The effect of asymmetry of the coil block on self-assembly in ABC coil-rod-coil triblock copolymers

Using the self-consistent field approach, the effect of asymmetry of the coil block on the microphase separation is focused in ABC coil-rod-coil triblock copolymers. For different fractions of the rod block $f_{\text B}$, some stable structures are observed, i.e., lamellae, cylinders, gyroid, and core-shell hexagonal lattice, and the phase diagrams are constructed. The calculated results show that the effect of the coil block fraction $f_{\text A}$ is dependent on $f_{\text B}$. When $f_{\text B}=0.2$, the effect of asymmetry of the coil block is similar to that of the ABC flexible triblock copolymers; When $f_{\text B}=0.4$, the self-assembly of ABC coil-rod-coil triblock copolymers behaves like rod-coil diblock copolymers under some condition. When $f_{\text B}$ continues to increase, the effect of asymmetry of the coil block reduces. For $f_{\text B}=0.4$, under the symmetrical and rather asymmetrical conditions, an increase in the interaction parameter between different components leads to different transitions between cylinders and lamellae. The results indicate some remarkable effect of the chain architecture on self-assembly, and can provide the guidance for the design and synthesis of copolymer materials.Comment: 9 pages, 3 figure

Self-gravitating Yang Monopoles in all Dimensions

The (2k+2)-dimensional Einstein-Yang-Mills equations for gauge group SO(2k) (or SU(2) for k=2 and SU(3) for k=3) are shown to admit a family of spherically-symmetric magnetic monopole solutions, for both zero and non-zero cosmological constant Lambda, characterized by a mass m and a magnetic-type charge. The k=1 case is the Reissner-Nordstrom black hole. The k=2 case yields a family of self-gravitating Yang monopoles. The asymptotic spacetime is Minkowski for Lambda=0 and anti-de Sitter for Lambda<0, but the total energy is infinite for k>1. In all cases, there is an event horizon when m>m_c, for some critical mass $m_c$, which is negative for k>1. The horizon is degenerate when m=m_c, and the near-horizon solution is then an adS_2 x S^{2k} vacuum.Comment: 16 pp. Extensive revision to include case of non-zero cosmological constant and implications for adS/CFT. Numerous additional reference

A systematic study of Zr and Sn isotopes in the Relativistic Mean Field theory

The ground-state properties of Zr and Sn isotopes are studied within the relativistic mean field theory. Zr and Sn isotopes have received tremendous attention due to various reasons, including the predicted giant halos in the neutron-rich Zr isotopes, the unique feature of being robustly spherical in the region of $^{100}$Sn $\sim$ $^{132}$Sn and the particular interest of Sn isotopes to nuclear astrophysics. Furthermore, four (semi-) magic neutron numbers, 40, 50, 82 and 126, make these two isotopic chains particularly important to test the pairing correlations and the deformations in a microscopic model. In the present work, we carry out a systematic study of Zr and Sn isotopes from the proton drip line to the neutron drip line with deformation effects, pairing correlations and blocking effects for nuclei with odd number of neutrons properly treated. A constrained calculation with quadrupole deformations is performed to find the absolute minimum for each nucleus on the deformation surface. All ground-state properties, including the separation energies, the odd-even staggerings, the nuclear radii, the deformations and the single-particle spectra are analyzed and discussed in detail.Comment: the final version to appear in Modern Physics Letters A. more figures, discussions, and references added. the data remain unchange

Spurious Shell Closures in the Relativistic Mean Field Model

Following a systematic theoretical study of the ground-state properties of over 7000 nuclei from the proton drip line to the neutron drip line in the relativistic mean field model [Prog. Theor. Phys. 113 (2005) 785], which is in fair agreement with existing experimental data, we observe a few spurious shell closures, i.e. proton shell closures at Z=58 and Z=92. These spurious shell closures are found to persist in all the effective forces of the relativistic mean field model, e.g. TMA, NL3, PKDD and DD-ME2.Comment: 3 pages, to appear in Chinese Physics Letter

The stability and the shape of the heaviest nuclei

In this paper, we report a systematic study of the heaviest nuclei within the relativistic mean field (RMF) model. By comparing our results with those of the Hartree-Fock-Bogoliubov method (HFB) and the finite range droplet model (FRDM), the stability and the shape of the heaviest nuclei are discussed. The theoretical predictions as well as the existing experimental data indicate that the experimentally synthesized superheavy nuclei are in between the fission stability line, the line connecting the nucleus with maximum binding energy per nucleon in each isotopic chain, and the $\beta$-stability line, the line connecting the nucleus with maximum binding energy per nucleon in each isobaric chain. It is shown that both the fission stability line and the $\beta$-stability line tend to be more proton rich in the superheavy region. Meanwhile, all the three theoretical models predict most synthesized superheavy nuclei to be deformed.Comment: 6 pages, 7 figures, to appear in Journal of Physics

First order shape transition and critical point nuclei in Sm isotopes from relativistic mean field approach

The critical point nuclei in Sm isotopes, which marks the first order phase transition between spherical U(5) and axially deformed shapes SU(3), have been investigated in the microscopic quadrupole constrained relativistic mean field (RMF) model plus BCS method with all the most used interactions, i.e., NL1, NL3, NLSH and TM1. The calculated potential energy surfaces show a clear shape transition for the even-even Sm isotopes with $N = 82\sim 96$ and the critical point nuclei are found to be $^{148}$Sm, $^{150}$Sm and $^{152}$Sm. Similar conclusions can also be drawn from the microscopic neutron and proton single particle spectra.Comment: 6 figure

Pressure dependence of the superconducting transition and electron correlations in Na_xCoO_2 \cdot 1.3H_2O

We report T_c and ^{59}Co nuclear quadrupole resonance (NQR) measurements on the cobalt oxide superconductor Na_{x}CoO_{2}\cdot 1.3H_{2}O (T_c=4.8 K) under hydrostatic pressure (P) up to 2.36 GPa. T_c decreases with increasing pressure at an average rate of -0.49\pm0.09 K/GPa. At low pressures P\leq0.49 GPa, the decrease of T_c is accompanied by a weakening of the spin correlations at a finite wave vector and a reduction of the density of states (DOS) at the Fermi level. At high pressures above 1.93 GPa, however, the decrease of T_c is mainly due to a reduction of the DOS. These results indicate that the electronic/magnetic state of Co is primarily responsible for the superconductivity. The spin-lattice relaxation rate 1/T_1 at P=0.49 GPa shows a T^3 variation below T_c down to T\sim 0.12T_c, which provides compelling evidence for the presence of line nodes in the superconducting gap function.Comment: published on 19, Sept. 2007 on Phys. Rev.