Fatty acid ethyl esters of Rhizopus arrhizus. Ethyl esters of long-chain fatty acids are reported for Rhizopus arrhizus

Presence of ethyl esters of long-chain fatty acids determined for Rhizopus arrhizu

Two populations of aliphatic hydrocarbons of teratoma and habituated tissue cultures of tobacco

Paraffinic hydrocarbons in tobacco tissue culture

Hydrocarbons and Free Fatty Acids Associated with the Air/Water Interface, Sediments, and Beaches of the Timbalier Bay and Offshore Louisiana Area

Paper by J. L. Laseter and E. J. Lede

The chemical enrichment in the early Universe as probed by JWST via direct metallicity measurements at z ∼ 8

We analyse the chemical properties of three z∼ 8 galaxies behind the galaxy cluster SMACS J0723.3-7327, observed as part of the Early Release Observations programme of the James Webb Space Telescope. Exploiting [O III]λ4363 auroral line detections in NIRSpec spectra, we robustly apply the direct Te method for the very first time at such high redshift, measuring metallicities ranging from extremely metal poor (12 + log(O/H)≈ 7) to about one-third solar. We also discuss the excitation properties of these sources, and compare them with local strong-line metallicity calibrations. We find that none of the considered diagnostics match simultaneously the observed relations between metallicity and strong-line ratios for the three sources, implying that a proper re-assessment of the calibrations may be needed at these redshifts. On the mass-metallicity plane, the two galaxies at z ∼ 7.6 (log(M∗/M☉) = 8.1, 8.7) have metallicities that are consistent with the extrapolation of the mass-metallicity relation at z∼2-3, while the least massive galaxy at z ∼ 8.5 (log(M∗/M☉) = 7.8) shows instead a significantly lower metallicity. The three galaxies show different level of offset relative to the Fundamental Metallicity Relation, with two of them (at z∼ 7.6) being marginally consistent, while the z∼ 8.5 source deviating significantly, being probably far from the smooth equilibrium between gas flows, star formation, and metal enrichment in place at later epochs

JADES: Detecting [OIII] λ 4363 emitters and testing strong line calibrations in the high- z Universe with ultra-deep JWST/NIRSpec spectroscopy up to z ~ 9.5

We present ten novel [OIII]λ4363 auroral line detections up to z~ 9.5 measured from ultra-deep JWST/NIRSpec MSA spectroscopy from the JWST Advanced Deep Extragalactic Survey (JADES). We leverage the deepest spectroscopic observations taken thus far with NIRSpec to determine electron temperatures and oxygen abundances using the direct Te method. We directly compare these results against a suite of locally calibrated strong-line diagnostics and recent high-z calibrations. We find the calibrations fail to simultaneously match our JADES sample, thus warranting a self-consistent revision of these calibrations for the high-z Universe. We find a weak dependence between R2 and O3O2 with metallicity, thus suggesting these line ratios are inefficient in the high-z Universe as metallicity diagnostics and degeneracy breakers. We find R3 and R23 are still correlated with metallicity, but we find a tentative flattening of these diagnostics, thus suggesting future difficulties when applying these strong line ratios as metallicity indicators in the high-z Universe. We also propose and test an alternative diagnostic based on a different combination of R3 and R2 with a higher dynamic range. We find a reasonably good agreement (median offset of 0.002 dex, median absolute offset of 0.13 dex) with the JWST sample at low metallicity, but future investigations are required on larger samples to probe past the turnover point. At a given metallicity, our sample demonstrates higher ionization and excitation ratios than local galaxies with rest-frame EWs(Hβ) ≈ 200-300 Å. However, we find the median rest-frame EWs(Hβ) of our sample to be~2× less than the galaxies used for the local calibrations. This EW discrepancy combined with the high ionization of our galaxies does not offer a clear description of [OIII]λ4363 production in the high-z Universe, thus warranting a much deeper examination into the factors influencing these processes

JADES: Insights into the low-mass end of the mass-metallicity-SFR relation at 3 < z < 10 from deep JWST/NIRSpec spectroscopy*

We analysed the gas-phase metallicity properties of a sample of low-stellar-mass (log M?/M. 9) galaxies at 3 6, with galaxies significantly less enriched than predicted given their M? and SFR (with a median offset in log(O/H) of ∼0.5 dex, significant at ∼5σ). These observations are consistent with an enhanced stochasticity in the gas accretion and star-formation history of high-redshift systems, prompting us to reconsider the nature of the relationship between M?, O/H, and SFR in the early Universe