Surface structure of thin asymmetric PS-b-PMMA diblock copolymers investigated by atomic force microscopy

Asymmetric poly(styrene-b-methyl methacrylate) (PS-b-PMMA) diblock copolymers of molecular weight M-n = 29,700g mol(-1) (M-PS = 9300 g mol(-1) M-PMMA = 20,100 g mol(-1), PD = 1.15, chi(PS) = 0.323, chi(PMMA) = 0.677) and M-n = 63,900 g mol(-1) (M-PS = 50,500 g mol(-1), M-PMMA = 13,400 g mol(-1), PD = 1.18, chi(PS) = 0.790, chi(PMMA) = 0.210) were prepared via reversible addition-fragmentation chain transfer (RAFT) polymerization. Atomic force microscopy (AFM) was used to investigate the surface structure of thin films, prepared by spin-coating the diblock copolymers on a silicon substrate. We show that the nanostructure of the diblock copolymer depends on the molecular weight and volume fraction of the diblock copolymers. We observed a perpendicular lamellar structure for the high molar mass sample and a hexagonal-packed cylindrical patterning for the lower molar mass one. Small-angle X-ray scattering investigation of these samples without annealing did not reveal any ordered structure. Annealing of PS-b-PMMA samples at 160 degrees C for 24 h led to a change in surface structure

Recent sanitary progress in Paris

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The automated array assembly task of the low-cost silicon solar array project, phase 2

Several specific processing steps as part of a total process sequence for manufacturing silicon solar cells were studied. Ion implantation was identified as the preferred process step for impurity doping. Unanalyzed beam ion implantation was shown to have major cost advantages over analyzed beam implantation. Further, high quality cells were fabricated using a high current unanalyzed beam. Mechanically masked plasma patterning of silicon nitride was shown to be capable of forming fine lines on silicon surfaces with spacings between mask and substrate as great as 250 micrometers. Extensive work was performed on advances in plated metallization. The need for the thick electroless palladium layer was eliminated. Further, copper was successfully utilized as a conductor layer utilizing nickel as a barrier to copper diffusion into the silicon. Plasma etching of silicon for texturing and saw damage removal was shown technically feasible but not cost effective compared to wet chemical etching techniques

Processing experiments on non-Czochralski silicon sheet

A program is described which supports and promotes the development of processing techniques which may be successfully and cost-effectively applied to low-cost sheets for solar cell fabrication. Results are reported in the areas of process technology, cell design, cell metallization, and production cost simulation

The evaluation of Education Maintenance Allowance Pilots: three years' evidence: a quantitative evaluation

This is the third report of the longitudinal quantitative evaluation of Education Maintenance Allowance (EMA) pilots and the first since the government announced that EMA is to be rolled out nationally from 2004. The evaluation was commissioned in 1999, by the Department for Education and Skills (DfES) from a consortium of research organisations, led by the Centre for Research in Social Policy (CRSP) and including the National Centre for Social Research, the Institute for Fiscal Studies (IFS) and the National Institute for Careers Education and Counselling (NICEC). The statistical evaluation design is a longitudinal cohort study involving large random sample surveys of young people (and their parents) in 10 EMA pilot areas and eleven control areas. Two cohorts of young people were selected from Child Benefit records. The first cohort of young people left compulsory schooling in the summer of 1999 and they, and their parents, were interviewed between October 1999 and April 2000 (Year 12 interview). A second interview was carried out with these young people between October 2000 and April 2001 (Year 13 interview). The second cohort left compulsory education the following summer of 2000 and young people, and their parents, were first interviewed between October 2000 and April 2001. The report uses both propensity score matching (PSM) and descriptive techniques, each of which brings their own particular strengths to the analysis

Condition index monitoring supports conservation priorities for the protection of threatened grass-finch populations

Conservation agencies are often faced with the difficult task of prioritizing what recovery actions receive support. With thenumber of species under threat of decline growing globally, research that informs conservation priorities is greatly needed. Therelative vulnerability of cryptic or nomadic species is often uncertain, because populations are difficult to monitor and localpopulations often seem stable in the short term. This uncertainty can lead to inaction when populations are in need of protection.We tested the feasibility of using differences in condition indices as an indication of population vulnerability to decline forrelated threatened Australian finch sub-species. The Gouldian finch represents a relatively well-studied endangered species,which has a seasonal and site-specific pattern of condition index variation that differs from the closely related non-declininglong-tailed finch. We used Gouldian and long-tailed finch condition variation as a model to compare with lesser studied, threatenedstar and black-throated finches. We compared body condition (fat and muscle scores), haematocrit and stress levels (corticosterone) among populations, seasons and years to determine whether lesser studied finch populations matched the modelof an endangered species or a non-declining species. While vulnerable finch populations often had lower muscle and higher fatand corticosterone concentrations during moult (seasonal pattern similar to Gouldian finches), haematocrit values did not differamong populations in a predictable way. Star and black-throated finch populations, which were predicted to be vulnerableto decline, showed evidence of poor condition during moult, supporting their status as vulnerable. Our findings highlight howmeasures of condition can provide insight into the relative vulnerability of animal and plant populations to decline and willallow the prioritization of efforts towards the populations most likely to be in jeopardy of extinctio

Staving off extinction – more than luck and fate

National Environmental Science Programme Threatened Species Recovery Hu

Precision Southern Hemisphere pulsar VLBI astrometry: techniques and results for PSR J1559-4438

We describe a data reduction pipeline for VLBI astrometric observations of pulsars, implemented using the ParselTongue AIPS interface. The pipeline performs calibration (including ionosphere modeling), phase referencing with proper accounting of reference source structure, amplitude corrections for pulsar scintillation, and position fitting to yield the position, proper motion and parallax. The optimal data weighting scheme to minimize the total error budget of a parallax fit, and how this scheme varies with pulsar parameters such as flux density, is also investigated. The robustness of the techniques employed are demonstrated with the presentation of the first results from a two year astrometry program using the Australian Long Baseline Array (LBA). The parallax of PSR J1559-4438 is determined to be 0.384 +- 0.081 mas (1 sigma), resulting in a distance estimate of 2600 pc which is consistent with earlier DM and HI absorption estimates.Comment: 30 pages, 8 figures, submitted to Ap