618 research outputs found

    Density functional study of the adsorption of K on the Ag(111) surface

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    Full-potential gradient corrected density functional calculations of the adsorption of potassium on the Ag(111) surface have been performed. The considered structures are Ag(111) (root 3 x root 3) R30degree-K and Ag(111) (2 x 2)-K. For the lower coverage, fcc, hcp and bridge site; and for the higher coverage all considered sites are practically degenerate. Substrate rumpling is most important for the top adsorption site. The bond length is found to be nearly identical for the two coverages, in agreement with recent experiments. Results from Mulliken populations, bond lengths, core level shifts and work functions consistently indicate a small charge transfer from the potassium atom to the substrate, which is slightly larger for the lower coverage.Comment: to appear in Phys Rev

    Programmatic Environmental Scans: A Survey Based on Program Planning and Evaluation Concepts

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    Within Extension, environmental scans are most commonly used to assess community or organizational issues or for strategic planning purposes. However, Extension has expanded the use of environmental scans to systematically identify “what programs exist” on a given topic or focus area. Yet, despite recent attention to the topic of environmental scanning in Extension, survey instruments used to conduct environmental scans have not been published. Given the emphasis on implementation of evidence-based practices and programs, having a ready-made survey that can be used to identify programs on a specific topic and that could subsequently lead to an evaluability assessment of those programs would be a useful resource. To encourage the use of environmental scans to identify existing evidence-based programs, this article describes a survey instrument developed for the purpose of scanning for 4-H Healthy Living programs ready for rigorous outcome evaluation and/or national replication. It focuses on the rationale for survey items, as well as provides a summary and definition of those items. The survey tool can be easily adapted for future programmatic environmental scans both within and outside Extension

    Antimicrobial Activity in the Pallial Cavity Fluids of the Oyster Crassostrea virginica (Gmelin) from a Highly Impacted Harbor in Western Long Island Sound

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    Fluid and its associatedmucus from the pallial (mantle) cavity of eastern oysters Crassostrea virginica (Gmelin) from Black RockHarbor, Bridgeport, Connecticut, inhibited growth of both Gram-positive (Bacillus subtilis, Staphylococcus aureus) and Gram-negative (Escherichia coli, Serratia marcescens, and Vibrio parahaemolyticus) bacteria in antimicrobial assays. In the presence of oyster fluid, E. coli resulted in significant reduction in growth after 26 h. Soluble lysozyme activity in pallial cavity fluid of oysters collected in the fall was 3 times greater than that measured in combined winter—spring—summer samples (P = 0.0008). During the course of the study, copper concentrations in pallial cavity fluid ranged from 0.60–2.49 ppm and zinc concentrations ranged from 9.7–61.0 ppm. Copper concentrations remained relatively constant throughout the study; the highest zinc concentrations were recorded in the fall. Fall antimicrobial assays showed heightened antimicrobial activity compared with the spring, which may be the result of increased lysozyme activity and higher zinc concentrations present in the pallial cavity fluid at that time of year. Results of this study suggest that pallial cavity fluid and its associated mucus likely serve an important role in defense-related functions as the first line of defense against infections from environmental pathogens in Crassostrea virginica

    Informing Youth Health and Well-Being Programs: A National 4-H Healthy Living Evaluation Study

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    4-H Healthy Living programs address healthy eating; physical activity; social-emotional health and well-being; alcohol, tobacco, and other drug use prevention; and injury prevention. Using the Systematic Screening and Assessment Method, this paper identified 32 4-H Healthy Living programs across the nation ready for comprehensive outcome evaluation and/or national replication based on 6 criteria. Weaknesses in an additional 78 programs that did not meet the criteria were also identified. Programs that failed to meet the criteria did so primarily because they lacked a clearly delineated theory of change or appropriate evaluation. Implications for practice include ways to strengthen program planning and use of a comprehensive evaluation framework. Specific attention is given to professional development for 4-H professionals
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