3,166 research outputs found

    The explicit expression of the fugacity for weakly interacting Bose and Fermi gases

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    In this paper, we calculate the explicit expression for the fugacity for two- and three-dimensional weakly interacting Bose and Fermi gases from their equations of state in isochoric and isobaric processes, respectively, based on the mathematical result of the boundary problem of analytic functions --- the homogeneous Riemann-Hilbert problem. We also discuss the Bose-Einstein condensation phase transition of three-dimensional hard-sphere Bose gases.Comment: 24 pages, 9 figure

    Kinetics and Mechanism of Hydroxyapatite Crystal Dissolution in Weak Acid Buffers Using the Rotating Disk Method

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    The dissolution rates of synthetic hydroxyapatite pellets under sink conditions were measured using the rotating disk method. The experimental data were analyzed by means of a physical model that yielded an ionic activity product of KHAP = a10Ca2+ a6 PO4 3- a2OH- = 1 × 10-124.5±1.0 that was found to govern the dissolution reaction. Also, a surface resistance factor of k' equal to about 174 sec/cm was deduced from the data.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/67157/2/10.1177_00220345760550033201.pd

    A new two-site model for hydroxyapatite dissolution in acidic media

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    A physical model featuring two distinct types of dissolution sites for hydroxyapatite (HAP) crystals is presented. One of these sites (site No. 1) is associated with dissolution along c axis dislocations of HAP crystals and is the important site when dissolution occurs into partially saturated solutions. Site No. 2 is active only when dissolution occurs into nearly completely unsaturated solutions, and, because of its greater apparent rate constant, is the more important dissolution site under these conditions.In the physical model block dental enamel or a compressed HAP pellet is represented as a porous matrix of these HAP crystals with interstitial spaces which are permeated by the dissolution medium. The behavior of the model for various situations can be calculated by combining Fick's second law equation for diffusion with the kinetic equations for the behavior of the dissolution sites and solving the resulting boundary value problem.This model is capable of accounting for dissolution kinetics over a range of variation of experimental variables (degree of undersaturation, Ca/P ratio, and effective diffusion layer thickness). The model also correctly predicts the conditions necessary for zonal as opposed to surface dissolution: high partial saturation, a viscous dissolution medium, or the presence of a site No. 2 dissolution inhibitor. Electron microscopic studies of dissolution morphology at the single crystal level are also in full agreement with the model.Finally, an examination of the available data on enamel remineralization suggests that the holes formed as a result of site No. 1 dissolution are likely the primary sites for remineralization.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/22735/1/0000290.pd

    Adiabatic Condition and Quantum Geometric Potential

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    In this paper, we present a U(1)-invariant expansion theory of the adiabatic process. As its application, we propose and discuss new sufficient adiabatic approximation conditions. In the new conditions, we find a new invariant quantity referred as quantum geometric potential (QGP) contained in all time-dependent processes. Furthermore, we also give detailed discussion and analysis on the properties and effects of QGP.Comment: 5 pages, 1 figur

    Mean-field Phase Diagram of Two-Dimensional Electrons with Disorder in a Weak Magnetic Field

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    We study two-dimensional interacting electrons in a weak perpendicular magnetic field with the filling factor ν≫1\nu \gg 1 and in the presence of a quenched disorder. In the framework of the Hartree-Fock approximation, we obtain the mean-field phase diagram for the partially filled highest Landau level. We find that the CDW state can exist if the Landau level broadening 1/2τ1/2\tau does not exceed the critical value 1/2τc=0.038ωH1/2\tau_{c}=0.038\omega_{H}. Our analysis of weak crystallization corrections to the mean-field results shows that these corrections are of the order of (1/ν)2/3≪1(1/\nu)^{2/3}\ll 1 and therefore can be neglected

    Expanding the set of rhodococcal Baeyer–Villiger monooxygenases by high-throughput cloning, expression and substrate screening

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    To expand the available set of Baeyer–Villiger monooxygenases (BVMOs), we have created expression constructs for producing 22 Type I BVMOs that are present in the genome of Rhodococcus jostii RHA1. Each BVMO has been probed with a large panel of potential substrates. Except for testing their substrate acceptance, also the enantioselectivity of some selected BVMOs was studied. The results provide insight into the biocatalytic potential of this collection of BVMOs and expand the biocatalytic repertoire known for BVMOs. This study also sheds light on the catalytic capacity of this large set of BVMOs that is present in this specific actinomycete. Furthermore, a comparative sequence analysis revealed a new BVMO-typifying sequence motif. This motif represents a useful tool for effective future genome mining efforts.

    4.5 years multi-wavelength observations of Mrk 421 during the ARGO-YBJ and Fermi common operation time

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    We report on the extensive multi-wavelength observations of the blazar Markarian 421 (Mrk 421) covering radio to gamma-rays, during the 4.5 year period of ARGO-YBJ and Fermi common operation time, from August 2008 to February 2013. In particular, thanks to the ARGO-YBJ and Fermi data, the whole energy range from 100 MeV to 10 TeV is covered without any gap. In the observation period, Mrk 421 showed both low and high activity states at all wavebands. The correlations among flux variations in different wavebands were analyzed. Seven large flares, including five X-ray flares and two GeV gamma-ray flares with variable durations (3-58 days), and one X-ray outburst phase were identified and used to investigate the variation of the spectral energy distribution with respect to a relative quiescent phase. During the outburst phase and the seven flaring episodes, the peak energy in X-rays is observed to increase from sub-keV to few keV. The TeV gamma-ray flux increases up to 0.9-7.2 times the flux of the Crab Nebula. The behavior of GeV gamma-rays is found to vary depending on the flare, a feature that leads us to classify flares into three groups according to the GeV flux variation. Finally, the one-zone synchrotron self-Compton model was adopted to describe the emission spectra. Two out of three groups can be satisfactorily described using injected electrons with a power-law spectral index around 2.2, as expected from relativistic diffuse shock acceleration, whereas the remaining group requires a harder injected spectrum. The underlying physical mechanisms responsible for different groups may be related to the acceleration process or to the environment properties.Comment: 17 pages, 9 figures, 5 tables, Accepted for publication in ApJ

    The cosmic ray proton plus helium energy spectrum measured by the ARGO-YBJ experiment in the energy range 3-300 TeV

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    The ARGO-YBJ experiment is a full-coverage air shower detector located at the Yangbajing Cosmic Ray Observatory (Tibet, People's Republic of China, 4300 m a.s.l.). The high altitude, combined with the full-coverage technique, allows the detection of extensive air showers in a wide energy range and offer the possibility of measuring the cosmic ray proton plus helium spectrum down to the TeV region, where direct balloon/space-borne measurements are available. The detector has been in stable data taking in its full configuration from November 2007 to February 2013. In this paper the measurement of the cosmic ray proton plus helium energy spectrum is presented in the region 3-300 TeV by analyzing the full collected data sample. The resulting spectral index is γ=−2.64±0.01\gamma = -2.64 \pm 0.01. These results demonstrate the possibility of performing an accurate measurement of the spectrum of light elements with a ground based air shower detector.Comment: 18 pages, 8 figures, preprint submitted to Phys. Rev.

    EAS age determination from the study of the lateral distribution of charged particles near the shower axis with the ARGO-YBJ experiment

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    The ARGO-YBJ experiment, a full coverage extensive air shower (EAS) detector located at high altitude (4300 m a.s.l.) in Tibet, China, has smoothly taken data, with very high stability, since November 2007 to the beginning of 2013. The array consisted of a carpet of about 7000 m2^2 Resistive Plate Chambers (RPCs) operated in streamer mode and equipped with both digital and analog readout, providing the measurement of particle densities up to few particles per cm2^2. The unique detector features (full coverage, readout granularity, wide dynamic range, etc) and location (very high altitude) allowed a detailed study of the lateral density profile of charged particles at ground very close to the shower axis and its description by a proper lateral distribution function (LDF). In particular, the information collected in the first 10 m from the shower axis have been shown to provide a very effective tool for the determination of the shower development stage ("age") in the energy range 50 TeV - 10 PeV. The sensitivity of the age parameter to the mass composition of primary Cosmic Rays is also discussed

    Study of the diffuse gamma-ray emission from the Galactic plane with ARGO-YBJ

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    The events recorded by ARGO-YBJ in more than five years of data collection have been analyzed to determine the diffuse gamma-ray emission in the Galactic plane at Galactic longitudes 25{\deg} < l < 100{\deg} and Galactic latitudes . The energy range covered by this analysis, from ~350 GeV to ~2 TeV, allows the connection of the region explored by Fermi with the multi-TeV measurements carried out by Milagro. Our analysis has been focused on two selected regions of the Galactic plane, i.e., 40{\deg} < l < 100{\deg} and 65{\deg} < l < 85{\deg} (the Cygnus region), where Milagro observed an excess with respect to the predictions of current models. Great care has been taken in order to mask the most intense gamma-ray sources, including the TeV counterpart of the Cygnus cocoon recently identified by ARGO-YBJ, and to remove residual contributions. The ARGO-YBJ results do not show any excess at sub-TeV energies corresponding to the excess found by Milagro, and are consistent with the predictions of the Fermi model for the diffuse Galactic emission. From the measured energy distribution we derive spectral indices and the differential flux at 1 TeV of the diffuse gamma-ray emission in the sky regions investigated.Comment: 11 pages, 6 figures, published in AP
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