127 research outputs found
Ethylenediamine- and propylenediaminediacetic acid derivatives as ligands for the "fac-[M(CO)3]+" core (M = Re, 99mTc)
The reaction of Re(CO)5Cl with o- or p-N-(nitrophenyl)ethylenediaminediacetic acid (H2L1, H2L2) and o- or p-N-(nitrophenyl)propylenediaminediacetic acid (H2L3, H2L4) in methanol leads to the formation of stable anionic [Et3NH][Re(CO)3(L)]·H2O complexes 1-4. These compounds have been characterized by means of IR, mass spectrometry, elemental analysis, NMR and conductimetry, as well as X-ray crystallography for 2 and 3. The [Re(CO)3]+ moiety is coordinated via the nitrogen of the iminodiacetic acid unit and two oxygens of monodentate carboxylate groups. In each case, the nitro group of the aromatic ring remains uncoordinated. The analogous technetium-99m complexes 1' and 3' were also prepared quantitatively by the reaction of H2L1 and H2L3, respectively, with the fac-[99mTc(CO)3(H2O)3]+ precursor in ethanol. The corresponding Re and 99mTc compounds were shown to possess the same structure by means of HPLC studies. The high affinity of these ligands for the Tc(I) or Re(I) core, coupled with the easiness of their derivatization (by reduction of the nitro group in amino group), implies that the utilization of this ligand system to develop target-specific radiopharmaceuticals for diagnosis and therapy is promising
Sodium [2-(mercaptomethylcarbonylamino)-N-(2-mercaptophenyl)ethanamide(4-)-[kappa]4S,N,N',S']oxorhenate(V) monohydrate
In the complex anion of the title compound, Na[Re(C10H8N2O2S2)O]·H2O, the Re atom adopts a square-pyramidal coordination, in which the Re=O bond is apical and the S,N,N,S-tetradentate ligand spans the four basal sites. The Na+ counter-ion is octahedrally surrounded by one S and five O atoms
Tetraphenylphosphonium [N-(2-aminophenyl)-2-(mercaptomethylcarbonylamino)ethanamido(4-)-[kappa]4S,N,N',N'']oxorhenate(V)
The title compound, (C24H20P)[Re(C10H9N3O2S)O], contains well separated square-pyramidal [OReL]- complex anions (L is the deprotonated N-(2-aminophenyl)-2-(mercaptomethylcarbonylamino)ethanamide ligand) and tetrahedral [(C6H5)4P]+ cations. In the anion, the Re=O bond is oriented along the apical direction and the four basal sites are occupied by one S- and three N-atom donors of the tetradentate L4- ligand
Charge-Density-Wave like Behavior in the One-Dimensional Charge-Ordered Semiconductor (NbSe4)3I
We report on broadband dielectric spectroscopy on the one-dimensional
semiconductor (NbSe4)3I. Below the structural phase transition close to 270 K
we observe colossal dielectric constants with a frequency and temperature
dependence very similar to what is observed in canonical charge-density wave
systems. Guided by structural details we interpret this structural phase
transition as driven by complex charge-order processes.Comment: 4 pages, 3 figure
Novel recoil nuclei detectors to qualify the AMANDE facility as a Standard for mono-energetic neutron fields
The AMANDE facility at IRSN-Cadarache produces mono-energetic neutron fields
from 2 keV to 20 MeV with metrological quality. To be considered as a standard
facility, characteristics of neutron field i.e fluence distribution must be
well known by a device using absolute measurements. The development of new
detector systems allowing a direct measurement of neutron energy and fluence
has started in 2006. Using the proton recoil telescope principle with the goal
of increase the efficiency, two systems with full localization are studied. A
proton recoil telescope using CMOS sensor (CMOS-RPT) is studied for
measurements at high energies and the helium 4 gaseous micro-time projection
chamber (microTPC He4) will be dedicated to the lowest energies. Simulations of
the two systems were performed with the transport Monte Carlo code MCNPX, to
choose the components and the geometry, to optimize the efficiency and
detection limits of both devices or to estimate performances expected. First
preliminary measurements realised in 2008 demonstrated the proof of principle
of these novel detectors for neutron metrology.Comment: to appear in Radiation Measurements, Proc. of 24th International
Conference on Nuclear Tracks in Solids (Bologna, 1-5 September 2008
A {\mu}-TPC detector for the characterization of low energy neutron fields
The AMANDE facility produces monoenergetic neutron fields from 2 keV to 20
MeV for metrological purposes. To be considered as a reference facility,
fluence and energy distributions of neutron fields have to be determined by
primary measurement standards. For this purpose, a micro Time Projection
Chamber is being developed to be dedicated to measure neutron fields with
energy ranging from 8 keV up to 1 MeV. In this work we present simulations
showing that such a detector, which allows the measurement of the ionization
energy and the 3D reconstruction of the recoil nucleus, provides the
determination of neutron energy and fluence of these neutron fields
Structural and Luminescence Properties of Silica-Based Hybrids Containing New Silylated-Diketonato Europium(III) Complex
A new betadiketonate ligand displaying a trimethoxysilyl group as grafting function and a diketone moiety as complexing site (TTA-Si = 4,4,4-trifluoro-2-(3-trimethoxysilyl)propyl)-1-3-butanedione (C4H3S)COCH[(CH2)3Si(OCH3)3]COCF3) and its highly luminescent europium(III) complex [Eu(TTA-Si)3] have been synthesized and fully characterized. Luminescent silica-based hybrids have been prepared as well with this new complex grafted on the surface of dense silica nanoparticles (28 (+/-3 nm) or on mesoporous
silica particles. The covalent bonding of Eu(TTA-Si)3 inside the core of uniform silica
nanoparticles (40 (+/- 5 nm) was also achieved. Luminescence properties are discussed in relation to the europium chemical environment involved in each of the three hybrids. The general methodology proposed allowed high grafting ratios and overcame chelate release and tendency to agglomeration, and it could be applied to any silica matrix (in the core or at the surface, nanosized or not, dense or mesoporous) and therefore numerous applications such as luminescent markers and luminophors could be foreseen
Bifunctional silica nanoparticles for the exploration of Pseudomonas aeruginosa biofilm
Luminescent silica nanoparticles (LSNPs) are frequently employed for biotechnology applications mainly because of easy functionalization, photo-stability and biocompatibility. Bifunctional silica nanoparticles (BSNPs) are described here as new efficient tools for the understanding of a complex biological system such as biofilms. Photoluminescence is brought by the incorporation of a silylated ruthenium(II) complex, surface properties of the silica particles are designed by reaction with. BSNPs are fully characterized and Zeta potential and contact angle measurements exhibit various surface properties according to the functional groups. Confocal Laser Scanning Microscopy measurements show that the spatial distribution of these nanoparticles inside PAO1 biofilm depends more on their hydrophilic/hydrophobic characteristics than on their size
Individual neutron monitoring in workplaces with mixed neutron/photon radiation
EVIDOS (‘evaluation of individual dosimetry in mixed neutron and photon radiation fields') is an European Commission (EC)-sponsored project that aims at a significant improvement of radiation protection dosimetry in mixed neutron/photon fields via spectrometric and dosimetric investigations in representative workplaces of the nuclear industry. In particular, new spectrometry methods are developed that provide the energy and direction distribution of the neutron fluence from which the reference dosimetric quantities are derived and compared to the readings of dosemeters. The final results of the project will be a comprehensive set of spectrometric and dosimetric data for the workplaces and an analysis of the performance of dosemeters, including novel electronic dosemeters. This paper gives an overview of the project and focuses on the results from measurements performed in calibration fields with broad energy distributions (simulated workplace fields) and on the first results from workplaces in the nuclear industry, inside a boiling water reactor and around a spent fuel transport cas
The Hubble PanCET program: The near-ultraviolet transmission spectrum of WASP-79b
We present Hubble Space Telescope (HST) transit observations of the
Hot-Jupiter WASP-79b acquired with the Space Telescope Imaging Spectrograph
(STIS) in the near ultraviolet (NUV). Two transit observations, part of the
PanCET program, are used to obtain the transmission spectra of the planet
between 2280 and 3070{\AA}. We correct for systematic effects in the raw data
using the jitter engineering parameters and polynomial modelling to fit the
white light curves of the two transits. We observe an increase in the
planet-to-star radius ratio at short wavelengths, but no spectrally resolved
absorption lines. The difference between the radius ratios at 2400 and
3000{\AA} reaches (4.5). Although the NUV
transmission spectrum does not show evidence of hydrodynamical escape, the
strong atmospheric features are likely due to species at very high altitudes.
We performed a 1D simulation of the temperature and composition of WASP-79b
using Exo-REM. The temperature pressure profile crosses condensation curves of
radiatively active clouds, particularly MnS, MgSiO, Fe, and
AlO. Still, none of these species produces the level of observed
absorption at short wavelengths and can explain the observed increase in the
planet's radius. WASP-79b's transit depth reaches 23 scale height, making it
one of the largest spectral features observed in an exoplanet at this
temperature (1700 K). The comparison of WASP-79b's transmission spectrum
with three warmer hot Jupiters shows a similar level of absorption to WASP-178b
and WASP-121b between 0.2 and 0.3m, while HAT-P-41b's spectrum is flat.
The features could be explained by SiO absorption.Comment: Accepted for publication January 31, 2023 in the Journal Astronomy &
Astrophysic
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