New Keck Observations of Lithium in Very Metal-poor Stars

Lithium abundances have been determined in more than 100 metal-poor halo stars both in the field and in clusters. From these data we find trends of Li with both temperature and metallicity and a real dispersion in Li abundances in the Spite Li plateau. We attribute this dispersion primarily to Li depletion (presumably due to extra mixing induced by stellar rotation) and to Galactic chemical evolution. We derive a primordial Li of 2.44 $\pm$0.18 for A(Li)$_p$ = log N(Li/H) + 12.00. This agrees with the Li abundances predicted by the $WMAP$ results. For stars cooler than the Li plateau we have evidence that Li depletion sets in at hotter temperatures for the higher metallicity stars than for the low-metal stars. This is the opposite sense of predictions from stellar models. The smooth transition of the Li content from the Li plateau stars to the cool stars adds weight to the inference of Li depletion in the plateau stars.Comment: Invited talk for IAU Symposium 228 "From Lithium to Uranium..." held in Paris in May, 2005. 6 pages, 6 figure

The Synthesis and Characterization of New, Robust Titanium (IV) Scorpionate Complexes

Titanium complexes possessing sterically encumbered ligands have allowed for the preparation of reactive moieties (imido, alkylidene and alkylidyne species) relevant to reactions such as olefin polymerization and alkyne hydroamination. For this reason, we have targeted robust scorpionate ancillary ligands to support reactive titanium centers. Thus, a series of titanium complexes were synthesized using an achiral oxazoline-based scorpionate ligand, tris(4,4-dimethyl-2-oxazolinyl)phenyl borate [To^M^]^-^ as well as the related chiral ligand, tris(4-isopropyl-2-oxazolinyl)phenyl borate [To^P^]^-^. The complex [Ti(κ^3^- To^M^)Cl~3~] was prepared in moderate yield (43%) by the rapid (<1 min at room temperature) reaction of Li[To^M^] and TiCl~4~ in methylene chloride; this new compound was characterized by ^1^H NMR spectroscopy as the expected C~3v~-symmetric species. One route to Ti (IV) alkyls involves salt metathesis; accordingly, syntheses of [To^M^]Ti alkyl complexes by interaction of [Ti(κ^3^-To^M^)Cl~3~] and one or three equivalents of alkylating agents, such as benzyl potassium (KCH~2~C~6~H~5~), trimethylsilylmethyl
lithium (LiCH~2~Si(CH~3~) ~3~), or neopentyl lithium (LiCH~2~C(CH~3~)~3~) are currently under investigation. The complexes [Ti(=NBut) (κ~3~-To^M^)(Cl)(Bu^t^py)] (Bu^t^py=4 tert-butylpyridine) and [Ti(=NBu^t^) (κ~3~-To^P^)(Cl)(Bu^t^py)] were synthesized by reaction of the known Ti imido [Ti(=NBu^t^)(Cl)~2~(Bu^t^py)~2~] with Li[To^M^] or Li[To^P^], respectively, by stirring overnight in methylene chloride at ambient temperature. The complexes were identified using ^1^H NMR spectroscopy, ^1^H-^13^C HMQC and ^1^H-^15^N HMBC correlation experiments

Beryllium in Ultra-Lithium-Deficient Halo Stars - The Blue Straggler Connection

There are nine metal-deficient stars that have Li abundances well below the Li plateau that is defined by over 100 unevolved stars with temperatures above 5800 K and values of [Fe/H] $<$ $-$1.0. Abundances of Be have been determined for most of these ultra-Li-deficient stars in order to investigate the cause of the Li deficiencies. High-resolution and high signal-to-noise spectra have been obtained in the Be II spectral region near 3130 \AA for six ultra-Li-deficient stars with the Keck I telescope and its new uv-sensitive CCD on the upgraded HIRES. The spectrum synthesis technique has been used to determine Be abundances. All six stars are found to have Be deficiencies also. Two have measurable - but reduced - Be and four have only upper limits on Be. These results are consistent with the idea that these Li- and Be-deficient stars are analogous to blue stragglers. The stars have undergone mass transfer events (or mergers) which destroy or dilute both Li and Be. The findings cannot be matched by the models that predict that the deficiencies are due to extra-mixing in a subset of halo stars that were initially rapid rotators, with the possible exception of one star, G 139-8. Because the ultra-Li-deficient stars are also Be-deficient, they appear to be genuine outliers in population of halo stars used to determine the value of primordial Li; they no longer have the Li in their atmospheres that was produced in the Big Bang.Comment: 17 pages of text, 12 figures, 3 tables Submitted to Ap

Lithium abundances in extremely metal-poor turn-off stars

We discuss the current status of the sample of Lithium abundances in extremely metal poor (EMP) turn-off (TO) stars collected by our group, and compare it with the available literature results. In the last years, evidences have accumulated of a progressive disruption of the Spite plateau in stars of extremely low metallicity. What appears to be a flat, thin plateau above [Fe/H]\sim-2.8 turns, at lower metallicities, into a broader distribution for which the plateau level constitutes the upper limit, but more and more stars show lower Li abundances. The sample we have collected currently counts abundances or upper limits for 44 EMP TO stars between [Fe/H]=-2.5 and -3.5, plus the ultra-metal poor star SDSS J102915+172927 at [Fe/H]=-4.9. The "meltdown" of the Spite plateau is quite evident and, at the current status of the sample, does not appear to be restricted to the cool end of the effective temperature distribution. SDSS J102915+172927 displays an extreme Li depletion that contrasts with its otherwise quite ordinary set of [X/Fe] ratios.Comment: 6 pages, 4 figures, proceedings of the "Lithium in the Cosmos" conference, Paris, 27-29 February 201

Comparison of Body Composition Measurements using a New Caliper, Two Established Calipers, Hydrostatic Weighing, and BodPod

Purposes: (1) To compare the Lafayette Instruments (LI) skinfold caliper to the Lange (L) and Harpenden (H) calipers using a diverse subject population. (2) To determine the validity of the LI caliper in a subset of subjects by comparing body compositions from skinfold thicknesses to those measured by hydrostatic weighing (HW) and air displacement plethysmography (ADP). (3) To compare measurements obtained by experienced (EX) and inexperienced (IX) technicians using all three calipers. Methods: Skinfold measurements were performed by both EX and IX technicians using three different calipers on 21 younger (21.2 ± 1.5 yrs) and 20 older (59.2 ± 4 yrs) subjects. Body compositions were calculated using the Jackson-Pollock seven-site and three-site formulas. HW and ADP tests were performed on a subset of subjects (10 younger, 10 older). Results: No significant differences existed between LI and L or H when measurements were made by EX. Further, the LI-EX measurements were highly correlated to both H-EX and L-EX. No significant differences existed in the subgroup between LI-EX and HW or ADP. Skinfold determinations made by EX and IX were similar. Conclusions: Similar body compositions determined using LI, H, and L suggest that LI determines body composition as effectively as H and L. High correlations between the three calipers support this notion. Similar results between LI and HW/ADP subgroup suggest that the LI caliper may be a valid method of measuring body composition. Overall, performance by IX was similar to EX and suggests similar ease of use for all three calipers

Structural and optical properties of MOCVD AllnN epilayers

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Environmental advertising in China and the USA: the desire to go green

Book Review Environmental advertising in China and the USA: the desire to go green, by Xinghua Li, London and New York, NY, Routledge, 2016, 158 pp., £90.00 (hardback), ISBN 978-415-74413-