Tracer concentration profiles measured in central London as part of the REPARTEE campaign

There have been relatively few tracer experiments carried out that have looked at vertical plume spread in urban areas. In this paper we present results from two tracer (cyclic perfluorocarbon) experiments carried out in 2006 and 2007 in central London centred on the BT Tower as part of the REPARTEE (Regent’s Park and Tower Environmental Experiment) campaign. The height of the tower gives a unique opportunity to study vertical dispersion profiles and transport times in central London. Vertical gradients are contrasted with the relevant Pasquill stability classes. Estimation of lateral advection and vertical mixing times are made and compared with previous measurements. Data are then compared with a simple operational dispersion model and contrasted with data taken in central London as part of the DAPPLE campaign. This correlates dosage with non-dimensionalised distance from source. Such analyses illustrate the feasibility of the use of these empirical correlations over these prescribed distances in central London

Random replicators with high-order interactions

We use tools of the equilibrium statistical mechanics of disordered systems to study analytically the statistical properties of an ecosystem composed of N species interacting via random, Gaussian interactions of order p >= 2, and deterministic self-interactions u <= 0. We show that for nonzero u the effect of increasing the order of the interactions is to make the system more cooperative, in the sense that the fraction of extinct species is greatly reduced. Furthermore, we find that for p > 2 there is a threshold value which gives a lower bound to the concentration of the surviving species, preventing then the existence of rare species and, consequently, increasing the robustness of the ecosystem to external perturbations.Comment: 7 pages, 4 Postscript figure

Analysing Charges in even dimensions

Lanczos-Lovelock theories of gravity, in its first order version, are studied on asymptotically locally anti de Sitter spaces. It is shown that thermodynamics satisfies the standard behavior and an expression for entropy is found for this formalism. Finally a short analysis of the algebra of conserved charges is displayed

N-Alkyl-α-amino acids in Nature and their biocatalytic preparation

PWS would like to acknowledge the European Union for his current funding: “This project has received funding from the European Union’s Horizon 2020 research and innovation programme under Marie Skłodowska-Curie grant agreement No 665919”.N-alkylated-α-amino acids are useful building blocks for the pharmaceutical and fine chemical industries. Enantioselective methods of N-alkylated-α-amino acid synthesis are therefore highly valuable and widely investigated. While there are a variety of chemical methods for their synthesis, they often employ stoichiometric quantities of hazardous reagents such as pyrophoric metal hydrides or genotoxic alkylating agents, whereas biocatalytic routes can provide a greener and cleaner alternative to existing methods. This review highlights the occurrence of the N-alkyl-α-amino acid motif and its role in nature, important applications towards human health and biocatalytic methods of preparation. Several enzyme classes that can be used to access chiral N-alkylated-α-amino acids and their substrate selectivities are detailed.PostprintPeer reviewe

Null cone preserving maps, causal tensors and algebraic Rainich theory

A rank-n tensor on a Lorentzian manifold V whose contraction with n arbitrary causal future directed vectors is non-negative is said to have the dominant property. These tensors, up to sign, are called causal tensors, and we determine their general properties in dimension N. We prove that rank-2 tensors which map the null cone on itself are causal. It is known that, to any tensor A on V there is a corresponding ``superenergy'' (s-e) tensor T{A} which always has the dominant property. We prove that, conversely, any symmetric rank-2 tensor with the dominant property can be written in a canonical way as a sum of N s-e tensors of simple forms. We show that the square of any rank-2 s-e tensor is proportional to the metric if N<5, and that this holds for the s-e tensor of any simple form for arbitrary N. Conversely, we prove that any symmetric rank-2 tensor T whose square is proportional to the metric must be, up to sign, the s-e of a simple p-form, and that the trace of T determines the rank p of the form. This generalises, both with respect to N and the rank p, the classical algebraic Rainich conditions, which are necessary and sufficient conditions for a metric to originate in some physical field, and has a geometric interpretation: the set of s-e tensors of simple forms is precisely the set of tensors which preserve the null cone and its time orientation. It also means that all involutory Lorentz transformations (LT) can be represented as s-e tensors of simple forms, and that any rank-2 s-e tensor is the sum of at most N conformally involutory LT. Non-symmetric null cone preserving maps are shown to have a causal symmetric part and are classified according to the null eigenvectors of the skew-symmetric part. We thus obtain a complete classification of all conformal LT and singular null cone preserving maps on V.Comment: 36 pages, no figures, LaTeX fil

General Gauss-Bonnet brane cosmology

We consider 5-dimensional spacetimes of constant 3-dimensional spatial curvature in the presence of a bulk cosmological constant. We find the general solution of such a configuration in the presence of a Gauss-Bonnet term. Two classes of non-trivial bulk solutions are found. The first class is valid only under a fine tuning relation between the Gauss-Bonnet coupling constant and the cosmological constant of the bulk spacetime. The second class of solutions are static and are the extensions of the AdS-Schwarzchild black holes. Hence in the absence of a cosmological constant or if the fine tuning relation is not true, the generalised Birkhoff's staticity theorem holds even in the presence of Gauss-Bonnet curvature terms. We examine the consequences in brane world cosmology obtaining the generalised Friedmann equations for a perfect fluid 3-brane and discuss how this modifies the usual scenario.Comment: 20 pages, no figures, typos corrected, refs added, section IV changed yielding novel result

New features of flat (4+1)-dimensional cosmological model with a perfect fluid in Gauss-Bonnet gravity

We investigated a flat multidimensional cosmological model in Gauss-Bonnet gravity in presence of a matter in form of perfect fluid. We found analytically new stationary regimes (these results are valid for arbitrary number of spatial dimensions) and studied their stability by means of numerical recipes in 4+1-dimensional case. In the vicinity of the stationary regime we discovered numerically another non-singular regime which appears to be periodical. Finally, we demonstrated that the presence of matter in form of a perfect fluid lifts some constraints on the dynamics of the 4+1-dimensional model which have been found earlier.Comment: 14 pages, 5 figures, 1 table; v2 minor corrections, conclusions unchange

Normal frames and the validity of the equivalence principle. III. The case along smooth maps with separable points of self-intersection

The equivalence principle is treated on a mathematically rigorous base on sufficiently general subsets of a differentiable manifold. This is carried out using the basis of derivations of the tensor algebra over that manifold. Necessary and/or sufficient conditions of existence, uniqueness, and holonomicity of these bases in which the components of the derivations of the tensor algebra over it vanish on these subsets, are studied. The linear connections are considered in this context. It is shown that the equivalence principle is identically valid at any point, and along any path, in every gravitational theory based on linear connections. On higher dimensional submanifolds it may be valid only in certain exceptional cases.Comment: 15 standard LaTeX 2e (11pt, A4) pages. The package amsfonts is require

Hamiltonian thermodynamics of a Lovelock black hole

We consider the Hamiltonian dynamics and thermodynamics of spherically symmetric spacetimes within a one-parameter family of five-dimensional Lovelock theories. We adopt boundary conditions that make every classical solution part of a black hole exterior, with the spacelike hypersurfaces extending from the horizon bifurcation three-sphere to a timelike boundary with fixed intrinsic metric. The constraints are simplified by a Kucha\v{r}-type canonical transformation, and the theory is reduced to its true dynamical degrees of freedom. After quantization, the trace of the analytically continued Lorentzian time evolution operator is interpreted as the partition function of a thermodynamical canonical ensemble. Whenever the partition function is dominated by a Euclidean black hole solution, the entropy is given by the Lovelock analogue of the Bekenstein-Hawking entropy; in particular, in the low temperature limit the system exhibits a dominant classical solution that has no counterpart in Einstein's theory. The asymptotically flat space limit of the partition function does not exist. The results indicate qualitative robustness of the thermodynamics of five-dimensional Einstein theory upon the addition of a nontrivial Lovelock term.Comment: 22 pages, REVTeX v3.

Topological Invariants, Instantons and Chiral Anomaly on Spaces with Torsion

In a spacetime with nonvanishing torsion there can occur topologically stable configurations associated with the frame bundle which are independent of the curvature. The relevant topological invariants are integrals of local scalar densities first discussed by Nieh and Yan (N-Y). In four dimensions, the N-Y form $N= (T^a \wedge T_a - R_{ab} \wedge e^a \wedge e^b)$ is the only closed 4-form invariant under local Lorentz rotations associated with the torsion of the manifold. The integral of $N$ over a compact D-dimensional (Euclidean) manifold is shown to be a topological invariant related to the Pontryagin classes of SO(D+1) and SO(D). An explicit example of a topologically nontrivial configuration carrying nonvanishing instanton number proportional to $\int N$ is costructed. The chiral anomaly in a four-dimensional spacetime with torsion is also shown to contain a contribution proportional to $N$, besides the usual Pontryagin density related to the spacetime curvature. The violation of chiral symmetry can thus depend on the instanton number of the tangent frame bundle of the manifold. Similar invariants can be constructed in D>4 dimensions and the existence of the corresponding nontrivial excitations is also discussed.Comment: 6 pages, RevTeX, no figures, two column