Supramolecular thermoplastics and thermoplastic elastomer materials with self-healing ability based on oligomeric charged triblock copolymers

Supramolecular polymeric materials constitute a unique class of materials held together by non-covalent interactions. These dynamic supramolecular interactions can provide unique properties such as a strong decrease in viscosity upon relatively mild heating, as well as self-healing ability. In this study we demonstrate the unique mechanical properties of phase-separated electrostatic supramolecular materials based on mixing of low molar mass, oligomeric, ABA-triblock copolyacrylates with oppositely charged outer blocks. In case of well-chosen mixtures and block lengths, the charged blocks are phase separated from the uncharged matrix in a hexagonally packed nanomorphology as observed by transmission electron microscopy. Thermal and mechanical analysis of the material shows that the charged sections have a T-g closely beyond room temperature, whereas the material shows an elastic response at temperatures far above this T-g ascribed to the electrostatic supramolecular interactions. A broad set of materials having systematic variations in triblock copolymer structures was used to provide insights in the mechanical properties and and self-healing ability in correlation with the nanomorphology of the materials

Chronic Exposure of Corals to Fine Sediments: Lethal and Sub-Lethal Impacts

Understanding the sedimentation and turbidity thresholds for corals is critical in assessing the potential impacts of dredging projects in tropical marine systems. In this study, we exposed two species of coral sampled from offshore locations to six levels of total suspended solids (TSS) for 16 weeks in the laboratory, including a 4 week recovery period. Dose-response relationships were developed to quantify the lethal and sub-lethal thresholds of sedimentation and turbidity for the corals. The sediment treatments affected the horizontal foliaceous species (Montipora aequituberculata) more than the upright branching species (Acropora millepora). The lowest sediment treatments that caused full colony mortality were 30 mg l−1 TSS (25 mg cm−2 day−1) for M. aequituberculata and 100 mg l−1 TSS (83 mg cm−2 day−1) for A. millepora after 12 weeks. Coral mortality generally took longer than 4 weeks and was closely related to sediment accumulation on the surface of the corals. While measurements of damage to photosystem II in the symbionts and reductions in lipid content and growth indicated sub-lethal responses in surviving corals, the most reliable predictor of coral mortality in this experiment was long-term sediment accumulation on coral tissue

Irrigation strategies to improve the water use efficiency of wheat-maize double cropping systems in North China Plain

Water is the most important limiting factor of wheat (Triticum aestivum L.) and maize (Zea mays L.) double cropping systems in the North China Plain (NCP). A two-year experiment with four irrigation levels based on crop growth stages was used to calibrate and validate RZWQM2, a hybrid model that combines the Root Zone Water Quality Model (RZWQM) and DSSAT4.0. The calibrated model was then used to investigate various irrigation strategies for high yield and water use efficiency (WUE) using weather data from 1961 to 1999. The model simulated soil moisture, crop yield, above-ground biomass and WUE in responses to irrigation schedules well, with root mean square errors (RMSEs) of 0.029 cm3 cm-3, 0.59 Mg ha-1, 2.05 Mg ha-1, and 0.19 kg m-3, respectively, for wheat; and 0.027 cm3 cm-3, 0.71 Mg ha-1, 1.51 Mg ha-1 and 0.35 kg m-3, respectively, for maize. WUE increased with the amount of irrigation applied during the dry growing season of 2001-2002, but was less sensitive to irrigation during the wet season of 2002-2003. Long-term simulation using weather data from 1961 to 1999 showed that initial soil water at planting was adequate (at 82% of crop available water) for wheat establishment due to the high rainfall during the previous maize season. Preseason irrigation for wheat commonly practiced by local farmers should be postponed to the most sensitive growth stage (stem extension) for higher yield and WUE in the area. Preseason irrigation for maize is needed in 40% of the years. With limited irrigation available (100, 150, 200, or 250 mm per year), 80% of the water allocated to the critical wheat growth stages and 20% applied at maize planting achieved the highest WUE and the least water drainage overall for the two crops

David Nemarnik and Tom Fitzpatrick Interview 01

David Nemarnik is photographed during an oral history interview at Alloro Vineyard in Sherwood, Oregon on July 21, 2016. Nemarnik and colleague Tom Fitzpatrick were interviewed by Linfield College Archives staff Rich Schmidt. David Nemarnik is the owner and vineyard manager at Alloro Vineyard (located on Laurel Ridge in the Chehalem Mountains), where Tom Fitzpatrick is the winemaker and general manager. Nemarnik planted the first vines for Alloro (Italian for \u27laurel\u27) in 1999. The Mediterranean-inspired winery and tasting room were completed in 2003. Fitzpatrick joined Alloro Vineyard in 2010 after working for wineries in Washington, New Zealand, Napa Valley, Burgundy, and Oregon.https://digitalcommons.linfield.edu/owha_willamette_ohphotos/1210/thumbnail.jp