Relationship between surface temperatures and seismic activity at Vulcano, Aeolian Island (Italy)

Time-series acquired during last years by surface monitoring parameters are compared, and the results are discussed, following a theoretical approach. Surface parameters are fluid temperature, soil temperatures and seismic activity at La Fossa of Vulcano. Discussed periods are 1998 and from 2004 to 2007, when time relationship between changes of the heat flow from the ground and seismic activity, resulted worth noting. Earthquakes originating in the area of Vulcano are associated with both fracturing and degassing mechanisms. The formers are related to the activity of tectonic structures; while the latter are connected to fluid dynamics within the interior of the volcanic apparatus. In November 1998 seismic activity at La Fossa sharply increased: Five events were registered, with seismic signals of typical faulting earthquakes, triggered by mechanism of shear fracturing and focal depths ranging 1-4 km. Fumaroles temperatures, recorded by continuous monitoring system of INGV - Palermo, showed a growing trend since October to November 1998, highlighting a big increase of heat transfer during the period, and also the soil temperature, out of the fumaroles field showed a marked increase. Fumaroles temperatures heralded the increase of heat and energy flow during a pre-seismic period of about 1 month. The transient variation of surface release reflect an excited state of the system and may have many different causes, not directly related to the magma. Indeed, stress drops generated by small fracturing earthquakes, introduce a significant perturbation in the system resulting in a relevant production of mass and energy flow. Until these flows counteract every stress gradient, they support stationary state of the system. The observed time relationships only allow a qualitative discussion about cause and effects, but doesn’t allow any quantitative evaluation. Pressure transients generate anomalies (flows of matter, differential in heat flows, chemical reaction rates) whose time frame is specific, depending on many possible processes and path-ways. Fluid phases, along fumarolic conduits, reach the surface faster than the co-genetic earthquake, as the earthquake is embedded in a strain transient that broadly exceeds the time-space frame of the seismic transient (Lomnitz, 1994). On the other hand, in a volcano-tectonic context, different energy flows can either be a cause, either an effect of perturbation, depending on depth of their primary source. Thus, in some instances the strain transient related to local earthquakes produces anomalous chemical flows, while, in other instances the local seismic activity may be produced by chemical flows from the magmatic source. Following a period of lower energy release, other 3 anomalous periods were observed from November 2004, either in the seismic release and in the surface heat flow, even out from fumaroles. So far, the monitored sites resulted very sensitive to minor perturbations of the system. The comparative analysis of different time-series supplies information related to perturbations of the state variables, useful to verify conceptual framework and to better define “classical” and “new” monitoring techniques for volcanic, as well as seismic surveillance

Alternate proof of the Rowe-Rosensteel proposition and seniority conservation

For a system with three identical nucleons in a single-$j$ shell, the states can be written as the angular momentum coupling of a nucleon pair and the odd nucleon. The overlaps between these non-orthonormal states form a matrix which coincides with the one derived by Rowe and Rosensteel [Phys. Rev. Lett. {\bf 87}, 172501 (2001)]. The propositions they state are related to the eigenvalue problems of the matrix and dimensions of the associated subspaces. In this work, the propositions will be proven from the symmetric properties of the $6j$ symbols. Algebraic expressions for the dimension of the states, eigenenergies as well as conditions for conservation of seniority can be derived from the matrix.Comment: 9 pages, no figur

Competition of different coupling schemes in atomic nuclei

Shell model calculations reveal that the ground and low-lying yrast states of the $N=Z$ nuclei $^{92}_{46}$Pd and $^{96}$Cd are mainly built upon isoscalar spin-aligned neutron-proton pairs each carrying the maximum angular momentum J=9 allowed by the shell $0g_{9/2}$ which is dominant in this nuclear region. This mode of excitation is unique in nuclei and indicates that the spin-aligned pair has to be considered as an essential building block in nuclear structure calculations. In this contribution we will discuss this neutron-proton pair coupling scheme in detail. In particular, we will explore the competition between the normal monopole pair coupling and the spin-aligned coupling schemes. Such a coupling may be useful in elucidating the structure properties of $N=Z$ and neighboring nuclei.Comment: 10 pages, 7 figures, 1 table. Proceedings of the Conference on Advanced Many-Body and Statistical Methods in Mesoscopic Systems, Constanta, Romania, June 27th - July 2nd 2011. To appear in Journal of Physics: Conference Serie

Temperature dependent BCS equations with continuum coupling

The temperature dependent BCS equations are modified in order to include the contribution of the continuum single particle states. The influence of the continuum upon the critical temperature corresponding to the phase transition from a superfluid to a normal state and upon the behaviour of the excitation energy and of the entropy is discussed.Comment: 9 pages, 3 figures, to appear in Phys. Rev.

Late Palaeozoic tectonics in Central Mediterranean: a reappraisal

A revision of late Palaeozoic tectonics recorded in Tuscany, Calabria and Corsica is here presented. We propose that, in Tuscany, upper Carboniferous-Permian shallow-marine to continental sedimentary basins, characterized by unconformities and abrupt changes in sedimentary facies, coal-measures, red fanglomerate deposits and felsic magmatism, may be related with a transtensional setting where upper-crustal splay faults are linked with a mid-crustal shear zone. The remnants of the latter can be found in the deep-well logs of Pontremoli and Larderello-Travale in northern and southern Tuscany respectively. In Calabria (Sila, Serre and Aspromonte), a continuous pre-Mesozoic crustal section is exposed, where the lower-crustal portion mainly includes granulites and migmatitic paragneisses, together with subordinate marbles and metabasites. The mid-crustal section, up to 13 km-thick, includes granitoids, tonalitic to granitic in composition, emplaced between 306 and 295 Ma. They were progressively deformed during retrograde extensional shearing, with a final magmatic activity, between 295 ± 1 and 277 ± 1 Ma, when shallower dykes were emplaced in a transtensional regime. The section is completed by an upper crustal portion, mainly formed by a Palaeozoic sedimentary succession deformed as a low-grade fold and thrust belt, and locally overlaying mediumgrade paragneiss units. As a whole, these features are reminiscent of the nappe zone domains of the Sardinia Variscan Orogen. In Corsica, besides the well-known effusive and intrusive Permian magmatism of the “Autochthonous” domain, the Alpine Santa Lucia Nappe exposes a kilometer-scale portion of the Permian lower to mid-crust, exhibiting many similarities to the Ivrea Zone. The distinct Mafic and Granitic complexes characterizing this crustal domain are juxtaposed through an oblique-slip shear zone named Santa Lucia Shear Zone. Structural and petrological data witness the interaction between magmatism, metamorphism and retrograde shearing during Permian, in a temperature range of c. 800–400 °C. We frame the outlined paleotectonic domains within a regional-scale, strain–partitioned, tectonic setting controlled by a first-order transcurrent/transtensional fault network that includes a westernmost fault (Santa Lucia Fault) and an easternmost one (East Tuscan Fault), with intervening crustal domains affected by extensional to transtensional deformation. As a whole, our revision allows new suggestions for a better understanding of the tectonic framework and evolution of the Central Mediterranean during the late Palaeozoic

In vitro fermentation and chemical characteristics of mediterranean by-products for swine nutrition

The purpose of the study is to determine the nutritional characteristics of some by-products derived from fruit juice and olive oil production to evaluate their use in pig nutrition. Five by-products of citrus fruit (three citrus fruit pulp and two molasses) and three by-products of olive oil (olive cake) obtained by different varieties are analysed for chemical composition. The fermentation characteristics are evaluated in vitro using the gas production technique with swine faecal inoculum. All the citrus by-products are highly fermentable, producing gas and a high amount of short-chain fatty acids. The fermentation kinetics vary when comparing pulps and molasses. Citrus fruit pulps show lower and slower fermentation rates than molasses. The olive oil by-products, compared to citrus fruits ones, are richer in NDF and ADL. These characteristics negatively affect all the fermentation parameters. Therefore, the high concentration of fiber and lipids represents a key aspect in the nutrition of fattening pigs. The preliminary results obtained in this study confirm that the use of by-products in pig nutrition could represent a valid opportunity the reduce the livestock economic cost and environmental impact

Au/CeO2 Photocatalyst for the Selective Oxidation of Aromatic Alcohols in Water under UV, Visible and Solar Irradiation

Au nanoparticles supported on CeO2 have been prepared and investigated as photocatalysts for the photocatalytic selective oxidation of benzyl alcohol and 4-methoxybenzyl alcohol to the correspondent benzaldehydes, in aqueous suspensions and room conditions under UV, visible and natural solar light irradiation. Au nanoparticles have been supported by impregnation (1 and 3 wt.%) on two types of CeO2 (i.e., a commercial one and a home prepared oxide obtained in the presence of NaOH as precipitation agent). The Au impregnated samples showed strong visible radiation absorption at 565–570 nm associated to localized surface plasmon resonance (LSPR). The bare CeO2 samples are activated by UV light and resulted virtually inactive under visible irradiation, whereas the presence of Au improved both the conversion of the alcohols and the selectivity of the reaction towards the aldehyde, giving rise to good results, particularly under visible and natural solar light irradiation. The activity of the materials increased by increasing the Au content

Synergistic effect in Ag/Fe-MnO2 catalysts for ethanol oxidation

Here we report the synergistic effect of OMS-2 catalysts tested in ethanol oxidation, and the effects produced by both the addition of an Fe modifier in the catalyst preparation stage, and the introduction of Ag on its surface by the impregnation method. To analyze the action of each component, the Fe-modified, Ag-containing OMS-2 catalysts with different Mn/Fe ratios were prepared. Combined XPS and XRF elemental analysis confirms the states and distribution of the Ag- and Fe-containing species between the surface and bulk of the OMS-2 catalysts, which form highly dispersed Ag species on the surface of 0.05Fe–OMS-2, and are also incorporated into the OMS-2 crystalline lattice. The cooperative action of Ag and Fe modifiers improves both reoxidation ability (TPO results) and the amount of adsorbed oxygen species on the catalyst surface. The introduction of Ag to the OMS-2 and 0.05 Fe–OMS-2 surface allows a high level of activity (T80 = 150–155 °C) and selectivity (SAc80 = 93%) towards the acetaldehyde formation

Coherence features of the spin-aligned neutron-proton pair coupling scheme

The seniority scheme has been shown to be extremely useful for the classification of nuclear states in semi-magic nuclei. The neutron-proton ($np$) correlation breaks the seniority symmetry in a major way. As a result, the corresponding wave function is a mixture of many components with different seniority quantum numbers. In this contribution we show that the $np$ interaction may favor a new kind of coupling in $N=Z$ nuclei, i.e., the so-called isoscalar spin-aligned $np$ pair mode. Shell model calculations reveal that the ground and low-lying yrast states of the $N = Z$ nuclei $^{92}$Pd and $^{96}$Cd may mainly be built upon such spin-aligned $np$ pairs each carrying the maximum angular momentum $J = 9$ allowed by the shell $0g_{9/2}$ which is dominant in this nuclear region.Comment: 5 pages, 4 figues, Proceedings of the Nordic Conference on Nuclear Physics 2011. To appear in Physica Scripta

Catalytic Dehydration of Fructose to 5-Hydroxymethylfurfural in Aqueous Medium over Nb2O5-Based Catalysts

The catalytic dehydration of fructose to 5-hydroxymethylfurfural (HMF) in water was performed in the presence of pristine Nb2O5 and composites containing Nb and Ti, Ce or Zr oxides. In all experiments, fructose was converted to HMF using water as the solvent. The catalysts were characterized by powder X-ray diffraction, scanning electron microscopy, N2 physical adsorption, infrared and Raman spectroscopy and temperature-programmed desorption of NH3. Experimental parameters such as fructose initial concentration, volume of the reacting suspension, operation temperature, reaction time and amount of catalyst were tuned in order to optimize the catalytic reaction process. The highest selectivity to HMF was ca. 80% in the presence of 0.5 g\ub7L 121 of bare Nb2O5, Nb2O5-TiO2 or Nb2O5-CeO2 with a maximum fructose conversion of ca. 70%. However, the best compromise between high conversion and high selectivity was reached by using 1 g\ub7L 121 of pristine Nb2O5. Indeed, the best result was obtained in the presence of Nb2O5, with a fructose conversion of 76% and a selectivity to HMF of 75%, corresponding to the highest HMF yield (57%). This result was obtained at a temperature of 165\ub0 in an autoclave after three hours of reaction by using 6 mL of 1 M fructose suspension with a catalyst amount equal to 1 g\ub7L 121