Ultrasound to Enhance a Liquid–Liquid Reaction

Liquid–liquid mass transfer with ultrasound was investigated experimentally during the hydrolysis of n-amyl acetate. Power ultrasound is supposed to improve the yield and kinetics of such multiphase chemical reactions thanks to the mechanical effects of cavitation. Indeed, implosion of micro-bubbles at the vicinity of the liquid– liquid interface generates disruption of this surface, and enhances mixing in the liquid around the inclusion, thus improving mass transfer between the two phases. This effect has been demonstrated here on the hydrolysis of n-amyl acetate by sodium hydroxide, a rather slow reaction but influenced by mass transfer; the reaction is carried out in a glass jacketed reactor, 500 mL of volume, equipped with a Rushton turbine and a 20 kHz sonotrode dipping in the solution. The ester is initially pure in the organic dispersed phase, and sodium hydroxide has an initial concentration of 300 mol/m3; one of the products, pentanol partitions between the two phases and the sodium salt stays in the aqueous phase. The initial apparent reaction rate is measured from the record of the conductivity giving the concentration of alkali versus time. The reaction rate was always found to increase when ultrasound is superimposed to mechanical stirring (at 600 rpm), with a positive influence of input power (20 and 50 W). When varying initial concentration (300 and 600 mol/m3), temperature (36 and 45°C) and ultrasound emitter (sonotrode or cuphorn), the benefit of ultrasound over mechanical agitation was systematic. The only case of a weak influence of ultrasound was the sonication of a dense medium, containing 23% of organic phase and impeding the propagation of ultrasound

High-temperature oxidation of nickel-based alloys and estimation of the adhesion strength of resulting oxide layers

The kinetics of isothermal oxidation (1100°C) of commercial nickel-based alloys with different content of sulfur (0.22–3.2 wt ppm) is studied. The adhesion strength in a metal/oxide system is estimated as a function of sulfur content and duration of high-temperature exposure. The scratch-test technique is proposed to quantitatively estimate the work of adhesion of resulting oxide films. It is found that the film microstructure is composed of an inner α-Al2O3 layer and an outer NiAl2O4 spinel layer, which are separated by discrete inclusions of TiO2. Residual stresses in the oxide film are experimentally determined by X-ray diffraction. spinel layer, which are separated by discrete inclusions of TiO2. Residual stresses in the oxide film are experimentally determined by X-ray diffractio

ZSE466-3 - TOPIK-TOPIK LANJUTAN DALAM GEOFIZIK USAHACARI - APRIL 1987.

ABSTRACT: The Piano Key weir (PKW) is a hydraulically attractive alternative to linear overflow weirs, increasing the unit discharge for similar heads and spillway widths. This advantage allows operating dam reservoirs on an increased level and provides thereby an enhanced retention volume. It is a result of the non-linear nature of PKWs being folded back and forth to make repeating cycles or keys. As PKWs are relatively novel structures, only few design equations are available, so that normally physical model tests of prototypes have to be conducted assuring and optimizing their hydraulic characteristics. Nevertheless, first comprehensive and systematic model test series were conducted in several laboratories. Based on such a test series, a general design equation for A-type PKWs is proposed and discussed. Considering furthermore data of other laboratory studies, the latter is validated. It turned out that main and secondary parameters exist regarding the relative effect on the rating curve. The main parameters having a significant effect on the capacity are the relative developed crest length and the relative head. The secondary parameters of small but not negligible effect comprise the ratio of the inlet and outlet key widths, the ratio of the inlet and outlet key heights, the relative overhang lengths, and the relative height of the parapet walls.

From Labyrinth to Piano Key Weirs – A historical review

Free crest spillways are hydraulically efficient and safe in operation. Since their discharge capacity is directly proportional to the crest length several types have been developed with the purpose to increase the length of the latter. Among these types traditional labyrinth weir spillways have been studied and used for a long time. Their hydraulic performance and the effect of the involved geometrical parameters are well known. Nevertheless, their design still has to be based on experimentally derived and generalized performance curves. The recently introduced Piano Key weirs present clear advantages regarding hydraulic performance and construction costs compared to classical labyrinth weirs. Especially its small footprint makes the PK weir an efficient and cost effective solution for the increase of the flood releasing capacity at existing concrete gravity dams. Until today only preliminary design procedures are available which cannot yet be generalized. The still ongoing research on this complex hydraulic structure is a challenge for many scientists all over the world. Despite of this, several prototypes have been installed successfully over the last years on existing dams which enhance efficiently the flood release capacity

Coupled spillway devices and energy dissipation system at St-Marc (France)

The physical modeling tests for the rehabilitation of St-Marc Dam with a PKW are presented. A particular focus is put on the energy dissipation downstream from the PKW. The adopted solution is a leaned “ski-jump gutter” placed at the contact line between the downstream face of the dam and the natural foundation rock. It consists of a cylindrical profile, developed around an inclined axis and closed by a horizontal reach at the end of the structure. The aim of this solution is to guide the flow issued from the PKW to the stilling basin of the left existing spillway. The experimental tests consider various operation conditions which required pressure measurements at different impact zones. Structural design of the PKW is impacted by the fact that the concrete of the dam is subjected to a noteworthy blowing reaction. For that reason, the new structure could not be anchored in the existing dam. Thus, the spillway behaves as a gravity structure

Axial speed of sound for the monitoring of injured equine tendons: a preliminary study.

PublishedJournal ArticleResearch Support, Non-U.S. Gov'tEquine superficial digital flexor tendons (SDFT) are often injured, and they represent an excellent model for human sport tendinopathies. While lesions can be precisely diagnosed by clinical evaluation and ultrasonography, a prognosis is often difficult to establish; the knowledge of the injured tendon's mechanical properties would help in anticipating the outcome. The objectives of the present study were to compare the axial speed of sound (SOS) measured in vivo in normal and injured tendons and to investigate their relationship with the tendons' mechanical parameters, in order to assess the potential of quantitative axial ultrasound to monitor the healing of the injured tendons. SOS was measured in vivo in the right fore SDFTs of 12 horses during walk, before and 3.5 months after the surgical induction of a bilateral core lesion. The 12 horses were then euthanized, their SDFTs isolated and tested in tension to measure their elastic modulus and maximal load (and corresponding stress). SOS significantly decreased from 2179.4 ± 31.4 m/s in normal tendons to 2065.8 ± 67.1 m/s 3.5 months after the surgical induction, and the tendons' elastic modulus (0.90 ± 0.17 GPa) was found lower than what has been reported in normal tendons. While SOS was not correlated to tendon maximal load and corresponding stress, the SOS normalized on its value in normal tendons was correlated to the tendons' elastic modulus. These preliminary results confirm the potential of axial SOS in helping the functional assessment of injured tendon.Direction Générale de l’Enseignement et de la Recherche (French Ministry of Agriculture)Région Basse-NormandieInstitut National de la Recherche AgronomiqueAgence Nationale de la Recherch

Computed tomography porosity and spherical indentation for determining cortical bone millimetre-scale mechanical properties

The cortex of the femoral neck is a key structural element of the human body, yet there is not a reliable metric for predicting the mechanical properties of the bone in this critical region. This study explored the use of a range of non-destructive metrics to measure femoral neck cortical bone stiffness at the millimetre length scale. A range of testing methods and imaging techniques were assessed for their ability to measure or predict the mechanical properties of cortical bone samples obtained from the femoral neck of hip replacement patients. Techniques that can potentially be applied in vivo to measure bone stiffness, including computed tomography (CT), bulk wave ultrasound (BWUS) and indentation, were compared against in vitro techniques, including compression testing, density measurements and resonant ultrasound spectroscopy. Porosity, as measured by micro-CT, correlated with femoral neck cortical bone’s elastic modulus and ultimate compressive strength at the millimetre length scale. Large-tip spherical indentation also correlated with bone mechanical properties at this length scale but to a lesser extent. As the elastic mechanical properties of cortical bone correlated with porosity, we would recommend further development of technologies that can safely measure cortical porosity in vivo. Introductio

Piano Key Weirs as efficient spillway structure

With increasing of hydrological data records and the development of technologies for flood discharge estimation, as well as higher requirements on dam safety issues, a large number of existing dams require spillway rehabilitation to improve their hydraulic capacity. For such projects, the Piano Key Weir (PKW) is an efficient alternative. When compared to standard labyrinth weirs, this structure provides a longer effective crest length for a given spillway width, with the advantage that a PKW can be mounted on the top of most existing dams, due to its reduced base surface [1, 2]. Although the hydraulic design and optimization process of PKWs are today supported by physical modelling of case studies [3, 4, 5, 6], systematic basic experiments performed in laboratory channels were important to understand their hydraulic behavior [7, 8, 9, 10]. Most of the experiments consider only one sectional part of the PKW, with uniform approach flow conditions. The three-dimensional effect of the lateral weir ends, characterizing a typical reservoir inflow, is consequently not considered. As a result of these systematic tests, some procedures for designing PKWs are proposed in literature. Among these methods, a simplified formulation for calculating the hydraulic capacity of A-type PKWs [10] is based on the most important geometrical dimensionless parameters of PKWs, i.e, L/W, Wi/Wo, Pi/Po and H/Pi, (Fig. 1). The objective of this paper is to present some selected results of systematic experiments performed in a laboratory channel, focusing on the number of PKW units and the influence of the parapet walls

Elasticité et porosité de l'os cortical humain : modèles et expériences

A l'échelle millimétrique, l'os cortical est vu comme une matrice minéralisée traversée de pores (canaux de Havers). Nous avons mesuré la porosité et l'élasticité de 21 échantillons (10 donneurs) et nous montrons que la rigidité de la matrice a une influence très faible sur l'élasticité apparente. Ces données permettent pour la première fois une analyse critique des modèles de changement d'échelle (homogénéisation asymptotique, Mori-Tanaka, bornes, etc.). Nous établissons que la densité apparente à l'échelle millimétrique peut être reliée au tenseur d'élasticité anisotrope grâce aux modèles