Dimensional perturbation theory for vibration-rotation spectra of linear triatomic molecules

A very efficient large-order perturbation theory is formulated for the nuclear motion of a linear triatomic molecule. To demonstrate the method, all of the experimentally observed rotational energies, with values of $J$ almost up to 100, for the ground and first excited vibrational states of CO$_2$ and for the ground vibrational states of N$_2$O and of OCS are calculated. All coupling between vibration and rotation is included. The perturbation expansions reported here are rapidly convergent. The perturbation parameter is $D^{-1/2}$, where $D$ is the dimensionality of space. Increasing $D$ is qualitatively similar to increasing the angular momentum quantum number $J$. Therefore, this approach is especially suited for states with high rotational excitation. The computational cost of the method scales only as $JN_v^{5/3}$, where $N_v$ is the size of the vibrational basis set.Comment: submitted to Journal of Chemical Physics, 23 pages, REVTeX, no figure

On the concepts of radial and angular kinetic energies

We consider a general central-field system in D dimensions and show that the division of the kinetic energy into radial and angular parts proceeds differently in the wavefunction picture and the Weyl-Wigner phase-space picture. Thus, the radial and angular kinetic energies are different quantities in the two pictures, containing different physical information, but the relation between them is well defined. We discuss this relation and illustrate its nature by examples referring to a free particle and to a ground-state hydrogen atom.Comment: 10 pages, 2 figures, accepted by Phys. Rev.

The Heine-Stieltjes correspondence and the polynomial approach to the standard pairing problem

A new approach for solving the Bethe ansatz (Gaudin-Richardson) equations of the standard pairing problem is established based on the Heine-Stieltjes correspondence. For $k$ pairs of valence nucleons on $n$ different single-particle levels, it is found that solutions of the Bethe ansatz equations can be obtained from one (k+1)x(k+1) and one (n-1)x(k+1) matrices, which are associated with the extended Heine-Stieltjes and Van Vleck polynomials, respectively. Since the coefficients in these polynomials are free from divergence with variations in contrast to the original Bethe ansatz equations, the approach thus provides with a new efficient and systematic way to solve the problem, which, by extension, can also be used to solve a large class of Gaudin-type quantum many-body problems and to establish a new efficient angular momentum projection method for multi-particle systems.Comment: ReVTeX, 4 pages, no figur

Renormalization of the Inverse Square Potential

The quantum-mechanical D-dimensional inverse square potential is analyzed using field-theoretic renormalization techniques. A solution is presented for both the bound-state and scattering sectors of the theory using cutoff and dimensional regularization. In the renormalized version of the theory, there is a strong-coupling regime where quantum-mechanical breaking of scale symmetry takes place through dimensional transmutation, with the creation of a single bound state and of an energy-dependent s-wave scattering matrix element.Comment: 5 page

Quantum mechanics in multiply connected spaces

This paper analyses quantum mechanics in multiply connected spaces. It is shown that the multiple connectedness of the configuration space of a physical system can determine the quantum nature of physical observables, such as the angular momentum. In particular, quantum mechanics in compactified Kaluza-Klein spaces is examined. These compactified spaces give rise to an additional angular momentum which can adopt half-integer values and, therefore, may be identified with the intrinsic spin of a quantum particle.Comment: Latex 15 page

Fokker-Planck description of the transfer matrix limiting distribution in the scattering approach to quantum transport

The scattering approach to quantum transport through a disordered quasi-one-dimensional conductor in the insulating regime is discussed in terms of its transfer matrix \bbox{T}. A model of $N$ one-dimensional wires which are coupled by random hopping matrix elements is compared with the transfer matrix model of Mello and Tomsovic. We derive and discuss the complete Fokker-Planck equation which describes the evolution of the probability distribution of \bbox{TT}^{\dagger} with system length in the insulating regime. It is demonstrated that the eigenvalues of \ln\bbox{TT}^{\dagger} have a multivariate Gaussian limiting probability distribution. The parameters of the distribution are expressed in terms of averages over the stationary distribution of the eigenvectors of \bbox{TT}^{\dagger}. We compare the general form of the limiting distribution with results of random matrix theory and the Dorokhov-Mello-Pereyra-Kumar equation.Comment: 25 pages, revtex, no figure

Development of the applied mathematics originating from the group theory of physical and mathematical problems

This is the final report of a three-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). Group theoretical methods are a powerful tool both in their applications to mathematics and to physics. The broad goal of this project was to use such methods to develop the implications of group (symmetry) structures underlying models of physical systems, as well as to broaden the understanding of simple models of chaotic systems. The main thrust was to develop further the complex mathematics that enters into many-particle quantum systems with special emphasis on the new directions in applied mathematics that have emerged and continue to surface in these studies. In this area, significant advances in understanding the role of SU(2) 3nj-coefficients in SU(3) theory have been made and in using combinatoric techniques in the study of generalized Schur functions, discovered during this project. In the context of chaos, the study of maps of the interval and the associated theory of words has led to significant discoveries in Galois group theory, to the classification of fixed points, and to the solution of a problem in the classification of DNA sequences