Chemistry of the iron-chlorine thermochemical cycle for hydrogen production utilizing industrial waste heat

This research presents an inventive thermochemical cycle that utilizes a reaction between iron and HCl acid for hydrogen production. The reaction occurs spontaneously at room temperature, yielding hydrogen and a FeCl2 solution as a by-product. Exploring the thermal decomposition of the FeCl2 by-product revealed that, at conditions suitable for utilization of low-temperature industrial waste heat (250 °C), chlorine gas formation can be circumvented. Instead, the resulting by-product is HCl, which is readily soluble in water, facilitating direct reuse in subsequent cycles. The utilization of low-temperature industrial heat not only optimizes resource utilization and reduces operational costs but also aligns with environmentally sustainable production processes. From the kinetic studies the activation energy was calculated to be 45 kJ/mol and kinetics curves were constructed. They showed significant kinetics at room temperature and above but rapid decrease towards lower temperatures. This is important to consider during real-scale technology optimization. The theoretical overall energy efficiency of the cycle, with 100% and 70% heat recuperation, was calculated at 68.8% and 44.8%, respectively. In practical implementation, considering the efficiency of DRI iron reduction technology and free waste heat utilization, the cycle achieved a 41.7% efficiency. Beyond its energy storage capabilities, the Iron-chlorine cycle addresses safety concerns associated with large-scale hydrogen storage, eliminating self-discharge, reducing land usage, and employing cost-effective storage materials. This technology not only facilitates seasonal energy storage but also establishes solid-state energy reserves, making it suitable for balancing grid demands during winter months using excess renewable energy accumulated in the summer

Študije krindža

Dano študijsko gradivo v grobem predstavlja transkripcije predavanj doc. dr. Primoža Mlačnik pri prvi in skrajšani izvedbi raziskovalnega študijskega predmeta Študije krindža v jesenskem semestru 2023/2024. Vsebuje grobe prevode nekaterih ključnih del (Philips, Ahmed), člankov, pregled študij sramu, delni izvedbeni načrt, izvirno raziskovalno delo predavatelja, Powerpoint predstavitve ter nekatere skene, ki so namenjeni izključno izobraževalnim namenom. Študijsko gradivo torej ni namenjeno javni uporabi, temveč izključno rabi za pedagoške namene pri predmetu

An archaeology of photographic identification

This project returns to an early moment in the history of photographic IDs to better understand the current entrapment of our identities within what are by now massive infrastructures of automatized, unregulated and largely unauthorized identity extraction

Photoelectrochemical activation of peroxymonosulfate using Sn-doped ▫α−Fe2O3α-Fe_2O_3▫ thin film for degradation of anti-inflammatory pharmaceutical drug

Introduction of oxygen vacancies (OVs) has been investigated as a promising way to improve the electrical and catalytic characteristics of a hematite (α-Fe2O3) based photoelectrode. In this work, we develop a novel method for preparing porous Sn-doped α-Fe2O3 (Sn:Fe2O3) thin films with intrinsic OVs. The procedure included spin- coating an iron precursor onto a fluorine-doped tin oxide (FTO) substrate, followed by thermal treatment at elevated temperatures. The influence of Sn dopant on the optoelectronic properties of α-Fe2O3 was demonstrated by X-ray photoelectron spectroscopy and photoelectrochemical (PEC) measurements. The combined effect of OVs and Sn doping was found to play a synergistic role in reducing the charge recombination’s. The Sn:Fe2O3 photoanodes were used as a dual catalyst to oxidise water and break down an anti-inflammatory drug called 2-(4- isobutylphenyl)propanoic acid (IBPA). The Sn:Fe2O3 thin film with a 30-minute heat treatment time displayed the highest incident photon-to-current efficiency. For the first time, Sn:Fe2O3 thin films were utilised in the effective PEC degradation of IBPA employing peroxymonosulfate (PMS) under visible light illumination. The hydroxyl radicals (•OH), singlet oxygen (1O2), photogenerated holes (h+), and sulfate radicals (SO4 • ) were discovered to be the main reactive species during PEC degradation. IBPA degradation and the formation of new compounds were verified using liquid chromatography-mass spectrometry. The Lepidium sativum L phytotoxicity test reveals that PEC-treated wastewater with IBPA exhibits decreased toxicity

Investigation of multi-messenger properties of FR0 radio galaxy emitted ultra-high energy cosmic rays

Low luminosity Fanaroff-Riley type 0 (FR0) radio galaxies are amongst potential contributors to the observed flux of ultra-high energy cosmic rays (UHECRs). Due to FR0s’ much higher abundance in the local universe than more powerful radio galaxies (e.g., about five times more ubiquitous at redshifts z≤0.05 than FR1s), they could provide a substantial fraction of the total UHECR energy density. In the presented work, we determine the mass composition and energy spectrum of UHECRs emitted by FR0 sources by fitting simulation results from the CRPropa3 framework to the recently published Pierre Auger Observatory data. The resulting emission spectral characteristics (spectral indices, rigidity cutoffs) and elemental group fractions are compared to the Auger results. The FR0 simulations include the approximately isotropic distribution of FR0s extrapolated from the measured FR0 galaxy properties and various extragalactic magnetic field configurations, including random and large-scale structured fields. We predict the fluxes of secondary photons and neutrinos produced during UHECR propagation through cosmic photon backgrounds. The presented results allow for probing the properties of the FR0 radio galaxies as cosmic-ray sources using observational high-energy multi-messenger data