Achirality in the low temperature structure and lattice modes of tris(acetylacetonate)iron(iii)

Tris(acetylacteonate) iron(III) is a relatively ubiquitous mononuclear inorganic coordination complex. The bidentate nature of the three acetylacteonate ligands coordinating around a single centre inevitably leads to structural isomeric forms, however whether or not this relates to chirality in the solid state has been questioned in the literature. Variable temperature neutron diffraction data down to T = 3 K, highlights the dynamic nature of the ligand environment, including the motions of the hydrogen atoms. The Fourier transform of the molecular dynamics simulation based on the experimentally determined structure was shown to closely reproduce the low temperature vibrational density of states obtained using inelastic neutron scattering

Macroscopic heat release in a molecular solar thermal energy storage system

The development of solar energy can potentially meet the growing requirements for a global energy system beyond fossil fuels, but necessitates new scalable technologies for solar energy storage. One approach is the development of energy storage systems based on molecular photoswitches, so-called molecular solar thermal energy storage (MOST). Here we present a novel norbornadiene derivative for this purpose, with a good solar spectral match, high robustness and an energy density of 0.4 MJ kg -1 . By the use of heterogeneous catalyst cobalt phthalocyanine on a carbon support, we demonstrate a record high macroscopic heat release in a flow system using a fixed bed catalytic reactor, leading to a temperature increase of up to 63.4 °C (83.2 °C measured temperature). Successful outdoor testing shows proof of concept and illustrates that future implementation is feasible. The mechanism of the catalytic back reaction is modelled using density functional theory (DFT) calculations rationalizing the experimental observations

The solar WIND and suprathermal ion composition investigation on the WIND spacecraft

The Solar Wind and Suprathermal Ion Composition Experiment (SMS) on WIND is designed to determine uniquely the elemental, isotopic, and ionic-charge composition of the solar wind, the temperatures and mean speeds of all major solar-wind ions, from H through Fe, at solar wind speeds ranging from 175 kms −1 (protons) to 1280 kms −1 (Fe +8 ), and the composition, charge states as well as the 3-dimensional distribution functions of suprathermal ions, including interstellar pick-up He + , of energies up to 230 keV/e. The experiment consists of three instruments with a common Data Processing Unit. Each of the three instruments uses electrostatic analysis followed by a time-of-flight and, as required, an energy measurement. The observations made by SMS will make valuable contributions to the ISTP objectives by providing information regarding the composition and energy distribution of matter entering the magnetosphere. In addition SMS results will have an impact on many areas of solar and heliospheric physics, in particular providing important and unique information on: (i) conditions and processes in the region of the corona where the solar wind is accelerated; (ii) the location of the source regions of the solar wind in the corona; (iii) coronal heating processes; (iv) the extent and causes of variations in the composition of the solar atmosphere; (v) plasma processes in the solar wind; (vi) the acceleration of particles in the solar wind; and (vii) the physics of the pick-up process of interstellar He as well as lunar particles in the solar wind, and the isotopic composition of interstellar helium.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/43776/1/11214_2004_Article_BF00751327.pd

Piezo is essential for amiloride-sensitive stretch-activated mechanotransduction in larval Drosophila dorsal bipolar dendritic sensory neurons

Date of Acceptance: 05/06/2015Peer reviewedPublisher PD