15,437 research outputs found
Static NLO susceptibilities: testing approximation schemes against exact results
The reliability of the approximations commonly adopted in the calculation of
static optical (hyper)polarizabilities is tested against exact results obtained
for an interesting toy-model. The model accounts for the principal features of
typical nonlinear organic materials with mobile electrons strongly coupled to
molecular vibrations. The approximations introduced in sum over states and
finite field schemes are analyzed in detail. Both the Born-Oppenheimer and the
clamped nucleus approximations turn out to be safe for molecules, whereas for
donor-acceptor charge transfer complexes deviations from adiabaticity are
expected. In the regime of low vibrational frequency, static susceptibilities
are strongly dominated by the successive derivatives of the potential energy
and large vibrational contributions to hyperpolarizabilities are found. In this
regime anharmonic corrections to hyperpolarizabilities are very large, and the
harmonic approximation, exact for the linear polarizability, turns out totally
inadequate for nonlinear responses. With increasing phonon frequency the role
of vibrations smoothly decreases, until, in the antiadiabatic (infinite
vibrational frequency) regime, vibrations do not contribute anymore to static
susceptibilities, and the purely electronic responses are regained.Comment: 9 pages, including 3 figure
A Relativistic Version of the Two-Level Atom in the Rest-Frame Instant Form of Dynamics
We define a relativistic version of the two-level atom, in which an extended
atom is replaced by a point particle carrying suitable Grassmann variables for
the description of the two-level structure and of the electric dipole. After
studying the isolated system "atom plus the electro-magnetic field" in the
electric-dipole representation as a parametrized Minkowski theory, we give its
restriction to the inertial rest frame and the explicit form of the Poincar\'e
generators. After quantization we get a two-level atom with a spin 1/2 electric
dipole and the relativistic generalization of the Hamiltonians of the Rabi and
Jaynes-Cummings models.Comment: 23 page
Negative mass corrections in a dissipative stochastic environment
We study the dynamics of a macroscopic object interacting with a dissipative stochastic environment using an adiabatic perturbation theory. The perturbation theory reproduces known expressions for the friction coefficient and, surprisingly, gives an additional negative mass correction. The effect of the negative mass correction is illustrated by studying a harmonic oscillator interacting with a dissipative stochastic environment. While it is well known that the friction coefficient causes a reduction of the oscillation frequency, we show that the negative mass correction can lead to its enhancement. By studying an exactly solvable model of a magnet coupled to a spin environment evolving under standard non-conserving dynamics we show that the effect is present even beyond the validity of the adiabatic perturbation theory.We are grateful to M Kolodrubetz for the careful reading of the manuscript and helpful comments. This work was partially supported by BSF 2010318 (YK and AP), NSF DMR-1506340 (LD and AP), AFOSR FA9550-10-1-0110 (LD and AP), ARO W911NF1410540 (LD and AP) and ISF grant (YK). LD acknowledges the office of Naval Research. YK is grateful to the BU visitors program. (2010318 - BSF; DMR-1506340 - NSF; FA9550-10-1-0110 - AFOSR; W911NF1410540 - ARO; ISF grant)Accepted manuscrip
The Chrono-geometrical Structure of Special and General Relativity: a Re-Visitation of Canonical Geometrodynamics
A modern re-visitation of the consequences of the lack of an intrinsic notion
of instantaneous 3-space in relativistic theories leads to a reformulation of
their kinematical basis emphasizing the role of non-inertial frames centered on
an arbitrary accelerated observer. In special relativity the exigence of
predictability implies the adoption of the 3+1 point of view, which leads to a
well posed initial value problem for field equations in a framework where the
change of the convention of synchronization of distant clocks is realized by
means of a gauge transformation. This point of view is also at the heart of the
canonical approach to metric and tetrad gravity in globally hyperbolic
asymptotically flat space-times, where the use of Shanmugadhasan canonical
transformations allows the separation of the physical degrees of freedom of the
gravitational field (the tidal effects) from the arbitrary gauge variables.
Since a global vision of the equivalence principle implies that only global
non-inertial frames can exist in general relativity, the gauge variables are
naturally interpreted as generalized relativistic inertial effects, which have
to be fixed to get a deterministic evolution in a given non-inertial frame. As
a consequence, in each Einstein's space-time in this class the whole
chrono-geometrical structure, including also the clock synchronization
convention, is dynamically determined and a new approach to the Hole Argument
leads to the conclusion that "gravitational field" and "space-time" are two
faces of the same entity. This view allows to get a classical scenario for the
unification of the four interactions in a scheme suited to the description of
the solar system or our galaxy with a deperametrization to special relativity
and the subsequent possibility to take the non-relativistic limit.Comment: 33 pages, Lectures given at the 42nd Karpacz Winter School of
Theoretical Physics, "Current Mathematical Topics in Gravitation and
Cosmology", Ladek, Poland, 6-11 February 200
Multi-wavelength observations of 3FGL J2039.6-5618: a candidate redback millisecond pulsar
We present multi-wavelength observations of the unassociated gamma-ray source
3FGL J2039.6-5618 detected by the Fermi Large Area Telescope. The source
gamma-ray properties suggest that it is a pulsar, most likely a millisecond
pulsar, for which neither radio nor -ray pulsations have been detected
yet. We observed 3FGL J2039.6-5618 with XMM-Newton and discovered several
candidate X-ray counterparts within/close to the gamma-ray error box. The
brightest of these X-ray sources is variable with a period of 0.22450.0081
d. Its X-ray spectrum can be described by a power law with photon index
, and hydrogen column density cm, which gives an unabsorbed 0.3--10 keV X-ray flux of erg cm s. Observations with the Gamma-Ray Burst
Optical/Near-Infrared Detector (GROND) discovered an optical counterpart to
this X-ray source, with a time-average magnitude . The counterpart
features a flux modulation with a period of 0.227480.00043 d that
coincides, within the errors, with that of the X-ray source, confirming the
association based on the positional coincidence. We interpret the observed
X-ray/optical periodicity as the orbital period of a close binary system where
one of the two members is a neutron star. The light curve profile of the
companion star, with two asymmetric peaks, suggests that the optical emission
comes from two regions at different temperatures on its tidally-distorted
surface. Based upon its X-ray and optical properties, we consider this source
as the most likely X-ray counterpart to 3FGL J2039.6-5618, which we propose to
be a new redback system.Comment: 35 pages, 8 figures, accepted for publication on Astrophysical
Journa
Mild behavioral impairment in Parkinson's disease: Data from the Parkinson's disease cognitive impairment study (PACOS)
Neuropsychiatric symptoms (NPS) have been frequently described in Parkinson's disease (PD), even in the earliest stages of the disease. Recently the construct of mild behavioral impairment (MBI) has been proposed as an at-risk state for incident cognitive decline and dementia. The aim of the present study is to evaluate the prevalence and associated factors of MBI in PD. Cross-sectional data from 429 consecutive PD patients enrolled in the PArkinson's disease COgnitive impairment Study (PACOS) were included in the study. All subjects underwent neuropsychological assessment, according to the MDS Level II criteria. NPS were evaluated with the Neuropsychiatric Inventory. Multivariate logistic regression models were used to evaluate clinical and behavioral characteristics, which are associated with PD-MBI. The latter was ascertained in 361 (84.1%) subjects of whom 155 (36.1%) were newly diagnosed patients (disease duration ≥1 year) and 206 (48.0%) had a disease duration <1 year. Furthermore, 68 (15.9%) out of 429 subjects were PDw (without MBI). Across the MBI domains, Impulse Dyscontrol was significantly more prevalent among PD-MBI with disease duration <1 year than newly diagnosed patients. The frequency of Social Inappropriateness and Abnormal Perception significantly increased throughout the entire PD-MBI sample with increasing Hoehn andYahr (H&Y) stages. PD-MBI in newly diagnosed PDwas significantly associated with H&Y stage (OR 2.35, 95% CI 1.05-5.24) and marginally with antidepressant drug use (OR 2.94, 95% CI 0.91-9.47), while in patients with a disease duration >1 year was associated with UPDRS-ME (OR 3.37, 95% CI 1.41-8.00). The overall MBI frequency in the PACOS sample was 84% and 36% among newly diagnosed patients. The presence of MBI mainly related to motor impairment and disability
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Data assimilation for the Martian atmosphere using MGS Thermal Emission Spectrometer observations
From the introduction: Given the quantity of data expected from current and forthcoming spacecraft missions to Mars, it is now possible to use data assimilation as a means of atmospheric analysis for the first time for a planet other than the Earth. Several groups have described plans to develop assimilation schemes for Mars [Banfield et al., 1995; Houben, 1999; Lewis and Read, 1995; Lewis et al., 1996, 1997; Zhang et al., 2001]. Data assimilation is a technique for the analysis of atmospheric observations which combines currently valid information with prior knowledge from previous observations and dynamical and physical constraints, via the use of a numerical model. Despite the number of new missions, observations of the atmosphere of Mars in the near future are still likely to be sparse when compared to those of the Earth, perhaps
comprising one orbiter and a few surface stations at best
at any one time. Data assimilation is useful as a means
to extract the maximum information from such observations,
both by a form of interpolation in space and time
using model constraints and by the combination of information from different observations, e.g. temperature
profiles and surface pressure measurements which may
be irregularly distributed. The procedure can produce a
dynamically consistent set of meteorological fields and
can be used directly to test and to refine an atmospheric
model against observations
Effects of noise and confidence thresholds in nominal and metric Axelrod dynamics of social influence
We study the effects of bounded confidence thresholds and of interaction and
external noise on Axelrod's model of social influence. Our study is based on a
combination of numerical simulations and an integration of the mean-field
Master equation describing the system in the thermodynamic limit. We find that
interaction thresholds affect the system only quantitatively, but that they do
not alter the basic phase structure. The known crossover between an ordered and
a disordered state in finite systems subject to external noise persists in
models with general confidence threshold. Interaction noise here facilitates
the dynamics and reduces relaxation times. We also study Axelrod systems with
metric features, and point out similarities and differences compared to models
with nominal features. Metric features are used to demonstrate that a small
group of extremists can have a significant impact on the opinion dynamics of a
population of Axelrod agents.Comment: 15 pages, 12 figure
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