N′-(5-Bromo-2-methoxy­benzyl­idene)-2-hydroxy­benzohydrazide

The title Schiff base compound, C15H13BrN2O3, is derived from the condensation of 5-bromo-2-methoxy­benzaldehyde with 2-hydroxy­benzohydrazide in an ethanol solution. The dihedral angle between the two aromatic rings is 6.9 (9)°. The meth­oxy group is coplanar with the attached ring [C—O—C—C = 3.1 (12)°]. An intra­molecular N—H⋯O hydrogen bond is observed. In the crystal structure, the mol­ecules are linked into chains along the [001] direction by inter­molecular O—H⋯N, O—H⋯O and C—H⋯O hydrogen bonds

Quantifying the effects of watershed subdivision scale and spatial density of weather inputs on hydrological simulations in a Norwegian Arctic watershed

The effects of watershed subdivisions on hydrological simulations have not been evaluated in Arctic conditions yet. This study applied the Soil and Water Assessment Tool and the threshold drainage area (TDA) technique to evaluate the impacts of watershed subdivision on hydrological simulations at a 5,913-km2 Arctic watershed, Målselv. The watershed was discretized according to four TDA scheme scales including 200, 2,000, 5,000, and 10,000 ha. The impacts of different TDA schemes on hydrological simulations in water balance components, snowmelt runoff, and streamflow were investigated. The study revealed that the complexity of terrain and topographic attributes altered significantly in the coarse discretizations: (1) total stream length (−47.2 to −74.6%); (2) average stream slope (−68 to −83%); and (3) drainage density (−24.2 to −51.5%). The spatial density of weather grid integration reduced from −5 to −33.33% in the coarse schemes. The annual mean potential evapotranspiration, evapotranspiration, and lateral flow slightly decreased, while areal rainfall, surface runoff, and water yield slightly increased with the increases of TDAs. It was concluded that the fine TDAs produced finer and higher ranges of snowmelt runoff volume across the watershed. All TDAs had similar capacities to replicate the observed tendency of monthly mean streamflow hydrograph, except overestimated/underestimated peak flows. Spatial variation of streamflow was well analyzed in the fine schemes with high density of stream networks, while the coarse schemes simplified this. Watershed subdivisions affected model performances, in the way of decreasing the accuracy of monthly streamflow simulation, at 60% of investigated hydro-gauging stations (3/5 stations) and in the upstream. Furthermore, watershed subdivisions strongly affected the calibration process regarding the changes in sensitivity ranking of 18 calibrated model parameters and time it took to calibrate

A Review of Hydrological Models Applied in the Permafrost-Dominated Arctic Region

The Arctic region is the most sensitive region to climate change. Hydrological models are fundamental tools for climate change impact assessment. However, due to the extreme weather conditions, specific hydrological process, and data acquisition challenges in the Arctic, it is crucial to select suitable hydrological model(s) for this region. In this paper, a comprehensive review and comparison of different models is conducted based on recently available studies. The functionality, limitations, and suitability of the potential hydrological models for the Arctic hydrological process are analyzed, including: (1) The surface hydrological models Topoflow, DMHS (deterministic modeling hydrological system), HBV (Hydrologiska Byråns Vattenbalansavdelning), SWAT (soil and water assessment tool), WaSiM (water balance simulation model), ECOMAG (ecological model for applied geophysics), and CRHM (cold regions hydrological model); and (2) the cryo-hydrogeological models ATS (arctic terrestrial simulator), CryoGrid 3, GEOtop, SUTRA-ICE (ice variant of the existing saturated/unsaturated transport model), and PFLOTRAN-ICE (ice variant of the existing massively parallel subsurface flow and reactive transport model). The review finds that Topoflow, HBV, SWAT, ECOMAG, and CRHM are suitable for studying surface hydrology rather than other processes in permafrost environments, whereas DMHS, WaSiM, and the cryo-hydrogeological models have higher capacities for subsurface hydrology, since they take into account the three phase changes of water in the near-surface soil. Of the cryo-hydrogeological models reviewed here, GEOtop, SUTRA-ICE, and PFLOTRAN-ICE are found to be suitable for small-scale catchments, whereas ATS and CryoGrid 3 are potentially suitable for large-scale catchments. Especially, ATS and GEOtop are the first tools that couple surface/subsurface permafrost thermal hydrology. If the accuracy of simulating the active layer dynamics is targeted, DMHS, ATS, GEOtop, and PFLOTRAN-ICE are potential tools compared to the other models. Further, data acquisition is a challenging task for cryo-hydrogeological models due to the complex boundary conditions when compared to the surface hydrological models HBV, SWAT, and CRHM, and the cryo-hydrogeological models are more difficult for non-expert users and more expensive to run compared to other models