibrational modes. Between 0.4 ML and 0.6 ML, substrate
mediated interactions produce an ordered superstructure with c(2x2) symmetry,
and at higher coverages, hydrogen exists as a disordered lattice gas. This
picture of how hydrogen interacts with NiAl(110) is developed from our data and
compared to current theoretical predictions.Comment: 36 pages, including 12 figures, 2 tables and 58 reference
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