Biochar production through hydrothermal carbonization: Energy efficiency and cost analysis of an industrial-scale plant

Hydrothermal carbonization (HTC) is an induced coalification process that converts raw biomass into a coal-like product, called hydrochar, characterized by high carbon content and high calorific value. This type of thermo-chemical conversion, also referred to as wet pyrolysis (or wet torrefaction), can be applied to a variety of non-traditional sources such as the organic fraction of municipal solid waste, wet agricultural residues, sewage sludge. Unlike traditional dry pyrolysis, the HTC process allows for the treatment of substrates with elevated moisture content, up to 75%–90%, without requiring a drying pre-treatment step. Please click on the file below for full content of the abstract

Granular activated carbon from grape seeds hydrothermal char

A two-stage conversion process for the production of a valuable product from biomass waste, i.e., grape seeds activated carbon (GSAC) was investigated. Such process involved hydrothermal carbonization (HTC) of grape seeds, followed by chemical activation with potassium hydroxide (KOH). Different HTC temperatures (THTC = 180–250 °C), as well as different KOH:hydrochar ratios (R = 0.25:1–1:1), were explored. The samples that were obtained from both stages of the biomass conversion process were analyzed in terms of textural characterization (apparent total and micro-pore surface areas, total and micro-pore volumes, pore size distribution), proximate and ultimate compositions, thermal stability, surface morphology (via SEM), and surface chemistry characterization (via FTIR). Overall yields of approximately 35% were achieved, which are comparable to those obtained with the state-of-art one-stage process. In a wide range of operating conditions, the higher THTC and R, the higher was the surface area of the GSAC, which was maximal (above 1000 m2/g) for THTC = 250 °C and R = 0.5. At such optimal conditions, around 90% of the total porosity was due to micro-pores. Such a trend was not fulfilled at the most severe operating conditions (THTC = 250 °C; R = 1), which resulted in larger pore size, causing surface area reduction. A proper selection of the process parameters of both the process stages gives great opportunities of tuning and optimizing the overall process. The produced GSACs showed a remarkable thermal stability, and their surface appeared rather free of functional groups

Precise optical timing of PSR J1023+0038, the first millisecond pulsar detected with Aqueye+ in Asiago

We report the first detection of an optical millisecond pulsar with the fast photon counter Aqueye+ in Asiago. This is an independent confirmation of the detection of millisecond pulsations from PSR J1023+0038 obtained with SiFAP at the Telescopio Nazionale Galileo. We observed the transitional millisecond pulsar PSR J1023+0038 with Aqueye+ mounted at the Copernicus telescope in January 2018. Highly significant pulsations were detected. The rotational period is in agreement with the value extrapolated from the X-ray ephemeris, while the time of passage at the ascending node is shifted by $11.55 \pm 0.08$ s from the value predicted using the orbital period from the X-rays. An independent optical timing solution is derived over a baseline of a few days, that has an accuracy of $\sim 0.007$ in pulse phase ($\sim 12$ $\mu$s in time). This level of precision is needed to derive an accurate coherent timing solution for the pulsar and to search for possible phase shifts between the optical and X-ray pulses using future simultaneous X-ray and optical observations.Comment: 6 pages, 4 figures, accepted for publication in Monthly Notices of the Royal Astronomical Society Letter

Supercritical Water Gasification of Biomass in a Ceramic Reactor:Long-Time Batch Experiments

Supercritical water gasification (SCWG) is an emerging technology for the valorization of (wet) biomass into a valuable fuel gas composed of hydrogen and/or methane. The harsh temperature and pressure conditions involved in SCWG (T > 375 °C, p > 22 MPa) are definitely a challenge for the manufacturing of the reactors. Metal surfaces are indeed subject to corrosion under hydrothermal conditions, and expensive special alloys are needed to overcome such drawbacks. A ceramic reactor could be a potential solution to this issue. Finding a suitable material is, however, complex because the catalytic effect of the material can influence the gas yield and composition. In this work, a research reactor featuring an internal alumina inlay was utilized to conduct long-time (16 h) batch tests with real biomasses and model compounds. The same experiments were also conducted in batch reactors made of stainless steel and Inconel 625. The results show that the three devices have similar performance patterns in terms of gas production, although in the ceramic reactor higher yields of C2+ hydrocarbons were obtained. The SEM observation of the reacted alumina surface revealed a good resistance of such material to supercritical conditions, even though some intergranular corrosion was observed

The codex Piero Giustinian: an example of the genesis and evolution of medieval chronicles

La tesi di dottorato di Luca Fiori: Il codice autografo di Piero Giustinian: un esempio di genesi ed evoluzione della cronachistica medievale ha il principale obiettivo quello di dimostrare attraverso la editio princeps dell’autografo in latino, i meccanismi di formazione, trasmissione e proliferazione dei testi cronachistici medievali veneziani, mediante la collazione disamina della tradizione testuale di Pietro Giustinian.The PhD thesis of Luca Fiori: "The codex Piero Giustiniani: an example of the genesis and evolution of the medieval chronicle" has the main objective of demonstrating through editio princeps of the autograph in Latin, the mechanisms of formation, proliferation and transmission of texts Venetian medieval chronicles, through the collation examination of the textual tradition of Pietro Giustinian

Prickly pear seed oil extraction, chemical characterization and potential health benefits

4openInternationalBothPrickly pear (Opuntia ficus-indica L.) is a member of the Cactaceae family originally grown in South America, and the plant is now distributed to many parts of the world, including the Middle East. The chemical composition and biological activities of different parts of prickly pear, including cladodes, flowers, fruit, seeds and seed oil, were previously investigated. Oil from the seeds has been known for its nutritive value and can be potentially used for health promotion. This review is an effort to cover what is actually known to date about the prickly pear seeds oil extraction, characteristics, chemical composition and potential health benefits to provide inspiration for the need of further investigation and future research. Prickly pear seeds oil has been extracted using different extraction techniques from conventional to advanced. Chemical characterization of the oil has been sufficiently studied, and it is sufficiently understood that the oil is a high linoleic oil. Its composition is influenced by the variety and environment and also by the method of extraction. The health benefits of the prickly pear seed oil were reported by many researchers. For future research, additional studies are warranted on mechanisms of action of the reported biological activities to develop nutraceutical products for the prevention of various chronic human diseasesopenAl-Naqeb, Ghanya; Fiori, Luca; Ciolli, Marco; Aprea, EugenioAl-Naqeb, G.; Fiori, L.; Ciolli, M.; Aprea, E

Impact-based flash-flood forecasting system: Sensitivity to high resolution numerical weather prediction systems and soil moisture

In recent years, continuous improvements have been made in weather forecasting and flood prediction with great benefit from Early Warning Systems (EWSs). Despite the continuous quest for innovation from the scientific and user communities, EWSs remain based mostly on hazard forecast, and the information on possible consequences and potential impacts is generally missing. In this work, a methodology for quantitative real-time impact assessment for flash floods is presented. The methodology uses a multi-model ensemble approach and considers soil moisture uncertainty. Moreover, the flood forecasting chain, which normally provides only the discharge probability of exceeding a given threshold, is extended to include a fully 2D hydraulic model and a damage estimation model to quantitatively assess impacts in terms of economic losses and the people involved. The procedure was tested on recent flood events occurring in Genoa in northwestern Italy. This paper discusses the potential challenges and opportunities offered by this approach in the decision-making workflow in an operational context

Investigating the accuracy achievable in reconstructing the angular sizes of stars through stellar intensity interferometry observations

Context: In recent years, stellar intensity interferometry has seen renewed interest from the astronomical community because it can be efficiently applied to Cherenkov telescope arrays. Aims: We have investigated the accuracy that can be achieved in reconstructing stellar sizes by fitting the visibility curve measured on the ground. The large number of expected available astronomical targets, the limited number of nights in a year, and the likely presence of multiple baselines will require careful planning of the observational strategy to maximise the scientific output. Methods: We studied the trend of the error on the estimated angular size, considering the uniform disk model, by varying several parameters related to the observations, such as the total number of measurements, the integration time, the signal-to-noise ratio, and different positions along the baseline. Results: We found that measuring the value of the zero-baseline correlation is essential to obtain the best possible results. Systems that can measure this value directly or for which it is known in advance will have better sensitivity. We also found that to minimise the integration time, it is sufficient to obtain a second measurement at a baseline half-way between 0 and that corresponding to the first zero of the visibility function. This function does not have to be measured at multiple positions. Finally, we obtained some analytical expressions that can be used under specific conditions to determine the accuracy that can be achieved in reconstructing the angular size of a star in advance. This is useful to optimise the observation schedule.Comment: Accepted for publication by Astronomy & Astrophysics (A&A