Laboratory and tentative interstellar detection of trans-methyl formate using the publicly available Green Bank Telescope PRIMOS survey

The rotational spectrum of the higher-energy trans conformational isomer of methyl formate has been assigned for the first time using several pulsed-jet Fourier transform microwave spectrometers in the 6-60 GHz frequency range. This species has also been sought toward the Sagittarius B2(N) molecular cloud using the publicly available PRIMOS survey from the Green Bank Telescope. We detect seven absorption features in the survey that coincide with laboratory transitions of trans-methyl formate, from which we derive a column density of 3.1 (+2.6, -1.2) \times 10^13 cm-2 and a rotational temperature of 7.6 \pm 1.5 K. This excitation temperature is significantly lower than that of the more stable cis conformer in the same source but is consistent with that of other complex molecular species recently detected in Sgr B2(N). The difference in the rotational temperatures of the two conformers suggests that they have different spatial distributions in this source. As the abundance of trans-methyl formate is far higher than would be expected if the cis and trans conformers are in thermodynamic equilibrium, processes that could preferentially form trans-methyl formate in this region are discussed. We also discuss measurements that could be performed to make this detection more certain. This manuscript demonstrates how publicly available broadband radio astronomical surveys of chemically rich molecular clouds can be used in conjunction with laboratory rotational spectroscopy to search for new molecules in the interstellar medium.Comment: 40 pages, 7 figures, 4 tables; accepted for publication in Ap

Spatial distribution of low-energy plasma around 2 comet 67P/CG from Rosetta measurements

International audienceWe use measurements from the Rosetta plasma consortium (RPC) Langmuir probe (LAP) and mutual impedance probe (MIP) to study the spatial distribution of low-energy plasma in the near-nucleus coma of comet 67P/Churyumov-Gerasimenko. The spatial distribution is highly structured with the highest density in the summer hemisphere and above the region connecting the two main lobes of the comet, i.e. the neck region. There is a clear correlation with the neutral density and the plasma to neutral density ratio is found to be ∼1-2·10 −6 , at a cometocentric distance of 10 km and at 3.1 AU from the sun. A clear 6.2 h modulation of the plasma is seen as the neck is exposed twice per rotation. The electron density of the collisonless plasma within 260 km from the nucleus falls of with radial distance as ∼1/r. The spatial structure indicates that local ionization of neutral gas is the dominant source of low-energy plasma around the comet

Effective ion speeds at ~200–250 km from comet 67P/Churyumov–Gerasimenko near perihelion

In 2015 August, comet 67P/Churyumov–Gerasimenko, the target comet of the ESA Rosetta mission, reached its perihelion at ~1.24 au. Here, we estimate for a three-day period near perihelion, effective ion speeds at distances ~200–250 km from the nucleus. We utilize two different methods combining measurements from the Rosetta Plasma Consortium (RPC)/Mutual Impedance Probe with measurements either from the RPC/Langmuir Probe or from the Rosetta Orbiter Spectrometer for Ion and Neutral Analysis (ROSINA)/Comet Pressure Sensor (COPS) (the latter method can only be applied to estimate the effective ion drift speed). The obtained ion speeds, typically in the range 2–8 km s⁻¹, are markedly higher than the expected neutral outflow velocity of ~1 km s⁻¹. This indicates that the ions were de-coupled from the neutrals before reaching the spacecraft location and that they had undergone acceleration along electric fields, not necessarily limited to acceleration along ambipolar electric fields in the radial direction. For the limited time period studied, we see indications that at increasing distances from the nucleus, the fraction of the ions’ kinetic energy associated with radial drift motion is decreasing

Evaluating Local Ionization Balance in the Nightside Martian Upper Atmosphere during MAVEN Deep Dip Campaigns

Combining the Mars Atmosphere and Volatile Evolution (MAVEN) measurements of atmospheric neutral and ion densities, electron temperature, and energetic electron intensity, we perform the first quantitative evaluation of local ionization balance in the nightside Martian upper atmosphere, a condition with the electron impact ionization (EI) of CO2 exactly balanced by the dissociative recombination (DR) of ambient ions. The data accumulated during two MAVEN Deep Dip (DD) campaigns are included: DD6 on the deep nightside with a periapsis solar zenith angle (SZA) of 165 degrees, and DD3 close to the dawn terminator with a periapsis SZA of 110 degrees. With the electron temperatures at low altitudes corrected for an instrumental effect pertaining to the MAVEN Langmuir Probe and Waves, a statistical agreement between the EI and DR rates is suggested by the data below 140 km during DD6 and below 180 km during DD3, implying that electron precipitation is responsible for the nightside Martian ionosphere under these circumstances and extra sources are not required. In contrast, a substantial enhancement in EI over DR is observed at higher altitudes during both campaigns, which we interpret as a signature of plasma escape down the tail.Strategic Priority Research Program of the Chinese Academy of Sciences [XDA17010201]; National Science Foundation of China [41525015, 41774186, 41525016]; National Aeronautics and Space Administration; Swedish National Space Agency [135/13, 166/14]; Swedish Research Council [621-2013-4191]This item from the UA Faculty Publications collection is made available by the University of Arizona with support from the University of Arizona Libraries. If you have questions, please contact us at [email protected]

The Morphology of the Topside Martian Ionosphere: Implications on Bulk Ion Flow

Prior to the Mars Atmosphere and Volatile Evolution mission, the only information on the composition of the Martian ionosphere came from the Viking Retarding Potential Analyzer data, revealing the presence of substantial ion outflow on the dayside of Mars. Extensive measurements made by the Mars Atmosphere and Volatile Evolution Neutral Gas and Ion Mass Spectrometer allow us to examine the morphology of the Martian ionosphere not only in unprecedented detail but also on both the dayside and the nightside of the planet. Above 300km, various ionospheric species present a roughly constant density scale height around 100km on the dayside and 180km on the nightside. An evaluation of the ion force balance, appropriate for regions with near-horizontal magnetic field lines, suggests the presence of supersonic ion outflow predominantly driven by the ambient magnetic pressure, with characteristic dayside and nightside flow velocities of 4 and 20km/s, respectively, both referred to an altitude of 500km. The corresponding total ion outflow rates are estimated to be 5x10(25)s(-1) on the dayside and 1x10(25)s(-1) on the nightside. The data also indicate a prominent variation with magnetic field orientation in that the ion distribution over regions with near-vertical field lines tends to be more extended on the dayside but more concentrated on the nightside, as compared to regions with near-horizontal field lines. These observations should have important implications on the pattern of ion dynamics in the vicinity of Mars. Plain Language Summary Prior to the Mars Atmosphere and Volatile Evolution mission, the only information on the composition of the Martian ionosphere came from the Viking Retarding Potential Analyzer data acquired on the dayside of Mars. Recently, extensive measurements made by the Mars Atmosphere and Volatile Evolution Neutral Gas and Ion Mass Spectrometer allow us to examine the Martian ionosphere not only in unprecedented detail but also on both the dayside and the nightside of the planet. By analyzing these data, we find that on each side, many of the detected ion species share a common density structure at altitudes above 300km. Meanwhile, such a structure is clearly influenced by the ambient magnetic fields, which are well known to be inhomogeneous on Mars and cluster over the Southern Hemisphere. Near strong magnetic fields, the Martian ionosphere tends to be more extended on the dayside but more concentrated on the nightside. These findings reveal the presence of supersonic ion outflow on Mars. Such an ion outflow makes a significant contribution to plasma escape, which influences the long-term evolution of the planet.National Natural Science Foundation of China [41525015, 41774186, 41525016]; Science and Technology Development Fund of Macau SAR [039/2013/A2, 119/2017/A3]; National Aeronautics and Space Administration (NASA); Swedish National Space Agency [135/13, 166/14]; Swedish Research Council (VR grant) [621-2013-4191]6 month embargo; published online: 13 February 2019This item from the UA Faculty Publications collection is made available by the University of Arizona with support from the University of Arizona Libraries. If you have questions, please contact us at [email protected]

Manifestations of Culture in Website Design

The web is a global phenomenon and its reach and influence ignores political and cultural boundaries. However, the web’s global presence and easy accessibility does not also mean there are no issues related to the understanding and interpretations of its content. Of particular interest to us is to find out whether there is any effect of culture on web design. In this paper, we report on our research into the identification of elements that can be attributed to culture on website design. We examined and compared South Korean and UK’s charity websites and identified these elements of the websites. The findings suggest that there are some differences and preferences in the website design that are mostly related to whether the websites employ multimedia and provide facilities for user input. <!--EndFragment--