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Peter R Mansfield, Barbara Mintzes and Dee Richard

First-principles study of ternary fcc solution phases from special quasirandom structures

In the present work, ternary Special Quasirandom Structures (SQSs) for a fcc solid solution phase are generated at different compositions, $x_A=x_B=x_C=\tfrac{1}{3}$ and $x_A=\tfrac{1}{2}$, $x_B=x_C=\tfrac{1}{4}$, whose correlation functions are satisfactorily close to those of a random fcc solution. The generated SQSs are used to calculate the mixing enthalpy of the fcc phase in the Ca-Sr-Yb system. It is observed that first-principles calculations of all the binary and ternary SQSs in the Ca-Sr-Yb system exhibit very small local relaxation. It is concluded that the fcc ternary SQSs can provide valuable information about the mixing behavior of the fcc ternary solid solution phase. The SQSs presented in this work can be widely used to study the behavior of ternary fcc solid solutions.Comment: 20 pages, 7 figure

Evaluation of pyrolysis chars derived from marine macroalgae silage as soil amendments

Sections PDFPDF Tools Share Abstract Pyrolysis char residues from ensiled macroalgae were examined to determine their potential as growth promoters on germinating and transplanted seedlings. Macroalgae was harvested in May, July and August from beach collections, containing predominantly Laminaria digitata and Laminaria hyperborea ; naturally seeded mussel lines dominated by Saccharina latissima ; and lines seeded with cultivated L. digitata . Material was ensiled, pressed to pellets and underwent pyrolysis using a thermo‐catalytic reforming (TCR) process, with and without additional steam. The chars generated were then assessed through proximate and ultimate analysis. Seasonal changes had the prevalent impact on char composition, though using mixed beach‐harvested material gave a greater variability in elements than when using the offshore collections. Applying the char at 5% (v/v)/2% (w/w) into germination or seedling soils was universally negative for the plants, inhibiting or delaying all parameters assessed with no clear advantage in harvesting date, species or TCR processing methodology. In germinating lettuce seeds, soil containing the pyrolysis chars caused a longer germination time, poorer germination, fewer true leaves to be produced, a lower average plant health score and a lower final biomass yield. For transplanted ryegrass seedlings, there were lower plant survival rates, with surviving plants producing fewer leaves and tillers, lower biomass yields when cut and less regrowth after cutting. As water from the char‐contained plant pots inhibited the lettuce char control, one further observation was that run‐off water from the pyrolysis char released compounds which detrimentally affected cultivated plant growth. This study clearly shows that pyrolysed macroalgae char does not fit the standard assumption that chars can be used as soil amendments at 2% (w/w) addition levels. As the bioeconomy expands in the future, the end use of residues and wastes from bioprocessing will become a genuine global issue, requiring consideration and demonstration rather than hypothesized use

Bio-processing of macroalgae Palmaria palmata: metabolite fractionation from pressed fresh material and ensiling considerations for long-term storage

Red algae, belonging to the phylum Rhodophyta, contain an abundance of useful chemicals including bioactive molecules and present opportunities for the production of different products through biorefinery cascades. The rhodophyte Palmaria palmata, commonly termed dulse or dillisk, grows predominantly on the northern coasts of the Atlantic and Pacific Oceans and is a well-known snack food. Due to its abundance, availability and cultivation capacity, P. palmata was selected for study as a potential candidate for a biorefinery process. In addition to studying juice and solid fractions of freshly harvested P. palmata, we have investigated the novel possibility of preserving algal biomass by ensilaging protocols similar to those employed for terrestrial forage crops. In the metabolite partitioning within the solid and liquid fractions following screw-pressing, the majority of the metabolites screened for—water soluble carbohydrates, proteins and amino acids, lipids, pigments, phenolics and antioxidant activity—remained in the solid fraction, though at differing proportions depending on the metabolite, from 70.8% soluble amino acids to 98.2% chlorophyll a and 98.1% total carotenoids. For the ensiling study, screw-pressed P. palmata, with comparative wilted and chopped, and chopped only samples, were ensiled at scale with and without Safesil silage additive. All samples were successfully ensiled after 90 days, with screw-pressing giving lower or equal pH before and after ensiling compared with the other preparations. Of particular note was the effluent volumes generated during ensiling: 26–49% of the fresh weight, containing 16–34% of the silage dry matter. This may be of advantage depending on the final use of the biomass

First-principle solubilities of alkali and alkaline earth metals in Mg-B alloys

By devising a novel framework, we present a comprehensive theoretical study of solubilities of alkali (Li, Na, K, Rb, Cs) and alkaline earth (Be, Ca, Sr, Ba) metals in the he boron-rich Mg-B system. The study is based on first-principle calculations of solutes formation energies in MgB$_2$, MgB$_4$, MgB$_7$ alloys and subsequent statistical-thermodynamical evaluation of solubilities. The advantage of the approach consists in considering all the known phase boundaries in the ternary phase diagram. Substitutional Na, Ca, and Li demonstrate the largest solubilities, and Na has the highest (0.5-1 % in MgB$_7$ at $T=650-1000$ K). All the considered interstitials have negligible solubilities. The solubility of Be in MgB$_7$ can not be determined because the corresponding low-solubility formation energy is negative indicating the existence of an unknown ternary ground state. We have performed a high-throughput search of ground states in binary Mg-B, Mg-$A$, and B-$A$ systems, and we construct the ternary phase diagrams of Mg-B-$A$ alloys based on the stable binary phases. Despite its high temperature observations, we find that Sr$_{9}$Mg$_{38}$ is not a low-temperature equilibrium structure. We also determine two new possible ground states CaB$_{4}$ and RbB$_{4}$, not yet observed experimentally.Comment: 5 figure

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Light land development in the South - By A. S. WILD, Assistant Superintendent of Wheat Farming, Department of Agriculture. It is only since World War II ended that successful large scale development of light land near the south coast of this State has been undertaken, although the many millions of acres of treeless plain country throughout the agricultural areas have, for many years, presented a challenge to the pioneering ability of Western Australians. The use of hormones in viticulture - By L. T. JONES, Senior Plant Research Officer The discovery and proper use of plant hormones, or as they are more accurately termed, growth-regulating: substances, probably represents the greatest contribution which science has made to agriculture in the past few decades. It was the discovery by Kogl in 1934 that indole acetic acid was an active growth substance which led rapidly to the preparation and testing of large numbers of compounds of similar chemical structure and among these were found many substances which were very potent and also comparatively cheap to produce. Recent trends in viticulture in Western Australia - By W. R. JAMIESON, Viticulturist, Department of Agriculture, Perth Today I want to talk very briefly about some of the more recent trends in viticulture in this State. The commercial production of grapevines is centred mainly around the Swan Valley and as most of the suitable vineyard land in this area has been planted, growers are exploring avenues to increase the returns per acre. Methods of irrigation - By G. GAUNTLETT, Assistant Officer-in-Charge, Irrigation The success of an irrigation scheme depends on several factors. Important among these is the choice and design of the method to be adopted. There are two methods of irrigation, viz., surface and spray irrigation. Canker disease of Red-flowered gum - By W. P. CASS SMITH, B.Sc. (Agric), Government Plant Pathologist Of the many beautiful native plants in Western Australia, few are esteemed more than the red-flowered gum known botanically as Eucalyptus flcifolia. This shapely tree commences blossoming about Christmas time—and provides a magnificent display for several weeks—the blossom shades varying from dark red to pink. Why many beans grow crooked - By M. HARDIE, Vegetable Instructor Sometimes in the process of growing a crop, bean growers find a number of pods which, instead of being long and straight and suitable for marketing, are crooked or bent and quite unsuitable for sale unless beans are in very short supply. It is not unusual for a small number of pods to be affected in this way, generally at the tail-end of the crop, but occasionally the percentage may be high. When this happens the grower is often at a loss to account for his failure to grow a marketable crop. To the best of his ability he has followed methods which normally return a crop of first-grade pods and yet for some reason, his crop is an unpayable one and he is anxious to ascertain the cause. Salt land programme for Autumn - By T. C. STONEMAN, Adviser, Soil Conservation Service Now that summer is over and winter approaches, the time has come to decide what you\u27ll do with that salt problem on your farm. What you SHOULD do, will depend on how severely the area is affected. To make quite clear how the recommendations made by the Department of Agriculture can be applied I will deal with each degree of severity in turn. Orchard cover crops - By J. CRIPPS, Horticultural Adviser The sowing of a cover crop is one of those routine operations which the orchardist often undertakes without much thought, but it is an operation worthy of consideration. Lupin seed - By B. J. QUINLIVAN, B.Sc. (Agric), Botanist, Weeds and Seeds Branch The three types of lupins which we grow in this State are the New Zealand, the W.A. blue, and the yellow lupin. The first two types are very common, the New Zealand lupin being grown mainly in the South-West, while the W.A. lupin is grown over extensive areas of the central and northern wheatbelt, particularly on the sandier types of soil. Cereal rye will grow on wind-eroded areas - By G. H. BURVILL, Chief Plant Research Officer. Travelling around the wheatbelt, one often sees areas of sandy soil quite bare, A due to wind erosion. Surface soil blown from these patches has built up against fences, or as mounds in the nearby scrub. Many of the eroded places are quite small— perhaps less than an acre or only a few acres. But some are large, with one to three hundred acres of bare yellow sand. As much as two feet of soil has been blown from big areas. Autumn-winter feeding for the fat lamb flock - By N. DAVENPORT, Senior Adviser, Meat Production The autumn-winter period is the most important part of the year for the fat lamb crop from a feed point of view. It is important not only from the aspect of the wellbeing of the sheep, but also of the pasture. Pasture plants are living things, too, and they also require consideration and care for their development. When a new season pasture is kept hard grazed in those critical first few weeks of growth it cannot carry as many sheep over the season as one which is lightly stocked during that time. Plant diseases in the home garden - By W. P. CASS-SMITH, B.Sc. (Agric), Government Plant Pathologist Recently many home-gardeners have complained that plantings of vegetables or ornamentals are making unthrifty growth, in spite of liberal waterings and fertilisation. These symptoms are commonly caused by root-knot eelworm, a pest which has unfortunately become very widespread in the sandy soils adjacent to Perth, and in many other parts of this State. This eelworm parasite attacks the roots of many kinds of plants causing them to rot and to develop bead-like swellings or galls. As a result, the intake of plant food and water is restricted and stunting of the above-ground parts occurs. Principles of commercial beekeeping - By R. S. COLEMAN, R.D.A., Government Apiculturist We have many queries from small beekeepers, and from people who have never opened a hive, on how to break into full-time beekeeping. So it was thought that you would like to know just what are the principles of successful bee farming. Grasshoppers and locusts - By C. F. H. JENKINS, M.A., Government Entomologist Grasshoppers and locusts are among the most ancient enemies of mankind for they figured prominently in Biblical times, and periodically throughout the ages have devastated crops in all parts of the world. Acetonaemia in dairy cattle - By P. M. A. HARWOOD, M.R.C.V.S., Veterinary Officer Acetonaemia, more correctly known as ketosis is a metabolic disease. Unlike infectious diseases such as tuberculosis or mastitis, which are caused by microbes, metabolic diseases result from an upset in the normal bodily processes. Molybdenum for subterranean clover - By T. C. DUNNE, B.Sc. (Agric), Ph.D. (Calif.), Chief Plant Nutrition and Research Officer Subterranean clover is undoubtedly the most important pasture species in this State. Because it is a legume, it can make excellent growth on soils with a low nitrogen content. The nitrogen it needs is, of course, provided by bacteria which inhabit the nodules found on its roots. These bacteria provide nitrogen by taking it from the air and converting it to a form which can be used by the clover. However, it is now known that the bacteria can use the nitrogen of the air only if enough molybdenum is available to them. Cobalt deficiency in sheep and cattle - By C. R. TOOP, B.V.SC, Chief Veterinary Officer With the establishment of group settlements at Denmark after the first world war, it was observed that young cattle, although running on lush pastures, developed systems of unthriftness and wasting and usually died. Research conducted of Filmer and Underwood later revealed that this condition was caused by a deficiency of cobalt and that it could be cured and prevented by addition of this mineral to the diet. Cobalt deficiency has since been met with other parts of the State and was recently diagnosed in sheep at Mount Manypeaks

Theatre and time ecology: deceleration in Stifters Dinge

This article explores the production of ‘time ecology’ in two works of postdramatic theatre: Heiner Goebbels’ Stifters Dinge (2007) and Philippe Quesne’s L’Effet de Serge (2007). By focusing on the practice of deceleration, it argues that theatre’s ecological potential resides not so much in its ability to represent the world, but rather in its capacity for producing new types of temporal experience that purposefully seek to break with modernity’s regime of historicity and the accelerated rhythms that it has given rise to. Importantly, my concern with deceleration is not an argument for slowness per se; on the contrary, I am interested in highlighting the presence of multiple and interpenetrating timescales and rhythms. As well as exposing the full extent of theatre’s temporal potential, such a concern with postdramatic ‘chronographies’ offers an implicit critique of dramatic theatre’s extant practices of eco-dramaturgy that, all too often, attempt to construct a linear narrative which is invested in conventional sequential models of temporality (beginning, middle, end)

Evaluation of toxicity after one-months treatment with Bauhinia forficata decoction in streptozotocin-induced diabetic rats

BACKGROUND: Previous experiments have shown that a decoction of Bauhinia forficata leaves reduces the changes in carbohydrate and protein metabolism that occur in rats with streptozotocin-induced diabetes. In the present investigation, the serum activities of enzymes known to be reliable toxicity markers were monitored in normal and streptozotocin-diabetic rats to discover whether the use of B. forficata decoction has toxic effects on liver, muscle or pancreas tissue or on renal microcirculation. METHODS: An experimental group of normal and streptozotocin-diabetic rats received an aqueous decoction of fresh B. forficata leaves (150 g/L) by mouth for 33 days while a control group of normal and diabetic rats received water for the same length of time. The serum activity of the toxicity markers lactate dehydrogenase, creatine kinase, amylase, angiotensin-converting enzyme and bilirubin were assayed before receiving B. forficata decoction and on day 19 and 33 of treatment. RESULTS: The toxicity markers in normal and diabetic rats were not altered by the diabetes itself nor by treatment with decoction. Whether or not they received B. forficata decoction the normal rats showed a significant increase in serum amylase activity during the experimental period while there was a tendency for the diabetic rats, both treated and untreated with decoction, to have lower serum amylase activities than the normal rats. CONCLUSIONS: Administration of an aqueous decoction of B. forficata is a potential treatment for diabetes and does not produce toxic effects measurable with the enzyme markers used in our study

Maintaining Disorder: Some Technical and Aesthetic Issues Involved in the Performance of Ligeti’s E´ tudes for Piano

This article examines some of the particular questions and associated strategies concerning matters of rhythm, perceived metre, notation, accentuation, line, physical approach to the keyboard, pedalling, and more in the performance of Ligeti’s Études for piano. I relate these issues to those encountered in earlier repertoire, including works of Schumann, Liszt, Stravinsky, Prokofiev, Bartók and Blacher, and argue that particular approaches and attitudes to both technical and musical matters in the context of these Études can fundamentally affect the concept of the music. A particular focus is upon issues of continuity and discontinuity, and the ‘situation’ of these works within particular pianistic and other traditions by virtue of the approach taken to performance