Soil respiration across a variety of tree-covered urban green spaces in Helsinki, Finland

As an increasing share of the human population is being clustered in cities, urban areas have swiftly become the epicentres of anthropogenic carbon (C) emissions. Understanding different parts of the biogenic C cycle in urban ecosystems is needed in order to assess the potential to enhance their C stocks as a cost-efficient means to balance the C emissions and mitigate climate change. Here, we conducted a field measurement campaign over three consecutive growing seasons to examine soil respiration carbon dioxide (CO2) fluxes and soil organic carbon (SOC) stocks at four measurement sites in Helsinki, representing different types of tree-covered urban green space commonly found in northern European cities. We expected to find variation in the main drivers of soil respiration – soil temperature, soil moisture, and SOC – as a result of the heterogeneity of urban landscape and that this variation would be reflected in the measured soil respiration rates. In the end, we could see fairly constant statistically significant differences between the sites in terms of soil temperature but only sporadic and seemingly momentary differences in soil moisture and soil respiration. There were also statistically significant differences in SOC stocks: the highest SOC stock was found in inactively managed deciduous urban forest and the lowest under managed streetside lawn with common linden trees. We studied the impacts of the urban heat island (UHI) effect and irrigation on heterotrophic soil respiration with process-based model simulations and found that the variation created by the UHI is relatively minor compared to the increase associated with active irrigation, especially during dry summers. We conclude that, within our study area, the observed variation in soil temperature alone was not enough to cause variation in soil respiration rates between the studied green space types, perhaps because the soil moisture conditions were uniform. Thus, irrigation could potentially be a key factor in altering the soil respiration dynamics in urban green space both within the urban area and in comparison to non-urban ecosystems.</p

Factors of air ion balance in a coniferous forest according to measurements in Hyytiälä, Finland

A new mathematical model describing air ion balance was developed and tested. It has improved approximations and includes dry deposition of ions onto the forest canopy. The model leads to an explicit algebraic solution of the balance equations. This allows simple calculation of both the ionization rate and the average charge of aerosol particles from measurements of air ions and aerosol particles, with some parameters of the forest. Charged aerosol particles are distinguished from cluster ions by their size, which exceeds 1.6 nm diameter. The relative uncertainty of the ionization rate is about the same or less than the relative uncertainties of the measurements. The model was tested with specific air ion measurements carried out simultaneously at two heights at the Hyytiälä forest station, Finland. Earlier studies have shown a difference in the predictions of the ionization rate in the Hyytiälä forest when calculated in two different ways: based on the measurements of the environmental radioactivity and based on the air ion and aerosol measurements. The new model explains the difference as a consequence of neglecting dry deposition of ions in the earlier models. The ionization rate during the 16 h campaign was 5.6&plusmn;0.8 cm^&minus;3 s^&minus;1 at the height of 2 m and 3.9&plusmn;0.2 cm^&minus;3 s^&minus;1 at the height of 14 m, between the tops of the trees. The difference points out the necessity to consider the height variation when the ionization rate is used as a parameter in studies of ion-induced nucleation. Additional results are some estimates of the parameters of air ion balance. The recombination sink of cluster ions on the ions of opposite polarity made up 9&ndash;13%, the sink on aerosol particles 65&ndash;69%, and the sink on forest canopy 18&ndash;26% of the total sink of cluster ions. The average lifetime of cluster ions was about 130 s for positive and about 110 s for negative ions. At the height of 2 m, about 70% of the space charge of air was carried by aerosol particles, and at the height of 14 m, about 84%

Carbon dioxide fluxes and carbon balance of an agricultural grassland in southern Finland

A significant proportion of the global carbon emissions to the atmosphere originate from agriculture. Therefore, continuous long-term monitoring of CO2 fluxes is essential to understand the carbon dynamics and balances of different agricultural sites. Here we present results from a new eddy covariance flux measurement site located in southern Finland. We measured CO2 and H2O fluxes at this agricultural grassland site for 2 years, from May 2018 to May 2020. In particular the first summer experienced prolonged dry periods, which affected the CO2 fluxes, and substantially larger fluxes were observed in the second summer. During the dry summer, leaf area index (LAI) was notably lower than in the second summer. Water use efficiency increased with LAI in a similar manner in both years, but photosynthetic capacity per leaf area was lower during the dry summer. The annual carbon balance was calculated based on the CO2 fluxes and management measures, which included input of carbon as organic fertilizers and output as yield. The carbon balance of the field was -57 +/- 10 and -86 +/- 12 g C m(-2) yr(-1) in the first and second study years, respectively.Peer reviewe

Waterfalls as sources of small charged aerosol particles

In this study, we measured the mobility distributions of cluster and intermediate ions with an ion spectrometer near a waterfall. We observed that the concentration of negative 1.5&ndash;10 nm ions was one-hundred fold higher than a reference point 100 m away from the waterfall. Also, the concentration of positive intermediate ions was found to be higher than that at the reference point by a factor of ten. This difference was observed only at the smallest sizes; above 10 nm the difference was insignificant

Relation of air mass history to nucleation events in Po Valley, Italy, using back trajectories analysis

International audienceIn this paper, we study the transport of air masses to San Pietro Capofiume (SPC) in Po Valley, Italy, by means of back trajectories analysis. Our main aim is to investigate whether air masses originate over different regions on nucleation event days and on nonevent days, during three years when nucleation events have been continuously recorded at SPC. The results indicate that nucleation events occur frequently in air masses arriving from Central Europe, whereas event frequency is much lower in the air transported from southern directions and from the Atlantic Ocean. We also analyzed the behaviour of meteorological parameters during 96 h transport to SPC, and found that, on average, event trajectories undergo stronger subsidence during the last 12 h before the arrival at SPC than nonevent trajectories. This causes a reversal in the temperature and relative humidity (RH) differences between event and nonevent trajectories: between 96 and 12 h back time, temperature is lower and RH is higher for event than nonevent trajectories and between 12 and 0 h vice versa. Boundary layer mixing is stronger along the event trajectories compared to nonevent trajectories. The absolute humidity (AH) is similar for the event and nonevent trajectories between about 96 h and about 60 h back time, but after that, the event trajectories AH becomes lower due to stronger rain. We also studied transport of SO2 to SPC, and conclude that although sources in Po Valley most probably dominate the measured concentrations, certain Central and Eastern European sources also make a substantial contribution

Characterization of air ions in boreal forest air during BIOFOR III campaign

International audienceThe behavior of the concentration of positive small (or cluster) air ions and naturally charged nanometer aerosol particles (aerosol ions) has been studied on the basis of measurements carried out in a boreal forest at the Hyytiälä SMEAR station, Finland, during the BIOFOR III campaign in spring 1999. Statistical characteristics of the concentrations of cluster ions, two classes of aerosol ions of the sizes of 2.5?8 nm and 8?ca 20 nm and the quantities that determine the balance of small ions in the atmosphere have been given for the nucleation event days and non-event days. The dependence of small ion concentration on the ion loss (sink) due to aerosol particles was investigated applying a model of bipolar diffusion charging of particles by small ions. The small ion concentration and the ion sink were closely correlated (correlation coefficient 87%) when the fog events and the hours of high relative humidity (above 97%), as well as nocturnal calms and weak wind (wind speed-1 had been excluded. In the case of nucleation burst events, variations in the concentration of small positive ions were in accordance with the changes caused by the ion sink due to aerosols; no clear indication of positive ion depletion by ion-induced nucleation was found. The estimated average ionization rate of air at the Hyytiälä station in early spring, when the ground was partly covered with snow, was about 4.8 ion pairs cm-3 s-1. The study of the charging state of nanometer aerosol particles (2.5?8 nm) revealed a strong correlation (correlation coefficient 88%) between the concentrations of particles and their charged fraction (positive air ions) during nucleation bursts. The estimated charged fraction of particles, which varied from 3% to 6% considering various nucleation event days, confirms that these particles are almost quasi-steady state charged. Also the particles and air ions in the size range of 8?ca 20 nm showed a good qualitative consistency; the correlation coefficient was 92%

An improved criterion for new particle formation in diverse atmospheric environments

A dimensionless theory for new particle formation (NPF) was developed, using an aerosol population balance model incorporating recent developments in nucleation rates and measured particle growth rates. Based on this theoretical analysis, it was shown that a dimensionless parameter &lt;i&gt;L&lt;/i&gt;&lt;sub&gt;&amp;Gamma;&lt;/sub&gt;, characterizing the ratio of the particle scavenging loss rate to the particle growth rate, exclusively determined whether or not NPF would occur on a particular day. This parameter determines the probability that a nucleated particle will grow to a detectable size before being lost by coagulation with the pre-existing aerosol. Cluster-cluster coagulation was shown to contribute negligibly to this survival probability under conditions pertinent to the atmosphere. Data acquired during intensive measurement campaigns in Tecamac (MILAGRO), Atlanta (ANARChE), Boulder, and Hyytiälä (QUEST II, QUEST IV, and EUCAARI) were used to test the validity of &lt;i&gt;L&lt;/i&gt;&lt;sub&gt;&amp;Gamma;&lt;/sub&gt; as an NPF criterion. Measurements included aerosol size distributions down to 3 nm and gas-phase sulfuric acid concentrations. The model was applied to seventy-seven NPF events and nineteen non-events (characterized by growth of pre-existing aerosol without NPF) measured in diverse environments with broad ranges in sulfuric acid concentrations, ultrafine number concentrations, aerosol surface areas, and particle growth rates (nearly two orders of magnitude). Across this diverse data set, a nominal value of &lt;i&gt;L&lt;/i&gt;&lt;sub&gt;&amp;Gamma;&lt;/sub&gt;=0.7 was found to determine the boundary for the occurrence of NPF, with NPF occurring when &lt;i&gt;L&lt;/i&gt;&lt;sub&gt;&amp;Gamma;&lt;/sub&gt;&lt;0.7 and being suppressed when &lt;i&gt;L&lt;/i&gt;&lt;sub&gt;&amp;Gamma;&lt;/sub&gt;&gt;0.7. Moreover, nearly 45% of measured &lt;i&gt;L&lt;/i&gt;&lt;sub&gt;&amp;Gamma;&lt;/sub&gt; values associated with NPF fell in the relatively narrow range of 0.1&lt;&lt;i&gt;L&lt;/i&gt;&lt;sub&gt;&amp;Gamma;&lt;/sub&gt;&lt;0.3

Socio-Economic support for good health in rural Malawi

Objective: To study the socio-economic support for good health among subsistence farmers in rural Malawi.Design: A cross-sectional survey.Setting: Lungwena, a rural area with 17000 inhabitants in southern Malawi.Participants: Seven hundred and ninety five pregnant women who attended the antenatal clinic at Lungwena Health Centre between June 1995 and September 1996. Interventions: Interviews about socio-economic conditions. Measurements of cultivated land areas and distances between home and the local health centre. Main outcome measures: Proportion of households lacking literate adults, adequate water source and sanitation, easy access to modern health care or food security.Results: Only 14% of the interviewed women could read and write and half of the households had no literate members. Every fifth household was lacking both an access to safe drinking water and a proper sanitary facility. The distance to the health centre was more than 5 kmamong half of the households and only 37% had enough land to grow food for all family members. When other potential means of obtaining food were taken into account, 27% of the households had no food security. Numerous households were lacking more than one socioeconomic prerequisites of good health: three or more were missing from a quarter of the families.Conclusions: Socio-economic prerequisites of health were commonly missing in Lungwena. Subsequent health interventions should strengthen the investments into general poverty alleviation

Evaluating the performance of five different chemical ionization techniques for detecting gaseous oxygenated organic species

The impact of aerosols on climate and air quality remains poorly understood due to multiple factors. One of the current limitations is the incomplete understanding of the contribution of oxygenated products, generated from the gas-phase oxidation of volatile organic compounds (VOCs), to aerosol formation. Indeed, atmospheric gaseous chemical processes yield thousands of (highly) oxygenated species, spanning a wide range of chemical formulas, functional groups and, consequently, volatilities. While recent mass spectrometric developments have allowed extensive on-line detection of a myriad of oxygenated organic species, playing a central role in atmospheric chemistry, the detailed quantification and characterization of this diverse group of compounds remains extremely challenging. To address this challenge, we evaluated the capability of current state-of-the-art mass spectrometers equipped with different chemical ionization sources to detect the oxidation products formed from alpha-Pinene ozonolysis under various conditions. Five different mass spectrometers were deployed simultaneously for a chamber study. Two chemical ionization atmospheric pressure interface time-of-flight mass spectrometers (CI-APi-TOF) with nitrate and amine reagent ion chemistries and an iodide chemical ionization time-of-flight mass spectrometer (TOF-CIMS) were used. Additionally, a proton transfer reaction time-of-flight mass spectrometer (PTR-TOF 8000) and a new "vocus" PTR-TOF were also deployed. In the current study, we compared around 1000 different compounds between each of the five instruments, with the aim of determining which oxygenated VOCs (OVOCs) the different methods were sensitive to and identifying regions where two or more instruments were able to detect species with similar molecular formulae. We utilized a large variability in conditions (including different VOCs, ozone, NOx and OH scavenger concentrations) in our newly constructed atmospheric simulation chamber for a comprehensive correlation analysis between all instruments. This analysis, combined with estimated concentrations for identified molecules in each instrument, yielded both expected and surprising results. As anticipated based on earlier studies, the PTR instruments were the only ones able to measure the precursor VOC, the iodide TOF-CIMS efficiently detected many semi-volatile organic compounds (SVOCs) with three to five oxygen atoms, and the nitrate CI-APi-TOF was mainly sensitive to highly oxygenated organic (O > 5) molecules (HOMs). In addition, the vocus showed good agreement with the iodide TOF-CIMS for the SVOC, including a range of organonitrates. The amine CI-APi-TOF agreed well with the nitrate CI-APi-TOF for HOM dimers. However, the loadings in our experiments caused the amine reagent ion to be considerably depleted, causing nonlinear responses for monomers. This study explores and highlights both benefits and limitations of currently available chemical ionization mass spectrometry instrumentation for characterizing the wide variety of OVOCs in the atmosphere. While specifically shown for the case of alpha-Pinene ozonolysis, we expect our general findings to also be valid for a wide range of other VOC-oxidant systems. As discussed in this study, no single instrument configuration can be deemed better or worse than the others, as the optimal instrument for a particular study ultimately depends on the specific target of the study.Peer reviewe

First measurements of the number size distribution of 1-2nm aerosol particles released from manufacturing processes in a cleanroom environment

This study was conducted to observe a potential formation and/or release of aerosol particles related to manufacturing processes inside a cleanroom. We introduce a novel technique to monitor airborne sub 2nm particles in the cleanroom and present results from a measurement campaign during which the total particle number concentration (>1nm and >7 nm) and the size resolved concentration in the 1 to 2nm size range were measured. Measurements were carried out in locations where atomic layer deposition (ALD), sputtering, and lithography processes were conducted, with a wide variety of starting materials. During our campaign in the clean room, we observed several time periods when the particle number concentration was 10(5) cm(-3) in the sub 2nm size range and 10(4) cm(-3) in the size class larger than 7nm in one of the sampling locations. The highest concentrations were related to the maintenance processes of the manufacturing machines, which were conducted regularly in that specific location. Our measurements show that around 500cm(-3) sub 2nm particles or clusters were in practice always present in this specific cleanroom, while the concentration of particles larger than 2nm was less than 2cm(-3). During active processes, the concentrations of sub 2nm particles could rise to over 10(5) cm(-3) due to an active new particle formation. The new particle formation was most likely induced by a combination of the supersaturated vapors, released from the machines, and the very low existing condensation sink, leading to pretty high formation rates J(1.4 nm) = (9 4) cm(-3) s(-1) and growth rates of particles (GR(1.1-1.3 nm) = (6 +/- 3) nm/h and GR(1.3-1.8 nm) = (14 +/- 3) nm/h).Copyright (c) 2017 American Association for Aerosol ResearchPeer reviewe