Investigation of the applicability of using the triple redundant hydrogen sensor for methane sensing

Application specifications for the methane sensor were assembled and design guidelines, development goals and evaluation criteria were formulated. This was done to provide a framework to evaluate sensor performance and any design adjustments to the preprototype sensor that could be required to provide methane sensitivity. Good response to hydrogen was experimentally established for four hydrogen sensor elements to be later evaluated for methane response. Prior results were assembled and analyzed for other prototype hydrogen sensor performance parameters to form a comparison base. The four sensor elements previously shown to have good hydrogen response were experimentally evaluated for methane response in 2.5% methane-in-air. No response was obtained for any of the elements, despite the high methane concentration used (50% of the Lower Flammability Limit). It was concluded that the preprototype sensing elements were insensitive to methane and were hydrogen specific. Alternative sensor operating conditions and hardware design changes were considered to provide methane sensitivity to the preprototype sensor, including a variety of different methane sensing techniques. Minor changes to the existing sensor elements, sensor geometry and operating conditions will not make the preprototype hydrogen sensor respond to methane. New sensor elements that will provide methane and hydrogen sensitivity require replacement of the existing thermistor type elements. Some hydrogen sensing characteristics of the modified sensor will be compromised (larger in situ calibration gas volume and H2 nonspecificity). The preprototype hydrogen sensor should be retained for hydrogen monitoring and a separate methane sensor should be developed

The development of an electrochemical technique for in situ calibrating of combustible gas detectors

A program to determine the feasibility of performing in situ calibration of combustible gas detectors was successfully completed. Several possible techniques for performing the in situ calibration were proposed. The approach that showed the most promise involved the use of a miniature water vapor electrolysis cell for the generation of hydrogen within the flame arrestor of a combustible gas detector to be used for the purpose of calibrating the combustible gas detectors. A preliminary breadboard of the in situ calibration hardware was designed, fabricated and assembled. The breadboard equipment consisted of a commercially available combustible gas detector, modified to incorporate a water vapor electrolysis cell, and the instrumentation required for controlling the water vapor electrolysis and controlling and calibrating the combustible gas detector. The results showed that operation of the water vapor electrolysis at a given current density for a specific time period resulted in the attainment of a hydrogen concentration plateau within the flame arrestor of the combustible gas detector

Andreev Level Qubit

We investigate the dynamics of a two-level Andreev bound state system in a transmissive quantum point contact embedded in an rf-SQUID. Coherent coupling of the Andreev levels to the circulating supercurrent allows manipulation and read out of the level states. The two-level Hamiltonian for the Andreev levels is derived, and the effect of interaction with the quantum fluctuations of the induced flux is studied. We also consider an inductive coupling of qubits, and discuss the relevant SQUID parameters for qubit operation and read out.Comment: 4 pages, 1 figur

Detection and Mapping of Phragmites australis using High Resolution Multispectral and Hyperspectral Satellite Imagery

Mapping invasive plant species is important to establish an invasion baseline, monitor plant propagation, and to implement an effective plan to deal with the invasion. In this thesis, methods are proposed to map invasive Phragmites australis in a Great Lakes coastal wetland. Chapter 2 presents an object-based Phragmites extraction method using Worldview-2 high-spatial-resolution satellite imagery. For the 4024 ha study area at Walpole Island,Ontario, 94% overall accuracy was achieved. Chapter 3 uses CHRIS PROBA hyperspectral satellite imagery for mapping the pixel abundance of Phragmites using a spectral mixture analysis method. An evaluation method was developed to assess the accuracy of the spectral mixture analysis fractions using the classification from Chapter 2. The overall accuracy for a Phragmites, native vegetation and water classification based on the dominant fraction in each pixel was 82.8%. A Phragmites invasion classification identifying pixels where Phragmites was non-dominant, potentially dominant, and dominant was 85.2% accurate

Development of a static feed water electrolysis system

A one person level oxygen generation subsystem was developed and production of the one person oxygen metabolic requirements, 0.82 kg, per day was demonstrated without the need for condenser/separators or electrolyte pumps. During 650 hours of shakedown, design verification, and endurance testing, cell voltages averaged 1.62 V at 206 mA/sq cm and at average operating temperature as low as 326 K, virtually corresponding to the state of the art performance previously established for single cells. This high efficiency and low waste heat generation prevented maintenance of the 339 K design temperature without supplemental heating. Improved water electrolysis cell frames were designed, new injection molds were fabricated, and a series of frames was molded. A modified three fluid pressure controller was developed and a static feed water electrolysis that requires no electrolyte in the static feed compartment was developed and successfully evaluated

Opportunities for and challenges to further reductions in the “specific power” rating of wind turbines installed in the United States

A wind turbine’s “specific power” rating relates its capacity to the swept area of its rotor in terms of Watt per square meter. For a given generator capacity, specific power declines as rotor size increases. In land-rich but capacity-constrained wind power markets, such as the United States, developers have an economic incentive to maximize megawatt-hours per constrained megawatt, and so have favored turbines with ever-lower specific power. To date, this trend toward lower specific power has pushed capacity factors higher while reducing the levelized cost of energy. We employ geospatial levelized cost of energy analysis across the United States to explore whether this trend is likely to continue. We find that under reasonable cost scenarios (i.e. presuming that logistical challenges from very large blades are surmountable), low-specific-power turbines could continue to be in demand going forward. Beyond levelized cost of energy, the boost in market value that low-specific-power turbines provide could become increasingly important as wind penetration grows

Advanced combined iodine dispenser and detector

A total weight of 1.23 kg (2.7 lb), a total volume of 1213 cu m (74 cu in), and an average power consumption of 5.5W was achieved in the advanced combined iodine dispenser/detector by integrating the detector with the iodine source, arranging all iodinator components within a compact package and lowering the parasitic power to the detector and electronics circuits. These achievements surpassed the design goals of 1.36 kg (3.0 lb), 1671 cu m (102 cu in) and 8W. The reliability and maintainability were improved by reducing the detector lamp power, using an interchangeable lamp concept, making the electronic circuit boards easily accessible, providing redundant water seals and improving the accessibility to the iodine accumulator for refilling. The system was designed to iodinate (to 5 ppm iodine) the fuel cell water generated during 27 seven-day orbiter missions (equivalent to 18,500 kg (40,700 lb) of water) before the unit must be recharged with iodine crystals

Triple redundant hydrogen sensor with in situ calibration

To meet sensing and calibration needs, an in situ calibration technique was developed. It is based on electrolytic generation of a hydrogen/air atmosphere within a hydrogen sensor. The hydrogen is generated from water vapor in the air, and being electrical in nature, the in situ calibration can be performed completely automatically in remote locations. Triply redundant sensor elements are integrated within a single, compact housing, and digital logic provides inter-sensor comparisons to warn of and identify malfunctioning sensor elements. An evaluation of this concept is presented

Realization of the purely spatial Einstein-Podolsky-Rosen paradox in full-field images of spontaneous parametric down conversion

We demonstrate Einstein-Podolsky-Rosen (EPR) entanglement by detecting purely spatial quantum correlations in the near and far fields of spontaneous parametric down-conversion generated in a type-2 beta barium borate crystal. Full-field imaging is performed in the photon-counting regime with an electron-multiplying CCD camera. The data are used without any postselection, and we obtain a violation of Heisenberg inequalities with inferred quantities taking into account all the biphoton pairs in both the near and far fields by integration on the entire two-dimensional transverse planes. This ensures a rigorous demonstration of the EPR paradox in its original position momentum form

Small high-temperature nuclear reactors for space power

Criticality calculations for small, cylindrical, lithium cooled reactors for space power system