539 research outputs found
Motorcycle helmets: what about their coating?
In traffic accidents involving motorcycles, paint traces can be transferred from the rider's helmet or smeared onto its surface. These traces are usually in the form of chips or smears and are frequently collected for comparison purposes. This research investigates the physical and chemical characteristics of the coatings found on motorcycles helmets. An evaluation of the similarities between helmet and automotive coating systems was also performed.Twenty-seven helmet coatings from 15 different brands and 22 models were considered. One sample per helmet was collected and observed using optical microscopy. FTIR spectroscopy was then used and seven replicate measurements per layer were carried out to study the variability of each coating system (intravariability). Principal Component Analysis (PCA) and Hierarchical Cluster Analysis (HCA) were also performed on the infrared spectra of the clearcoats and basecoats of the data set.
The most common systems were composed of two or three layers, consistently involving a clearcoat and basecoat. The coating systems of helmets with composite shells systematically contained a minimum of three layers. FTIR spectroscopy results showed that acrylic urethane and alkyd urethane were the most frequent binders used for clearcoats and basecoats. A high proportion of the coatings were differentiated (more than 95%) based on microscopic examinations. The chemical and physical characteristics of the coatings allowed the differentiation of all but one pair of helmets of the same brand, model and color. Chemometrics (PCA and HCA) corroborated classification based on visual comparisons of the spectra and allowed the study of the whole data set at once (i.e., all spectra of the same layer). Thus, the intravariability of each helmet and its proximity to the others (intervariability) could be more readily assessed. It was also possible to determine the most discriminative chemical variables based on the study of the PCA loadings. Chemometrics could therefore be used as a complementary decision-making tool when many spectra and replicates have to be taken into account.
Similarities between automotive and helmet coating systems were highlighted, in particular with regard to automotive coating systems on plastic substrates (microscopy and FTIR). However, the primer layer of helmet coatings was shown to differ from the automotive primer. If the paint trace contains this layer, the risk of misclassification (i.e., helmet versus vehicle) is reduced. Nevertheless, a paint examiner should pay close attention to these similarities when analyzing paint traces, especially regarding smears or paint chips presenting an incomplete layer system
Discussion on how to implement a verbal scale in a forensic laboratory: benefits, pitfalls and suggestions to avoid misunderstandings
In a recently published guideline for evaluative reporting in forensic science, the European Network of Forensic Science Institutes (ENFSI) recommended the use of the likelihood ratio for the measurement of the value of forensic results. As a device to communicate the probative value of the results, the ENFSI guideline mentions the possibility to define and use a verbal scale, which should be unified within a forensic institution. This paper summarizes discussions held between scientists of our institution to develop and implement such a verbal scale. It intends to contribute to general discussions likely to be faced by any forensic institution that engages in continuous monitoring and improving of their evaluation and reporting format. We first present published arguments in favour of the use of such verbal qualifiers. We emphasize that verbal qualifiers do not replace the use of numbers to evaluate forensic findings, but are useful to communicate the probative value, since the weight of evidence in terms of likelihood ratio are still apprehended with difficulty by both the forensic scientists, especially in absence of hard data, and the recipient of information. We further present arguments that support the development of the verbal scale we propose. Recognising the limits of the use of such a verbal scale, we then discuss its disadvantages: it may lead to the spurious view according to which the value of the observations made in a given case is relative to other cases. Verbal qualifiers are also prone to misunderstandings and cannot be coherently combined with other evidence. We therefore recommend not using the verbal qualifier alone in a written statement. While scientists should only report on the probability of the findings - and not on the probability of the propositions, which are the duty of the Court - we suggest showing examples to let the recipient of information understand how the scientific evidence affects the probabilities of the propositions. To avoid misunderstandings, we also advise to mention in the statement what the results do not mean. Finally, we are of the opinion that if experts were able to coherently articulate numbers, and if recipients of information could properly handle such numbers, then verbal qualifiers could be abandoned completely. At that time, numerical expressions of probative value will be appropriately understood, as other numerical measures that most of us understand without the need of any further explanation, such as expressions for length or temperature
Toward Forecasting Volcanic Eruptions using Seismic Noise
During inter-eruption periods, magma pressurization yields subtle changes of
the elastic properties of volcanic edifices. We use the reproducibility
properties of the ambient seismic noise recorded on the Piton de la Fournaise
volcano to measure relative seismic velocity variations of less than 0.1 % with
a temporal resolution of one day. Our results show that five studied volcanic
eruptions were preceded by clearly detectable seismic velocity decreases within
the zone of magma injection. These precursors reflect the edifice dilatation
induced by magma pressurization and can be useful indicators to improve the
forecasting of volcanic eruptions.Comment: Supplementary information:
http://www-lgit.obs.ujf-grenoble.fr/~fbrengui/brenguier_SI.pdf Supplementary
video:
http://www-lgit.obs.ujf-grenoble.fr/~fbrengui/brenguierMovieVolcano.av
Summer extreme cyclone impacts on arctic sea ice
In this study the impact of extreme cyclones on Arctic sea ice in summer is investigated. Examined in particular are relative thermodynamic and dynamic contributions to sea ice volume budgets in the vicinity of Arctic summer cyclones in 2012 and 2016. Results from this investigation illustrate that sea ice loss in the vicinity of the cyclone trajectories during each year was associated with different dominant processes: thermodynamic processes (melting) in the Pacific sector of the Arctic in 2012, and both thermodynamic and dynamic processes in the Pacific sector of the Arctic in 2016. Comparison of both years further suggests that the Arctic minimum sea ice extent is influenced by not only the strength of the cyclone, but also by the timing and location relative to the sea ice edge. Located near the sea ice edge in early August in 2012, and over the central Arctic later in August in 2016, extreme cyclones contributed to comparable sea ice area (SIA) loss, yet enhanced sea ice volume loss in 2012 relative to 2016. Central to a characterization of extreme cyclone impacts on Arctic sea ice from the perspective of thermodynamic and dynamic processes, we present an index describing relative thermodynamic and dynamic contributions to sea ice volume changes. This index helps to quantify and improve our understanding of initial sea ice state and dynamical responses to cyclones in a rapidly warming Arctic, with implications for seasonal ice forecasting, marine navigation, coastal community infrastructure, and designation of protected and ecologically sensitive marine zones
Low loss coatings for the VIRGO large mirrors
présentée par L. PinardThe goal of the VIRGO program is to build a giant Michelson type interferometer (3 kilometer long arms) to detect gravitational waves. Large optical components (350 mm in diameter), having extremely low loss at 1064 nm, are needed. Today, the Ion beam Sputtering is the only deposition technique able to produce optical components with such performances. Consequently, a large ion beam sputtering deposition system was built to coat large optics up to 700 mm in diameter. The performances of this coater are described in term of layer uniformity on large scale and optical losses (absorption and scattering characterization). The VIRGO interferometer needs six main mirrors. The first set was ready in June 2002 and its installation is in progress on the VIRGO site (Italy). The optical performances of this first set are discussed. The requirements at 1064 nm are all satisfied. Indeed, the absorption level is close to 1 ppm (part per million), the scattering is lower than 5 ppm and the R.M.S. wavefront of these optics is lower than 8 nm on 150 mm in diameter. Finally, some solutions are proposed to further improve these performances, especially the absorption level (lower than 0.1 ppm) and the mechanical quality factor Q of the mirrors (thermal noise reduction)
Plant growth environments with programmable relative humidity and homogeneous nutrient availability
We describe the design, characterization, and use of “programmable”, sterile growth environments for individual (or small sets of) plants. The specific relative humidities and nutrient availability experienced by the plant is established (RH between 15% and 95%; nutrient concentration as desired) during the setup of the growth environment, which takes about 5 minutes and <1$ in disposable cost. These systems maintain these environmental parameters constant for at least 14 days with minimal intervention (one minute every two days). The design is composed entirely of off-the-shelf components (e.g., LEGO® bricks) and is characterized by (i) a separation of root and shoot environment (which is physiologically relevant and facilitates imposing specific conditions on the root system, e.g., darkness), (ii) the development of the root system on a flat surface, where the root enjoys constant contact with nutrient solution and air, (iii) a compatibility with root phenotyping.
We demonstrate phenotyping by characterizing root systems of Brassica rapa plants growing in different relative humidities (55%, 75%, and 95%). While most phenotypes were found to be sensitive to these environmental changes, a phenotype tightly associated with root system topology – the size distribution of the areas encircled by roots – appeared to be remarkably and counterintuitively insensitive to humidity changes.
These setups combine many of the advantages of hydroponics conditions (e.g., root phenotyping, complete control over nutrient composition, scalability) and soil conditions (e.g., aeration of roots, shading of roots), while being comparable in cost and setup time to Magenta® boxes
Search for non-Gaussian events in the data of the VIRGO E4 engineering run
International audienc
STE-QUEST - Test of the Universality of Free Fall Using Cold Atom Interferometry
In this paper, we report about the results of the phase A mission study of the atom
interferometer instrument covering the description of the main payload elements, the
atomic source concept, and the systematic error sources
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