Homogeneous and heterogeneous chemistry along air parcel trajectories

The study of coupled heterogeneous and homogeneous chemistry due to polar stratospheric clouds (PSC's) using Lagrangian parcel trajectories for interpretation of the Airborne Arctic Stratosphere Experiment (AASE) is discussed. This approach represents an attempt to quantitatively model the physical and chemical perturbation to stratospheric composition due to formation of PSC's using the fullest possible representation of the relevant processes. Further, the meteorological fields from the United Kingdom Meteorological office global model were used to deduce potential vorticity and inferred regions of PSC's as an input to flight planning during AASE

MEVTV Workshop on Nature and Composition of Surface Units on Mars

Topics addressed include: SNC meteorites and their potential for providing information about the geochemical evolution of Mars; remote sensing; photogeological inferences of Martian surface compositions; and interactions of the surface with volatiles in either the surface or the atmosphere

Daytime ClO over McMurdo in September 1987: Altitude profile retrieval accuracy

During the 1987 National Ozone Expedition, mm-wave emission line spectra of the 278.6 GHz rotational stratospheric ClO were observed at McMurdo Station, Antarctica. The results confirm the 1986 discovery of a lower stratospheric layer with approximately 100 times the normal amount of ClO; the 1987 observations, made with a spectrometer bandwidth twice that used in 1986, make possible a more accurate retrieval of the altitude profile of the low altitude component of stratospheric ClO from the pressure broadened line shape, down to approximately 16 km. The accuracy of the altitude profile retrievals is discussed, using the daytime (09:30 to 19:30, local time) data from 20 to 24 September, 1987 as an example. The signal strength averaged over this daytime period is approx. 85 percent of the midday peak value. The rate of ozone depletion implied by the observed ClO densities is also discussed

Quantitative observations of the behavior of anomalous low altitude ClO in the Antarctic spring Stratosphere, 1987

During the second National Ozone Expedition ground-based observations at McMurdo Station Antarctica were performed which resulted in a second season's measurement of abnormally large amounts of ClO in the Antarctic spring stratosphere. The original measurements of 1986, in which the presence of this anomalous layer was first discovered, were limited in low altitude recovery of the ClO mixing ratio profile by the restrictions of the spectral bandwidth (256 MHz) which was used to measure the pressure-broadened ClO emission line shape. The 1987 measurements were marked by the use of twice the spectral bandpass employed the previous year, and allow a better characterization of the ClO mixing ratio profile in the critical altitude range 18 to 25 km. In-situ aircraft measurements of ClO made over the Palmer Peninsula during Aug. and Sept. of 1987 by Anderson, et al. effectively determined the important question of the ClO mixing ratio profile at altitudes inaccessible to our technique, below approximately 18 to 18.5 km. These flights did not penetrate further than 75 deg S, however, (vs 78 deg S for McMurdo) and were thus limited to coverage near the outer boundaries of the region of severest ozone depletion over Antarctica in 1987, did not reach an altitude convincingly above that of the peak mixing ratio for ClO, and were not able to make significant observations of the diurnal variation of ClO. The two techniques, and the body of data recovered by each, thus complement one another in producing a full picture of the anomalous ClO layer intimately connected with the region of Antarctic spring ozone depletion. An analysis is presented of the mixing ratio profile from approximately 18 to 45 km, the diurnal behavior, and the secular change in ClO over McMurdo Station during Sept. and early Oct. 1987

Ground-based measurements of O3, NO2, OClO, and BrO during the 1987 Antarctic ozone depletion event

Near-ultraviolet absorption spectroscopy in the wavelength range from 330 to 370 nm was used to measure O3, NO2, OClO, and BrO at McMurdo Station (78S) during 1987. Visible absorption measurements of O3, NO2, and OClO were also obtained using the wavelength range from about 403 to 453 nm. These data are described and compared to observations obtained in 1986. It is shown that comparisons of observations in the two wavelength ranges provide a sensitive measure of the altitude where the bulk of atmospheric absorption takes place

Visible and near-ultraviolet spectroscopy at Thule AFB (76.5 N) from January 28 - February 15, 1988

Near-ultraviolet and visible spectrographs identical to those employed at McMurdo Station, Antarctica (77.8 S) during the austral spring seasons of 1986 and 1987 were used to study the stratosphere above Thule, Greenland (76.5 N) during early spring, 1988. Observations were carried out both at night using the direct moon as a light source, and during the day by collecting the scattered light from the zenith sky when solar zenith angles were less than about 94.5 degrees. Excellent meteorological conditions prevailed in the troposphere and stratosphere at Thule. Surface weather was extremely clear over most of the period, facilitating measurements of the direct light from the moon. The lower stratospheric arctic polar vortex was located very near Thule throughout the observing period, and temperature at the 30 mbar level were typically below -80 C above Thule, according to the National Meteorological Center daily analyses. Thus conditions were favorable for polar stratospheric cloud formation above Thule. Total column ozone abundances were about 350 to 400 Dobson units, and did not suggest a clear temporal trend over the observing period. Stratospheric nitrogen dioxide measurements were complicated by the presence of a large component of tropospheric pollution on many occasions. Stratospheric nitrogen dioxide could be identified on most days using the absorption in the scattered light from the zenith sky, which greatly enhances the stratospheric airmass while suppressing the tropospheric contribution. These measurements suggest that the total vertical column abundance of nitrogen dioxide present over Thule in February was extremely low, sometimes as low as 3 x 10 to the 14th per sq cm. The abundance of nitrogen dioxide increased systemically from about 3 x 10 to the 14th in late January to 1.0 x 10 to the 15th per sq cm in mid-February, perhaps because of photolysis of N2O5 in the upper part of the stratosphere, near 25 to 35 km

Application of remote sensing to state and regional problems

The methods and procedures used, accomplishments, current status, and future plans are discussed for each of the following applications of LANDSAT in Mississippi: (1) land use planning in Lowndes County; (2) strip mine inventory and reclamation; (3) white-tailed deer habitat evaluation; (4) remote sensing data analysis support systems; (5) discrimination of unique forest habitats in potential lignite areas; (6) changes in gravel operations; and (7) determining freshwater wetlands for inventory and monitoring. The documentation of all existing software and the integration of the image analysis and data base software into a single package are now considered very high priority items

Polar ozone

The observation and interpretation of a large, unexpected ozone depletion over Antarctica has changed the international scientific view of stratospheric chemistry. The observations which show the veracity, seasonal nature, and vertical structure of the Antarctic ozone hole are presented. Evidence for Arctic and midlatitude ozone loss is also discussed. The chemical theory for Antarctic ozone depletion centers around the occurrence of polar stratospheric clouds (PSCs) in Antarctic winter and spring; the climatology and radiative properties of these clouds are presented. Lab studies of the physical properties of PSCs and the chemical processes that subsequently influence ozone depletion are discussed. Observations and interpretation of the chemical composition of the Antarctic stratosphere are described. It is shown that the observed, greatly enhanced abundances of chlorine monoxide in the lower stratosphere are sufficient to explain much if not all of the ozone decrease. The dynamic meteorology of both polar regions is given, interannual and interhemispheric variations in dynamical processes are outlined, and their likely roles in ozone loss are discussed