Structural selective charge transfer in iodine-doped carbon nanotubes

We have investigated iodine intercalated carbon nanostructures by extended X-ray absorption fine structure (EXAFS) and Raman spectroscopies. We discuss here the charge transfer and the iodine–carbon interaction as a function of the carbon nanostructures (graphite, multi-walled, double-walled and single walled nanotubes). The results show that iodine is weakly adsorbed on the surface of all multi-walled nanotubes. By contrast, a charge transfer between iodine and single walled nanotubes is evidenced

A reassessment of prebiotically relevant chemical agents for the activation of α-amino acids and peptides

International audienceFrom an origin-of-life perspective, processes able to provide energy to feed self-organizing systems are required for the formation of their own components but also to maintain a far from equilibrium state essential for the system to remain under kinetic control. α-Amino acid N-carboxyanhydrides (NCAs) and 5(4H)-oxazolones represent activated intermediates of the chemistry of peptides that may be involved in the self-organization of life and in the evolution of translation. An experimental survey of previously published activating agents has been carried out using the epimerization associated with the transient formation of 5(4H)-oxazolones as a tool to monitor their potential to promote strong activation. None of reagents investigated in this survey proved to be totally satisfactory demonstrating that the identification of activation processes remains a crucial goal in this field

Is sweep-flocculation relevant to saponite aggregation?

International audienceSynthetic saponites with various Cationic Exchange Capacities were aggregated at pH 8.0 in a stirred vessel by hydrolyzed aluminum species. Floc growth was followed by Fraunhoffer laser diffraction and the efficiency of clarification was assessed from conventional residual turbidity and sediment volume measurements. We show that the aggregation mechanisms are layer-charge dependent and can not be described by the widely accepted sweep flocculation model

Hydration Properties and Interlayer Organization of Water and Ions in Synthetic Na-Smectite with Tetrahedral Layer Charge. Part 1. Results from X-ray Diffraction Profile Modeling

International audienceThe dehydration of two Na-saturated synthetic saponites with contrasting layer charge was studied by modeling the X-ray diffraction (XRD) patterns recorded along a water vapor desorption isotherm. The interlayer configurations used to reproduce the XRD data over a large angular range include Na+ cations located in the interlayer midplane and H2O molecules normally distributed about one or two main positions for mono- and bihydrated layers, respectively. Although strongly reduced in comparison to natural smectites, hydration heterogeneity was systematically observed for these synthetic saponites, especially along the transition between two hydration states. Using improved models for the description of the interlayer organization, the influence of layer charge on the structure of interlayer water can be precisely assessed. In addition, the comparison with water contents obtained from water vapor gravimetry experiments allows discriminating the relative contributions of H2O molecules from 1W and 2W interlayers (crystalline water) and from the pore space network

The Analytical Narrative Project

African and African American StudiesGovernmen

Campylobacter fetus Bacteremia Revealed by Cellulitis without Gastrointestinal Symptoms in the Context of Acquired Hypogammaglobulinemia: A Report of Three Cases

Campylobacter fetus bacteremia is rare and occurs mainly in patients with immunosuppression. This infection, which often involves secondary localizations has already been reported in some primary humoral immune deficiencies. We describe three cases of severe infection due to C. fetus with cellulitis at presentation, but without any gastrointestinal symptoms, occurring in patients with acquired hypogammaglobulinemia

Exhaust emissions of regulated and unregulated pollutants of passenger cars

Exhaust emissions of VOC speciation, aldehydes and other carbonyl compounds, polyaromatics and regulated pollutants are measured using a vehicle bench on a sample of passenger cars. 30 diesel and gasoline cars are tested, complying with ECE 1504 to Euro 3 emission standards, according to 10 real-world driving cycles based on European driving behaviour, with some of them adapted to vehicle size. The emission results of this large-scale measurement campaign show the influence of vehicle technology and driving behaviour on the emission of 100 individual pollutants. In addition, the results are discussed per VOC group and compared with other studies. The influence of the successive emission standards on the emission factors is very positive in most of cases. However, whereas hot CO2 is almost stable, diesel hot NOx, diesel hot and cold VOC, and the 6 most carcinogenic gasoline PAH have increased with standards. Diesel vehicles are less pollutant for CO, HC, CO2, VOC, but more pollutant for NOx and PAH. The distribution of VOC species per molecular family highlights the fact that monoaromatics make up the biggest share (~88 and 62 % resp. for gasoline and diesel vehicles). The second family is the alkanes which contribute resp. 8 and 9% of the total mass of measured VOC. The majority of volatile PAH is observed in the gaseous phase, but the least volatile and the carcinogenic PAH are adsorbed more in particulate phase

Functional Role of P-Glycoprotein and Binding Protein Effect on the Placental Transfer of Lopinavir/Ritonavir in the Ex Vivo Human Perfusion Model

Aims. To study the influence of P-glycoprotein (P-glycoprotein, ABCB1, MDR1) function on placental transfer of lopinavir with ritonavir at different albumin concentrations. Methods. Cotyledons were perfused with lopinavir, ritonavir, and the internal control antipyrin, at various albumin concentrations (10, 30, 40 g/L). After the control phase of each experiment, the P-glycoprotein inhibitor ciclosporin A was added at middle perfusion (45 minutes). Fetal Transfer Rate (FTR) and Clearance Index (CLI) were compared between the 2 phases. Results. In the control phase, the clearance index of lopinavir decreased from 0.401 ± 0.058 to 0.007 ± 0.027, as albumin concentrations increased from 10 g/L to higher concentrations (30, 40 g/L). When adding ciclosporin A at physiological albumin concentrations, the clearance index of lopinavir increased significantly 10.3 fold (95% of CI difference [−0.156, −0.002], P = .046) and became positive for ritonavir. Conclusions. Even at high albumin concentrations, inhibition of placental P-glycoprotein increased placental transfer of lopinavir, suggesting that this efflux pump actively reduces placental transfer of the drug. This mechanism may play a role in fetal exposure to maternal antiretroviral therapy

Analytic Narratives Revisited

African and African American StudiesGovernmen