Spectrum of π\pi Electrons in Graphene as an Alternant Macromolecule and Its Specific Features in Quantum Conductance

An exact description of $\pi$ electrons based on the tight-binding model of graphene as an alternant, plane macromolecule is presented. The model molecule can contain an arbitrary number of benzene rings and has armchair- and zigzag-shaped edges. This suggests an instructive alternative to the most commonly used approach, where the reference is made to the honeycomb lattice periodic in its A and B sublattices. Several advantages of the macromolecule model are demonstrated. The newly derived analytical relations detail our understanding of $\pi$ electron nature in achiral graphene ribbons and carbon tubes and classify these structures as quantum wires.Comment: 13 pages 8 figures, revised in line with referee's comment

Transport in Molecular Junctions with Different Metallic Contacts

Ab initio calculations of phenyl dithiol connected to Au, Ag, Pd, and Pt electrodes are performed using non-equilibrium Green's functions and density functional theory. For each metal, the properties of the molecular junction are considered both in equilibrium and under bias. In particular, we consider in detail charge transfer, changes in the electrostatic potential, and their subsequent effects on the IV curves through the junctions. Gold is typically used in molecular junctions because it forms strong chemical bonds with sulfur. We find however that Pt and Pd make better electrical contacts than Au. The zero-bias conductance is found to be greatest for Pt, followed by Pd, Au, and then Ag

Relations between Entropies Produced in Nondeterministic Thermodynamic Processes

Landauer's erasure principle is generalized to nondeterministic processes on systems having an arbitrary number of non-symmetrical logical states. The condition that the process is applied in the same way, irrespective of the initial logical state, imposes some restrictions on the individual heat exchanges associated with each possible transition. The complete set of such restrictions are derived by a statistical analysis of the phase-space flow induced by the process. Landauer's erasure principle can be derived from and is a special case of these.Comment: 12 pages with one figure; a final major revision in presentation; physical assumptions are clarified no

Effect of dephasing on the current statistics of mesoscopic devices

We investigate the effects of dephasing on the current statistics of mesoscopic conductors with a recently developed statistical model, focusing in particular on mesoscopic cavities and Aharonov-Bohm rings. For such devices, we analyze the influence of an arbitrary degree of decoherence on the cumulants of the current. We recover known results for the limiting cases of fully coherent and totally incoherent transport and are able to obtain detailed information on the intermediate regime of partial coherence for a varying number of open channels. We show that dephasing affects the average current, shot noise, and higher order cumulants in a quantitatively and qualitatively similar way, and that consequently shot noise or higher order cumulants of the current do not provide information on decoherence additional or complementary to what can be already obtained from the average current.Comment: 4 pages, 4 figure

The conditional tunneling time for reflection using the WKB wave-function

We derive an expression for the conditional time for the reflection of a wave from an arbitrary potential barrier using the WKB wavefunction in the barrier region. Our result indicates that the conditional times for transmission and reflection are equal for a symmetric barrier within the validity of the WKB approach.Comment: 4 pages RevTeX, 1 eps figure include

Dynamic generation of orbital quasiparticle entanglement in mesoscopic conductors

We propose a scheme for dynamically creating orbitally entangled electron-hole pairs through a time-dependent variation of the electrical potential in a mesoscopic conductor. The time-dependent potential generates a superposition of electron-hole pairs in two different orbital regions of the conductor, a Mach-Zehnder interferometer in the quantum Hall regime. The orbital entanglement is detected via violation of a Bell inequality, formulated in terms of zero-frequency current noise. Adiabatic cycling of the potential, both in the weak and strong amplitude limit, is considered.Comment: 4 pages, 2 figures; references update

Frequency dependent effective conductivity of two-dimensional metal-dielectric composites

We analyze a random resistor-inductor-capacitor $(RLC)$ lattice model of 2-dimensional metal-insulator composites. The results are compared with Bruggeman's and Landauer's Effective Medium Approximations where a discrepancy was observed for some frequency zones. Such a discrepancy is mainly caused by the strong conductivity fluctuations. Indeed, a two-branches distribution is observed for low frequencies. We show also by increasing the system size that at $p_c$ the so-called Drude peak vanishes; it increases for vanishing losses.Comment: 7 pages including all figures, accepted in Int. J. Mod. Phys.

Memory erasure in small systems

We consider an overdamped nanoparticle in a driven double-well potential as a generic model of an erasable one-bit memory. We study in detail the statistics of the heat dissipated during an erasure process and show that full erasure may be achieved by dissipating less heat than the Landauer bound. We quantify the occurrence of such events and propose a single-particle experiment to verify our predictions. Our results show that Landauer's principle has to be generalized at the nanoscale to accommodate heat fluctuations.Comment: 4 pages, 4 figure

The Escape Problem for Irreversible Systems

The problem of noise-induced escape from a metastable state arises in physics, chemistry, biology, systems engineering, and other areas. The problem is well understood when the underlying dynamics of the system obey detailed balance. When this assumption fails many of the results of classical transition-rate theory no longer apply, and no general method exists for computing the weak-noise asymptotics of fundamental quantities such as the mean escape time. In this paper we present a general technique for analysing the weak-noise limit of a wide range of stochastically perturbed continuous-time nonlinear dynamical systems. We simplify the original problem, which involves solving a partial differential equation, into one in which only ordinary differential equations need be solved. This allows us to resolve some old issues for the case when detailed balance holds. When it does not hold, we show how the formula for the mean escape time asymptotics depends on the dynamics of the system along the most probable escape path. We also present new results on short-time behavior and discuss the possibility of focusing along the escape path.Comment: 24 pages, APS revtex macros (version 2.1) now available from PBB via `get oldrevtex.sty

Electromotive force and internal resistance of an electron pump

We present a scattering theory of the electromotive force and internal resistance of an electron pump. The characterization of the device performance in terms of only two parameters requires the assumption of incoherent multiple scattering within the circuit and complete thermalization among electrons moving in a given direction. The electromotive force is shown to be of the order of the driving frequency in natural units. In an open setup, the electromotive force adds to the voltage difference between reservoirs to drive the current, both facing a contact resistance which is absent in the case of a closed circuit of uniform width