Freetown's Mudslides and the Slippery Slope of Urban Risks in Africa

To break these cycles and prevent or reduce the effects of disasters such as the recent mudslide in Freetown, a better understanding is needed of how knowledge of risk can lead to action. This requires collaboration between government, humanitarian actors, and civil sector organisations in partnership with local communities in both formal and informal areas

Study of Bioengineered Zebra Fish Olfactory Receptor 131-2: Receptor Purification and Secondary Structure Analysis

How fishes are able to detect trace molecules in large bodies of water is not understood. It is plausible that they use olfactory receptors to detect water-soluble compounds. How the zebra fish Danio Rerio, an organism with only 98 functional olfactory receptors, is able to selectively detect and recognize numerous compounds in water remains a puzzling phenomenon. We are interested in studying the biochemical and molecular mechanisms of olfaction in fish. Here, we report on the study of a bioengineered zebra fish olfactory receptor OR131-2, affinity-purified from a HEK293S tetracycline-inducible system. This receptor was expressed and translocated to the cell plasma membrane as revealed by confocal microscopy. Circular dichroism spectroscopy showed that the purified zebra fish receptor folded into an α-helical structure, as observed for other G-protein coupled receptors (GPCRs). Our study shows that it is possible to produce viable quantities of the zebra fish olfactory receptor. This will not only enable detailed structural and functional analyses, but also aid in the design of biosensor devices in order to detect water-soluble metabolites or its intermediates, which are associated with human health.Singapore. Institute of Bioengineering and Nanotechnolog

Communicating risk from the frontline: projecting community voices into disaster risk management policies across scales, in: Urban Ark Briefing No 19. October 2018

Research carried out in Dar es Salaam, Tanzania on cross-scalar risk communication and disaster risk governance reveals that, while there is considerable potential for communities to measure and communicate risk and to prioritise actions, there is little scope for them to influence disaster risk governance at this point in time. This is partly because, although disaster risk management (DRM) is devolved in Tanzania, it has not gone far enough to give adequate powers and financing to the lowest level of government at the sub-wards, which are at the frontline of managing the biggest everyday risks that people face. The effective communication of risks upwards from communities to governments, and of DRM policies and opportunities downwards to communities and across sectors is crucial to overcome these gaps. When communication is participatory and collaborative, there is scope for local city actors to reflect on the need for action to be joined across governance scales, and to ensure communication plays a key role at and between all levels

Cloud condensation nuclei closure study on summer arctic aerosol

We present an aerosol – cloud condensation nuclei (CCN) closure study on summer high Arctic aerosol based on measurements that were carried out in 2008 during the Arctic Summer Cloud Ocean Study (ASCOS) on board the Swedish ice breaker <i>Oden</i>. The data presented here were collected during a three-week time period in the pack ice (>85° N) when the icebreaker <i>Oden</i> was moored to an ice floe and drifted passively during the most biological active period into autumn freeze up conditions. <br><br> CCN number concentrations were obtained using two CCN counters measuring at different supersaturations. The directly measured CCN number concentration was then compared with a CCN number concentration calculated using both bulk aerosol mass composition data from an aerosol mass spectrometer (AMS) and aerosol number size distributions obtained from a differential mobility particle sizer, assuming κ-Köhler theory, surface tension of water and an internally mixed aerosol. The last assumption was supported by measurements made with a hygroscopic tandem differential mobility analyzer (HTDMA) for particles >70 nm. <br><br> For the two highest measured supersaturations, 0.73 and 0.41%, closure could not be achieved with the investigated settings concerning hygroscopicity and density. The calculated CCN number concentration was always higher than the measured one for those two supersaturations. This might be caused by a relative larger insoluble organic mass fraction of the smaller particles that activate at these supersaturations, which are thus less good CCN than the larger particles. On average, 36% of the mass measured with the AMS was organic mass. At 0.20, 0.15 and 0.10% supersaturation, closure could be achieved with different combinations of hygroscopic parameters and densities within the uncertainty range of the fit. The best agreement of the calculated CCN number concentration with the observed one was achieved when the organic fraction of the aerosol was treated as nearly water insoluble (κ<sub>org</sub>=0.02), leading to a mean total κ, κ<sub>tot</sub>, of 0.33 ± 0.13. However, several settings led to closure and κ<sub>org</sub>=0.2 is found to be an upper limit at 0.1% supersaturation. κ<sub>org</sub>≤0.2 leads to a κ<sub>tot</sub> range of 0.33 ± 013 to 0.50 ± 0.11. Thus, the organic material ranges from being sparingly soluble to effectively insoluble. These results suggest that an increase in organic mass fraction in particles of a certain size would lead to a suppression of the Arctic CCN activity

Uncertain pasts and risk-sensitive futures in sub-Saharan urban transformation

This chapter explores the status and the scope for transition of risk- sensitive and transformative urban development in diverse cities of sub-Saharan Africa. Sub-Saharan Africa is important because of its large proportions of urban populations with high vulnerability and growing exposure to risks. High rates of urban growth pose increasing risks as we go into the future, yet there is also opportunity to reduce risk through integrating risk management into development. However, this opportunity space is often constrained by limited capacities to plan and manage the rapid urbanisation process, particularly in informal settlements. Limited capacities to prevent processes of risk accumulation pose threats to poverty reduction and sustainable development. In this context, there is an increasingly urgent need for squarely recognising and addressing the underlying vulnerabilities of urban populations and their root causes. Transitioning towards such sustainable urban pathways will require the strengthening of capacities and accountability of city authorities and broader governance systems, both formal and informal

Stable, Efficient, and All-Solution-Processed Quantum Dot Light-Emitting Diodes with Double-Sided Metal Oxide Nanoparticle Charge Transport Layers

Cataloged from PDF version of article.An efficient and stable quantum dot light-emitting diode (QLED) with double-sided metal oxide (MO) nanoparticle (NP) charge transport layers is fabricated by utilizing the solution-processed tungsten oxide (WO3) and zinc oxide (ZnO) NPs as the hole and electron transport layers, respectively. Except for the electrodes, all other layers are deposited by a simple spin-coating method. The resulting MO NP-based QLEDs show excellent device performance, with a peak luminance of 21300 cd/m(2) at the emission wavelength of 516 nm, a maximal current efficiency of 4.4 cd/A, and a low turn-on voltage of 3 V. More importantly, with the efficient design of the device architecture, these devices exhibit a significant improvement in device stability and the operational lifetime of 95 h measured at room temperature can be almost 20-fold longer than that of the standard device

Self-consistent 3D radiative transfer for kilonovae: directional spectra from merger simulations

We present three-dimensional radiative transfer calculations for the ejecta from a neutron star merger that include line-by-line opacities for tens of millions of bound-bound transitions, composition from an r-process nuclear network, and time-dependent thermalization of decay products from individual $\alpha$ and $\beta^-$ decay reactions. In contrast to expansion opacities and other wavelength-binned treatments, a line-by-line treatment enables us include fluorescence effects and associate spectral features with the emitting and absorbing lines of individual elements. We find variations in the synthetic observables with both the polar and azimuthal viewing angles. The spectra exhibit blended features with strong interactions by Ce III, Sr II, Y II, and Zr II that vary with time and viewing direction. We demonstrate the importance of wavelength-calibration of atomic data using a model with calibrated Sr, Y, and Zr data, and find major differences in the resulting spectra, including a better agreement with AT2017gfo. The synthetic spectra for near-polar inclination show a feature at around 8000 A, similar to AT2017gfo. However, they evolve on a more rapid timescale, likely due to the low ejecta mass (0.005 M$_\odot$) as we take into account only the early ejecta. The comparatively featureless spectra for equatorial observers gives a tentative prediction that future observations of edge-on kilonovae will appear substantially different from AT2017gfo. We also show that 1D models obtained by spherically averaging the 3D ejecta lead to dramatically different direction-integrated luminosities and spectra compared to full 3D calculations.Comment: 12 pages, 5 figures. Accepted by ApJ

Influence of Arctic Microlayers and Algal Cultures on Sea Spray Hygroscopicity and the Possible Implications for Mixed-Phase Clouds

As Arctic sea ice cover diminishes, sea spray aerosols (SSA) have a larger potential to be emitted into the Arctic atmosphere. Emitted SSA can contain organic material, but how it affects the ability of particles to act as cloud condensation nuclei (CCN) is still not well understood. Here we measure the CCN-derived hygroscopicity of three different types of aerosol particles: (1) Sea salt aerosols made from artificial seawater, (2) aerosol generated from artificial seawater spiked with diatom species cultured in the laboratory, and (3) aerosols made from samples of sea surface microlayer (SML) collected during field campaigns in the North Atlantic and Arctic Ocean. Samples are aerosolized using a sea spray simulation tank (plunging jet) or an atomizer. We show that SSA containing diatom and microlayer exhibit similar CCN activity to inorganic sea salt with a κ value of ∼1.0. Large-eddy simulation (LES) is then used to evaluate the general role of aerosol hygroscopicity in governing mixed-phase low-level cloud properties in the high Arctic. For accumulation mode aerosol, the simulated mixed-phase cloud properties do not depend strongly on κ, unless the values are lower than 0.4. For Aitken mode aerosol, the hygroscopicity is more important; the particles can sustain the cloud if the hygroscopicity is equal to or higher than 0.4, but not otherwise. The experimental and model results combined suggest that the internal mixing of biogenic organic components in SSA does not have a substantial impact on the cloud droplet activation process and the cloud lifetime in Arctic mixed-phase clouds

Quantum Dot Light-Emitting Diode with Quantum Dots Inside the Hole Transporting Layers

Cataloged from PDF version of article.We report a hybrid, quantum dot (QD)-based, organic light-emitting diode architecture using a noninverted structure with the QDs sandwiched between hole transporting layers (HTLs) outperforming the reference device structure implemented in conventional noninverted architecture by over five folds and suppressing the blue emission that is otherwise observed in the conventional structure because of the excess electrons leaking towards the HTL. It is predicted in the new device structure that 97.44% of the exciton formation takes place in the QD layer, while 2.56% of the excitons form in the HTL. It is found that the enhancement in the external quantum efficiency is mainly due to the stronger confinement of exciton formation to the QDs