Amplitude enhancements in Antarctic MF radar echoes

Enhancements in the amplitude of returns from a medium-frequency (MF) radar at Davis, Antarctica, have been identified and their potential use as a measure of polar mesosphere summer echoes (PMSE) has been explored. A method for finding these enhancements has been applied to data spanning the period from mid-1995 to the end of 1997. The character of these enhancements on short and long timescales has been studied, and factors that may affect their detection have been considered. It has been found that they are short-lived (2 min or less being most common) and largely limited to the months around summer. Apart from describing the character of these amplitude enhancements, this study illustrates the potential pitfalls associated with identifying a proxy measure of PMSE.D. J. Murphy, R. A. Vincenthttp://cat.inist.fr/?aModele=afficheN&cpsidt=85383

Improving C=N bond reductions with (Cyclopentadienone)iron complexes: Scope and limitations

Herein, we broaden the application scope of (cyclo-pentadienone)iron complexes 1 in C=N bond reduction. The catalytic scope of pre-catalyst 1b, which is more active than the \u201cKn\uf6lker complex\u201d (1a) and other members of its family, has been expanded to the catalytic transfer hydrogenation (CTH) of a wider range of aldimines and ketimines, either pre-isolated or generated in situ. The kinetics of 1b-promoted CTH of ketimine S1 were assessed, showing a pseudo-first order profile, with TOF = 6.07 h\u20131 at 50 % conversion. Moreover, the chiral complex 1c and its analog 1d were employed in the enantioselective reduction of ketimines and reductive amination of ketones, giving fair to good yields and moderate enantioselectivity