A review of China’s resources of lithium in coal seams

Lithium gains an increasing importance in new energy vehicles and stationary energy storage, and development and utilization of lithium mines has attracted great attention around the world. In addition to the traditional lithium resources, lithium resources in coal seams have great potential in industrial application. Therefore, how to develop and utilize them is strategically significant for guaranteeing supply of lithium resources in China and promoting clean energy transformation. This paper summarizes the metallogenic ages, occurrence, enrichment factors, availability of lithium resources in coal seams in China. Conclusion are obtained as follows. i. coal-hosted lithium deposits discovered in China so far mainly occur in the Carboniferous-Permian strata of North China. They are less concentrated in smaller range in the Permian strata of Qilian-Qinling. ii. In China, coal-hosted lithium is mainly enriched in aluminum-bearing minerals. Lithium in coal seams mainly occurs in the inorganic matter, and some occurs in the organic matter. iii. Lithium enrichment in coal seams is caused by stable supply of aluminum and lithium-bearing minerals and special structural and geological factors. iv. According to China’s national standards on grades of lithium content in coal seams, the metallogenic belts of lithium in coal seams at the southern foothill of Yin Shan and in Qilian-Qinling have the potential of lithium development and extraction, covering Junger mining area in Inner Mongolia, and Pingshuo and Ningwu mining areas in Shanxi

Visualization of ultrasonic wave field by stroboscopic polarization selective imaging

A stroboscopic method based on polarization selective imaging is proposed for dynamic visualization of ultrasonic waves propagating in a transparent medium. Multiple independent polarization parametric images were obtained, which enabled quantitative evaluation of the distribution of the ultrasonic pressure in quartz. In addition to the detection of optical phase differences δ in conventional photo-elastic techniques, the azimuthal angle φ and the Stokes parameter S2 of the polarized light are found to be highly sensitive to the wave-induced refraction index distribution, opening a new window on ultrasonic field visualization

One-Step Hydrothermal Synthesis of Highly Fluorescent MoS2 Quantum Dots for Lead Ion Detection in Aqueous Solutions

Lead ions in water are harmful to human health and ecosystems because of their high toxicity and nondegradability. It is important to explore effective fluorescence probes for Pb2+ detection. In this work, surface-functionalized molybdenum disulfide quantum dots (MoS2 QDs) were prepared using a hydrothermal method, and ammonium tetrathiomolybdate and glutathione were used as precursors. The photoluminescence quantum yield of MoS2 QDs can be improved to 20.4%, which is higher than that for MoS2 QDs reported in current research. The as-prepared MoS2 QDs demonstrate high selectivity and sensitivity for Pb2+ ions, and the limit of detection is 0.056 μM. The photoluminescence decay dynamics for MoS2 QDs in the presence of Pb2+ ions in different concentrations indicate that the fluorescence quenching originated from nonradiative electron transfer from excited MoS2 QDs to the Pb2+ ion. The prepared MoS2 QDs have great prospect and are expected to become a good method for lead ion detection

Visualization of ultrasonic wave field by stroboscopic polarization selective imaging

A stroboscopic method based on polarization selective imaging is proposed for dynamic visualization of ultrasonic waves propagating in a transparent medium. Multiple independent polarization parametric images were obtained, which enabled quantitative evaluation of the distribution of the ultrasonic pressure in quartz. In addition to the detection of optical phase differences δ in conventional photo-elastic techniques, the azimuthal angle φ and the Stokes parameter S2 of the polarized light are found to be highly sensitive to the wave-induced refraction index distribution, opening a new window on ultrasonic field visualization.status: publishe

Nonmagnetic impurity effect on magnetic correlation in the triangular-lattice antiferromagnet Ba

The nonmagnetic impurity effects on the triangular-lattice antiferromagnet (TLAF) Ba3Mn1−xZnxSb2O9 ($0\le x \le 0.16$ ) by Zn2+ ($S =0$ ) dilutions are investigated based on magnetic susceptibility, specific heat and electron spin resonance (ESR) measurements. The ac susceptibility and specific heat result reveal that the two-dimensional (2D) antiferromagnetic (AFM) ground state is stable rather than forming a spin-glass (SG) phase for Zn2+ substitution up to $x=0.16$ , where the AFM transition temperature (TN) shifts slowly from 10.2 K ($x = 0$ ) to 8.2 K ($x = 0.16$ ). For all samples, the divergence of the temperature-dependent linewidth of ESR can be well described in terms of the Berezinskii-Kosterlitz-Thouless (BKT) scenario. The evolution of ESR spectra suggests that the nonmagnetic impurity does not induce magnetic defects decoupled with AFM matrix but rather change the bulk AFM properties

Microstructure Modulation of Zn Doped VO₂(B) Nanorods with Improved Electrochemical Properties towards High Performance Aqueous Batteries

Vanadium dioxide with monoclinic structure is theoretically a promising layered cathode material for aqueous metal-ion batteries due to its excellent specific capacity. However, its poor cycling stability limits its application as an electrode material. In this study, a series of Zn-doped VO2 (V1−xZnxO2) nanorods were successfully fabricated by the technology of one-step hydrothermal synthesis. The XRD result indicated that there was a slight lattice distortion caused by doped Zn2+ with a larger ion radius. The positron lifetime spectrum showed that there were vacancy cluster defects in all the samples. The electrochemical measurement demonstrated the enhancement of the specific capacitance of V1−xZnxO2 electrodes compared with the undoped sample. In addition, the discharge capacitance of the sample remained around 86% after 1000 charge/discharge cycles. This work proves that Zn2+ doping is a valid tactic for the application of nano-VO2(B) in energy storage electrode materials

Product and Metal Stocks Accumulation of China's Megacities: Patterns, Drivers, and Implications

The rapid urbanization in China since the 1970s has led to an exponential growth of metal stocks (MS) in use in cities. A retrospect on the quantity, quality, and patterns of these MS is a prerequisite for projecting future metal demand, identifying urban mining potentials of metals, and informing sustainable urbanization strategies. Here, we deployed a bottom up stock accounting method to estimate stocks of iron, copper, and aluminum embodied in 51 categories of products and infrastructure across 10 Chinese megacities from 1980 to 2016. We found that the MS in Chinese megacities had reached a level of 2.6-6.3 t/cap (on average 3.7 t/cap for iron, 58 kg/cap for copper, and 151 kg/cap for aluminum) in 2016, which still remained behind the level of western cities or potential saturation level on the country level (e.g., approximately 13 t/cap for iron). Economic development was identified as the most powerful driver for MS growth based on an IPAT decomposition analysis, indicating further increase in MS as China's urbanization and economic growth continues in the next decades. The latecomer cities should therefore explore a wide range of strategies, from urban planning to economy structure to regulations, for a transition toward more "metal-efficient" urbanization pathways