6 research outputs found
Nonequilibrium electron energy distribution in Au under subpicosecond laser irradiation: A kinetic study
We have performed a kinetic study of the electron dynamic
relaxation inside a Au film subjected to a subpicosecond laser
pulse. For this purpose, we have developed a time-dependent
numerical solution of the Boltzmann equation for the electrons
inside the film considering the collision integrals due to
electron–electron and electron–phonon collisions
and a perturbation term due to the laser pulse. Our results
show that, after the pulse excitation, electron distributions
are very far from equilibrium. Therefore it is not possible,
especially in the first part of the temporal evolution, to describe
the relaxation of the electron distribution through a
two-temperature model
Reduced Two-Level Approach for Air Kinetics in Recombination Regime
Abstract. The possibility of using reduced model, that account for non-Boltzmann vibrational distributions for nitrogen monoxide kinetics has been explored. The basic idea is that the rate coefficients, which are proportional to the tail of the vibrational distribution function, are strictly correlated to reactant density rather than to vibrational temperature, which depend on the low energy distribution. The model consider the rate coefficients as a function of the population of the last vibrational level of the relevant species, which evolution is calculated with a proper kinetic equation
Advances in non-equilibrium
Numerous applications have required the study of plasmas since the 1960s, from lasers to spacecraft heat shields. However, in recent years, intense research activities on the subject have restarted because of environmental problems associated with emissions. The present review provides a synthesis of the current state of knowledge on the physical chemistry of cold plasmas. In particular, the different modeling approaches implemented to address specific aspects of plasmas are presented. Throughout the paper, the importance of conducting joint experimental, theoretical and modeling studies to elucidate the complex couplings at play in plasmas is emphasized. Therefore, the experimental data that are likely to bring relevant constraints to the different modeling approaches are first reviewed. Second, the calculation of some key elementary processes obtained with semi-empirical, classical and quantum methods is presented. In order to describe the electron kinetics, the latest coherent sets of cross section satisfying the constraints of “electron swarm” analyses are introduced, and the need for self-consistent calculations for determining accurate electron energy distribution function (EEDF) is evidenced. The main findings of the latest zero-dimensional (0D) global models about the complex chemistry of and its dissociation products in different plasma discharges are then given, and full state-to-state (STS) models of only the vibrational-dissociation kinetics developed for studies of spacecraft shields are described. Finally, two important points for all applications using containing plasma are discussed: the role of surfaces in contact with the plasma, and the need for 2D/3D models to capture the main features of complex reactor geometries including effects induced by fluid dynamics on the plasma properties. In addition to bringing together the latest advances in the description of non-equilibrium plasmas, the results presented here also highlight the fundamental data that are still missing and the possible routes that still need to be investigated