Evaluation of optical techniques for characterising soil organic matter quality in agricultural soils

Soil organic matter (SOM) is one of the main global carbon pools. It is a measure of soil quality as its presence increases carbon sequestration and improves physical and chemical soil properties. The determination and characterisation of humic substances gives essential information of the maturity and stresses of soils as well as of their health. However, the determination of the exact nature and molecular structure of these substances has been proven difficult. Several complex techniques exist to characterise SOM and mineralisation and humification processes. One of the more widely accepted for its accuracy is nuclear magnetic resonance (NMR) spectroscopy. Despite its efficacy, NMR needs significant economic resources, equipment, material and time. Proxy measures like the fluorescence index (FI), cold and hot-water extractable carbon (CWC and HWC) and SUVA-254 have the potential to characterise SOM and, in combination, provide qualitative and quantitative data of SOM and its processes. Spanish and British agricultural cambisols were used to measure SOM quality and determine whether similarities were found between optical techniques and 1H NMR results in these two regions with contrasting climatic conditions. High correlations (p < 0.001) were found between the specific aromatic fraction measured with 1H NMR and SUVA-254 (Rs = 0.95) and HWC (Rs = 0.90), which could be described using a linear model. A high correlation between FI and the aromatics fraction measured with 1H NMR (Rs = −0.976) was also observed. In view of our results, optical measures have a potential, in combination, to predict the aromatic fraction of SOM without the need of expensive and time consuming techniques

A 300-year record of sedimentation in a small tilled catena in Hungary based on δ13C, δ15N, and C/N distribution

Purpose Soil erosion is one of the most serious hazards that endanger sustainable food production. Moreover, it has marked effects on soil organic carbon (SOC) with direct links to global warming. At the same time, soil organic matter (SOM) changes in composition and space could influence these processes. The aim of this study was to predict soil erosion and sedimentation volume and dynamics on a typical hilly cropland area of Hungary due to forest clearance in the early eighteenth century. Materials and methods Horizontal soil samples were taken along two parallel intensively cultivated complex convex-concave slopes from the eroded upper parts at mid-slope positions and from sedimentation in toe-slopes. Samples were measured for SOC, total nitrogen (TN) content, and SOMcompounds (δ13C, δ15N, and photometric indexes). They were compared to the horizons of an in situ non-eroded profile under continuous forest. On the depositional profile cores, soil depth prior to sedimentation was calculated by the determination of sediment thickness. Results and discussion Peaks of SOC in the sedimentation profiles indicated thicker initial profiles, while peaks in C/N ratio and δ13C distribution showed the original surface to be ~ 20 cm lower. Peaks of SOC were presumed to be the results of deposition of SOC-enriched soil from the upper slope transported by selective erosion of finer particles (silts and clays). Therefore, changes in δ13C values due to tillage and delivery would fingerprint the original surface much better under the sedimentation scenario than SOC content. Distribution of δ13C also suggests that the main sedimentation phase occurred immediately after forest clearance and before the start of intense cultivation with maize. Conclusions This highlights the role of relief in sheet erosion intensity compared to intensive cultivation. Patterns of δ13C indicate the original soil surface, even in profiles deposited as sediment centuries ago. The δ13C and C/N decrease in buried in situ profiles had the same tendency as recent forest soil, indicating constant SOM quality distribution after burial. Accordingly, microbiological activity, root uptake, and metabolism have not been effective enough to modify initial soil properties

Conventional tillage versus organic farming in relation to soil organic carbon stock in olive groves in Mediterranean rangelands (southern Spain)

Soil organic carbon (SOC) concentration is a soil variable subject to changes. The management system is a key factor that influences these changes. To determine the long-term effects of the management system on SOC stocks (SOCS) in olive groves, 114 soil profiles were studied in the Los Pedroches Valley (Mediterranean rangelands – southern Spain) for 20 years. The management practices were conventional tillage (CT) and organic farming (OF) in four soil types: Cambisols (CMs), Regosols (RGs), Luvisols (LVs) and Leptosols (LPs). Soil properties were statistically analysed by management techniques, soil types and horizons. Significant differences (p < 0.05) were found between soil types and management practices. It was equally observed that the management system affected SOCS. In addition, the total SOCS during the 20-year experiment increased in OF with respect to CT by 72 and 66% in CMs and LVs respectively. SOC showed significant differences for horizons (p < 0.05) in relation to the management type. The stratification ratio (SR) was used as an indicator of soil quality based on the influence of surface SOC levels on erosion control, water infiltration and nutrient conservation with respect to deep layers. The SR of SOC from the surface to depth was greater in CT compared to OF with the exception of RGs. In all cases, the SR of SOC was >2. These results indicate high soil quality and that management practices affect SOC storage in the Los Pedroches Valley

Impacts of land use change in soil carbon and nitrogen in a Mediterranean agricultural area (Southern Spain)

The agricultural Mediterranean areas are dedicated to arable crops (AC), but in the last decades, a significant number of AC has led to a land use change (LUC) to olive grove (OG) and vineyards (V). A field study was conducted to determine the long-term effects (46 years) of LUC (AC by OG and V) and to determine soil organic carbon (SOC), total nitrogen (TN), C : N ratio and their stratification across the soil entire profile, in Montilla-Moriles denomination of origin (D.O.), in Calcic-Chromic Luvisols (LVcc/cr), an area under semiarid Mediterranean conditions. The experimental design consisted of studying the LUC on one farm between 1965 and 2011. Originally, only AC was farmed in 1965, but OG and V were farmed up to now (2011). This LUC principally affected the horizon thickness, texture, bulk density, pH, organic matter, organic carbon, total nitrogen and C : N ratio. The LUC had a negative impact in the soil, affecting the SOC and TN stocks. The conversion from AC to V and OG involved the loss of the SOC stock (52.7% and 64.9% to V and OG respectively) and the loss of the TN stock (42.6% and 38.1% to V and OG respectively). With respect to the stratification ratios (SRs), the effects were opposite; 46 years after LUC increased the SRs (in V and OG) of SOC, TN and C : N ratio

Soil organic carbon along an altitudinal gradient in the Despeñaperros Natural Park, southern Spain

Soil organic carbon (SOC) is extremely important in the global carbon (C) cycle as C sequestration in non-disturbed soil ecosystems can be a C sink and mitigate greenhouse-gas-driven climate change. Soil organic carbon changes in space and time are relevant to understand the soil system and its role in the C cycle. This is why the influence of topographic position on SOC should be studied. Seven topographic positions from a toposequence between 607 and 1168 m were analyzed in the Despeñaperros Natural Park (Jaén, SW Spain). Depending on soil depth, one to three control sections (0–25, 25–50 and 75 cm) were sampled at each site. The SOC content in studied soils was below 30 g kg⁻¹ and strongly decreases with depth. These results were related to the gravel content and to the bulk density. The SOC content from the topsoil (0–25 cm) varied largely through the altitudinal gradient ranging between 27.3 and 39.9 g kg⁻¹. The SOC stock (SOCS) varied between 53.8 and 158.0 Mg ha⁻¹ in the studied area, which had been clearly conditioned by the topographic position. Therefore, results suggest that elevation should be included in SOCS models and estimations at local and regional scales

Soil quality assessment based on carbon stratification index in different olive grove management practices in Mediterranean areas

In Mediterranean areas, conventional tillage increases soil organic matter losses, reduces soil quality, and contributes to climate change due to increased CO2 emissions. CO2 sequestration rates in soil may be enhanced by appropriate agricultural soil management and increasing soil organic matter content. This study analyzes the stratification ratio (SR) index of soil organic carbon (SOC), nitrogen (N) and C:N ratio under different management practices in an olive grove (OG) in Mediterranean areas (Andalusia, southern Spain). Management practices considered in this study are conventional tillage (CT) and no tillage (NT). In the first case, CT treatments included addition of alperujo (A) and olive leaves (L). A control plot with no addition of olive mill waste was considered (CP). In the second case, NT treatments included addition of chipped pruned branches (NT1) and chipped pruned branches and weeds (NT2). The SRs of SOC increased with depth for all treatments. The SR of SOC was always higher in NT compared to CT treatments, with the highest SR of SOC observed under NT2. The SR of N increased with depth in all cases, ranging between 0.89 (L-SR1) and 39.11 (L-SR3 and L-SR4).The SR of C:N ratio was characterized by low values, ranging from 0.08 (L-SR3) to 1.58 (NT1-SR2) and generally showing higher values in SR1 and SR2 compared to those obtained in SR3 and SR4. This study has evaluated several limitations to the SR index such as the fact that it is descriptive but does not analyze the behavior of the variable over time. In addition, basing the assessment of soil quality on a single variable could lead to an oversimplification of the assessment. Some of these limitations were experienced in the assessment of L, where SR1 of SOC was the lowest of the studied soils. In this case, the higher content in the second depth interval compared to the first was caused by the intrinsic characteristics of this soil's formation process rather than by degradation. Despite the limitations obtained SRs demonstrate that NT with the addition of organic material improves soil quality

Managing cropland and rangeland for climate mitigation: an expert elicitation on soil carbon in California

Understanding the magnitude of and uncertainty around soil carbon flux (SCF) is important in light of California’s efforts to increase SCF (from the atmosphere to soils) for climate change mitigation. SCF depends, to a great extent, on how soils are managed. Here, we summarize the results of an elicitation of soil science and carbon cycle experts aiming to characterize understanding of current SCF in California’s cropland and rangeland, and how it may respond to alternative management practices over time. We considered four cropland management practices—biochar, compost, cover crops, and no-till—and two rangeland management practices, compost and high-impact grazing. Results across all management practices reveal underlying uncertainties as well as very modest opportunities for soil carbon management to contribute meaningfully to California’s climate mitigation. Under median scenarios, experts expect all the surveyed management practices to reverse SCF from negative to positive, with direct carbon additions via biochar and compost offering the best potential for boosting the soil carbon pool