The influence of polydispersity and inhomogeneity on EXAFS of bimetallic catalysts

The effect of polydispersity and inhomogeneity of supported bimetallic catalysts on the EXAFS analysis is investigated with some simple model calculations. These show that EXAFS is very insensitive to polydispersity. Polydispersity and inhomogeneous distribution of the metals over the particles however have only limited influence on the ability to distinguish between core-shell particles and particles with random distribution of both metals

Software fault characteristics: A synthesis of the literature

Faults continue to be a significant problem in software. Understanding the nature of these faults is important for practitioners and researchers. There are many published fault characteristics schemes but no one scheme dominates. Consequently it is difficult for practitioners to effectively evaluate the nature of faults in their software systems, and it is difficult for researchers to compare the types of faults found by different fault detection techniques. In this paper we synthesise previous fault characteristics schemes into one comprehensive scheme. Our scheme provides a richer view of faults than the previous schemes published and presents a comprehensive, unified approach which accommodates the many previous schemes. A characteristics-based view of faults should be considered by future researchers in the analysis of software faults and in the design and evaluation of new fault detection tools. We recommend that our fault characteristics scheme be used as a benchmark scheme

A New Façade Concept

This paper is focussing on the development and opportunities for new façadeconcepts. In a survey on the possibilities for energy saving in the supply chain ofthe Dutch glass industry it appeared that there are major opportunities forapplications of glass in the European building stock. The integral application ofseveral glass products was the basis for the development of a new façade concept.Apart from saving energy this concept also solves some major problems in theconstruction industry and the refurbishment of the European building stock.Therefore this paper also contains information about shortcomings anddevelopments in the European construction industry as well as the scale andcharacteristics of the European building stock suitable for the application of thenew concept

A Continuous-Discontinuous Approach to Simulate Heat Transfer in Fractured Media

A macroscopic framework to model heat transfer in materials and composites, subjected to physical degradation, is proposed. The framework employs the partition of unity concept and captures the change from conduction-dominated transfer in the initial continuum state to convection and radiation-dominated transfer in the damaged state. The underlying model can be directly linked to a mechanical cohesive zone model, governing the initiation and subsequent growth and coalescence of micro-cracks. The methodology proved to be applicable for quasi-static, periodic, and transient problem

Experimental and numerical cross-validation of flow in real porous media. Part 1: Experimental framework

International audienceIn this study, we present the design of a purpose-built test cell, capable of closely mimicking boundary conditions which can be routinely imposed in fluid flow simulators. The test cell permits conducting systematic studies on the influence of unresolved pore-scale wall-roughness and pore space morphology on the hydraulic conductivity: it is therefore an ideal instrument for the generation of validation datasets for the next generation numerical flow models

On the canonical degrees of curves in varieties of general type

A widely believed conjecture predicts that curves of bounded geometric genus lying on a variety of general type form a bounded family. One may even ask whether the canonical degree of a curve $C$ in a variety of general type is bounded from above by some expression $a\chi(C)+b$, where $a$ and $b$ are positive constants, with the possible exceptions corresponding to curves lying in a strict closed subset (depending on $a$ and $b$). A theorem of Miyaoka proves this for smooth curves in minimal surfaces, with $a>3/2$. A conjecture of Vojta claims in essence that any constant $a>1$ is possible provided one restricts oneself to curves of bounded gonality. We show by explicit examples coming from the theory of Shimura varieties that in general, the constant $a$ has to be at least equal to the dimension of the ambient variety. We also prove the desired inequality in the case of compact Shimura varieties.Comment: 10 pages, to appear in Geometric and Functional Analysi

Adaptive NLMS Partial Crosstalk Cancellation in Digital Subscriber Lines

Crosstalk is a major limitation to achieving high data-rates in next generation VDSL systems. Whilst crosstalk cancellation can be applied to completely remove crosstalk, it is often too complex for application in typical VDSL binders, which can contain up to hundreds of lines. A practical alternative, known as partial cancellation limits the cancellation to crosstalkers that cause severe interference to the other lines within the binder. In real VDSL systems, the crosstalk environment changes rapidly as new lines come online; old lines go offline, and the crosstalk channels change with fluctuations in ambient temperature. Therefore, adaptive crosstalk cancellers are often required. In this paper, we propose a new detection guided adaptive NLMS method for Adaptive Partial Crosstalk Cancellation that detects significant crosstalkers and tracks variations in their crosstalk channels. This exploits the sparse and column-wise diagonal dominant properties of the crosstalk channel matrix and leads to fast convergence, accurate crosstalk channel tracking, with a lower update complexity. The end result is an adaptive Partial Crosstalk Cancellation algorithm that has lower run-time complexity than prior state-of-the-art whilst yielding comparatively high data-rates and reliable service

Relations between some invariants of algebraic varieties in positive characteristic

We discuss relations between certain invariants of varieties in positive characteristic, like the a-number and the height of the Artin-Mazur formal group. We calculate the a-number for Fermat surfacesComment: 13 page