Influence of basement rocks on fluid evolution during multiphase deformation: the example of the Estamariu thrust in the Pyrenean Axial Zone

Calcite veins precipitated in the Estamariu thrust during two tectonic events decipher the temporal and spatial relationships between deformation and fluid migration in a long-lived thrust and determine the influence of basement rocks on the fluid chemistry during deformation. Structural and petrological observations constrain the timing of fluid migration and vein formation, whilst geochemical analyses (δ13C, δ18O, 87Sr/86Sr, clumped isotope thermometry and elemental composition) 15 of the related calcite cements and host rocks indicate the fluid origin, pathways and extent of fluid-rock interaction. The first tectonic event, recorded by calcite cements Cc1a and Cc2, is related to the Alpine reactivation of the Estamariu thrust, and is characterized by the migration of meteoric fluids, heated at depth (temperatures between 56 and 98 ºC) and interacted with crystalline basement rocks before upflowing through the thrust zone. During the Neogene extension, the Estamariu thrust was reactivated and normal faults and shear fractures with calcite cements Cc3, Cc4 and Cc5 developed. Cc3 and Cc4 precipitated 20 from hydrothermal fluids (temperatures between 127 and 208 ºC and between 102 and 167 ºC, respectively) derived from crystalline basement rocks and expelled through fault zones during deformation. Cc5 precipitated from low temperature meteoric waters percolating from the surface through small shear fractures. The comparison between our results and already published data in other structures from the Pyrenees suggests that regardless of the origin of the fluids and the tectonic context, basement rocks have a significant influence on the fluid chemistry, particularly on the 87Sr/86Sr ratio. Accordingly, the cements 25 precipitated from fluids interacted with crystalline basement rocks have significantly higher 87Sr/86Sr ratios (> 0.710) with respect to those precipitated from fluids that have interacted with the sedimentary cover (< 0.710)

Changes in fluid regime in syn-orogenic sediments during the growth of the south Pyrenean fold and thrust belt

The eastern sector of the south Pyrenean fold and thrust belt developed during the Alpine compression and affected Upper Cretaceous to lower Oligocene foreland basin deposits. In this study, we determine the changes in fluid regime and fluid composition during the growth of this fold and thrust belt, integrating petrographic and geochemical data obtained from fracture-filling cements. Hydrothermal fluids at temperatures up to 154 °C, migrated from the Axial zone to the foreland basin and mixed with connate fluids in equilibrium with Eocene sea-water during lower and middle Eocene (underfilled foreland basin). As the thrust front progressively emerged, low-temperature meteoric waters migrated downwards the foreland basin and mixed at depth with the hydrothermal fluids from middle Eocene to lower Oligocene (overfilled non-marine foreland basin). The comparison of the fluid flow models from the Southern Pyrenees with other orogens worldwide, seems to indicate that the presence or absence of thick evaporitic units highly control fluid composition during the development of fold and thrust belts. Whereas in thrusts not detached along thick evaporite units, mixed fluids are progressively more depleted in δ18O and have a lower temperature and lower Fe and Sr contents as the thrust front emerges, in thrust detachments through thick evaporite units, the mixed fluids are enriched in δ18O

Fluid Dynamics in a Thrust Fault Inferred from Petrology and Geochemistry of Calcite Veins: An Example from the Southern Pyrenees

Petrographic and geochemical analyses (δ18O, δ13C, 87Sr/86Sr, clumped isotopes, and elemental composition) coupled with field structural data of synkinematic calcite veins, fault rocks, and host rocks are used to reconstruct the episodic evolution of an outstanding exposed thrust zone in the Southern Pyrenees and to evaluate the fault behavior as a conduit or barrier to fluid migration. The selected thrust displaces the steeply dipping southern limb of the Sant Corneli-Bóixols anticline, juxtaposing a Cenomanian-Turonian carbonate unit against a Coniacian carbonate sequence. Successive deformation events are recorded by distinct fracture systems and related calcite veins, highlighting (i) an episodic evolution of the thrust zone, resulting from an upward migration of the fault tip (process zone development) before growth of the fault (thrust slip plane propagation), and (ii) compartmentalization of the thrust fault zone, leading to different structural and fluid flow histories in the footwall and hanging wall. Fractures within the footwall comprise three systematically oriented fracture sets (F1, F2, and F3), each sealed by a separate generation calcite cement, and a randomly oriented fracture system (mosaic to chaotic breccia), cemented by the same cements as fracture sets F1 and F2. The formation of fractures F1 and F2 and the mosaic to chaotic breccia is consistent with dilatant fracturing within the process zone (around the fault tip) during initial fault growth, whereas the formation of the latest fracture system points to hybrid shear-dilational failure during propagation of the fault. The continuous formation of different fracture systems and related calcite cementation phases evidences that the structural permeability in the footwall was transient and that the fluid pathways and regime evolved due to successive events of fracture opening and calcite cementation. Clumped isotopes evidence a progressive increase in precipitation temperatures from around 50°C to 117°C approximately, interpreted as burial increase linked to thrust sheet emplacement. During this period, the source of fluid changed from meteoric fluids to evolved meteoric fluids due to the water-rock interaction at increasing depths and temperatures. Contrary to the footwall, within the hanging wall, only randomly oriented fractures are recognized and the resulting crackle proto-breccia is sealed by a later and different calcite cement, which is also observed in the main fault plane and in the fault core. This cement precipitated from formation fluids, at around 95°C, that circulated along the fault core and in the hanging wall block, again supporting the interpretation of compartmentalization of the thrust structure. The integration of these data reveals that the studied thrust fault acted as a transverse barrier, dividing the thrust zone into two separate fluid compartments, and a longitudinal drain for migration of fluids. This study also highlights the similarity in deformation processes and mechanisms linked to the evolution of fault zones in compressional and extensional regimes involving carbonate rocks

Application of a non destructive method for developing physical properties ofbone tissue based on Imagenology tecniques and Cad software tools

Los ensayos mecánicos son usados para la caracterización de propiedades mecánicas de tejidos óseos, sin embargo, debido al carácter destructivo del ensayo, las probetas usadas son generalmente de tejidos óseos de cadáver humano o animales. La caracterización resultante de estos ensayos por lo tanto, es válida solo en los especímenes probados, porque el tejido óseo presenta alta variabilidad en sus propiedades debido al cambio de su densidad. Por este argumento y la naturaleza destructiva de los ensayos mecánicos, este tipo de ensayo no es apropiado para realizar la caracterización mecánica de tejidos vivos, lo cual limita las posibilidades de desarrollo en proyectos de investigación en vivo. El presente estudio fue desarrollado con el propósito de evaluar la viabilidad del uso de un método no destructivo, propuesto para calcular los valores de densidad aparente a partir de la densidad radiográfica. El método no destructivo tuvo su fundamento en la implementación de técnicas diagnósticas de imágenes tomográficas de hueso de mandíbula y el posterior reconocimiento de estas imágenes en un software Bio-CAD. A través del software MIMIC´S, se cuantificaron los valores de densidad a escala Hounsfield; los datos obtenidos fueron usados para deducir la curva de calibración lineal, permitiendo de esta forma, calcular el valor de densidad aparente de los especímenes. A partir de esta caracterización y la revisión de literatura, fue posible definir las propiedades mecánicas de la probeta ósea. De acuerdo con los resultados obtenidos en el presente trabajo de investigación, se estableció una alternativa para la caracterización mecánica de tejidos rígidos como el hueso. De acuerdo a la naturaleza no destructiva del método, el uso de este método podría ser extendido a experimentación con tejidos vivos, la cual estaba restringida, por las limitaciones existentes con el método destructivo basado en ensayos mecánicos.Abstract: Mechanical tests are used for characterization of mechanical properties of bone tissue; however, due to the destructive nature of the test, the specimens are generally used human cadaver bone tissues or animals. Furthermore the resultant characterization of these tests is valid only in the specimens tested, because the bone tissue shows high variability in their properties, so, the density change. This argument and the destructive nature of the mechanical tests are reason that this type of test is not appropriated for the mechanical characterization of living tissue, which limits the possibilities of development in live research projects. The present study was developed with the purpose of assessing the feasibility of using a non-destructive method to deduce the values of apparent density from radiographic density, supported by tomographic imaging diagnostic techniques in jaw bone and recognition these images in Bio-CAD software. Through software MIMIC’S, were quantified scale density values Hounsfield; these data were used to derive the linear calibration curve allowing calculating the apparent density of the specimens. From this characterization and review of literature, it was possible to determine the mechanical properties of the bone specimen. According to the results obtained in the present investigation, it was established an alternative to mechanical characterization through the application of non-destructive techniques, based on the analysis of Bio-CAD software and the calibration curve. Using this method could be extended to experiment with living tissue, which was restricted by the constraints with the destructive method based on mechanical tests

Fracture distribution in a folded fluvial succession: The Puig-reig anticline (south-eastern Pyrenees)

Sedimentary rocks of foreland fold-and-thrust belts typically undergo intensive fracturing as folds grow. The resulting fracture networks can present significant variations depending on the distribution of sedimentary facies and the complex structural characteristics of fold-and-thrust belts. The Puig-reig anticline, located in the south-eastern Pyrenees, mainly exposes proximal fluvial deposits in the north limb and medial fluvial deposits in the rest of the anticline. Thus, this anticline constitutes an excellent case study to investigate the main controls on the distribution of fracture networks in folded fluvial deposits, in terms of structural position and lithofacies variations. Outcrops were selected to be representative of different structural positions, from the fold hinge to its limbs, and of a variety of the main lithofacies, from proximal to medial fluvial deposits. Fracture data were acquired using the linear scanline method. The results indicate that the anticline rocks have been affected by four sets of fractures. The north limb is dominated by thick conglomerate bodies with interlayered sandstones deposited from unconfined flash floods and wide-shallow channel streams in the proximal fluvial fan, and presents large fracture spacing and low fracture intensity but relatively large fracture length and aperture. The crest and the crest-limb transition zones are mainly characterised by interlayered conglomerates, sandstones, siltstones and clays, deposited from braided channel streams and overbanks in the medial fluvial fan, and present fractures with relatively high fracture intensity and variable fracture length and aperture. The south limb, composed of channel filling sandstone layers and stable overbank fine deposits in the medial fluvial fan, is characterised by low fracture intensity and small fracture length and aperture. Based on multiple linear regression analysis, fracture intensity is mainly controlled by the structural position, bedding thickness and lithological associations, with relatively more intense fracturing in thin sandstone layers with multiple interlayers of fine deposits in the anticline crest. The fracture length mainly depends on bedding thickness and is affected lithological associations. The fracture apertures are mainly controlled by lithofacies, with relatively higher apertures affecting conglomerate bodies. The results of this study are relevant for characterising similar systems in the subsurface, where data is scarce

ENFERMERÍA Y EDUCACIÓN PARA LA SALUD EN NUTRICIÓN ENTERAL DOMICILIARIA.

Home enteral nutrition (HEN) allows, besides guaranteeing a correct nutricional treatment, improving patient autonomy and wellbeing along with a reduction of the expenditure on hospitalization. Due to the characteristics of this treatment, which is administered at home, Health Education becomes of high importance: the patient, their family and/or caregivers need to learn theoretical and practical aspects of this procedure. For this reason, one of the nursing tasks could be not only the identification and treatment of its complications, but also being a patient/family educator.La nutrición enteral domiciliaria (NED) permite, además de garantizar un correcto tratamiento nutricional, favorecer la autonomía y el bienestar del paciente, junto con una reducción del coste sanitario por hospitalización. Debido al carácter domiciliario de esta terapéutica, adquiere especial importancia en este procedimiento la Educación para la Salud (EpS), que deberá manifestarse mediante un aprendizaje teórico-práctico al paciente, familia y/o cuidadores. Es por esto, que el profesional de Enfermería puede ser requerido para atender a este tipo de pacientes, no sólo desde el punto de vista asistencial, con la identificación y tratamiento de las complicaciones, sino por su papel de educador al paciente y a sus familiares

Quantum walks: a comprehensive review

Quantum walks, the quantum mechanical counterpart of classical random walks, is an advanced tool for building quantum algorithms that has been recently shown to constitute a universal model of quantum computation. Quantum walks is now a solid field of research of quantum computation full of exciting open problems for physicists, computer scientists, mathematicians and engineers. In this paper we review theoretical advances on the foundations of both discrete- and continuous-time quantum walks, together with the role that randomness plays in quantum walks, the connections between the mathematical models of coined discrete quantum walks and continuous quantum walks, the quantumness of quantum walks, a summary of papers published on discrete quantum walks and entanglement as well as a succinct review of experimental proposals and realizations of discrete-time quantum walks. Furthermore, we have reviewed several algorithms based on both discrete- and continuous-time quantum walks as well as a most important result: the computational universality of both continuous- and discrete- time quantum walks.Comment: Paper accepted for publication in Quantum Information Processing Journa

Knowledge and attitudes of primary healthcare patients regarding population-based screening for colorectal cancer

<p>Abstract</p> <p>Background</p> <p>The aim of this study was to assess the extent of knowledge of primary health care (PHC) patients about colorectal cancer (CRC), their attitudes toward population-based screening for this disease and gender differences in these respects.</p> <p>Methods</p> <p>A questionnaire-based survey of PHC patients in the Balearic Islands and some districts of the metropolitan area of Barcelona was conducted. Individuals between 50 and 69 years of age with no history of CRC were interviewed at their PHC centers.</p> <p>Results</p> <p>We analyzed the results of 625 questionnaires, 58% of which were completed by women. Most patients believed that cancer diagnosis before symptom onset improved the chance of survival. More women than men knew the main symptoms of CRC. A total of 88.8% of patients reported that they would perform the fecal occult blood test (FOBT) for CRC screening if so requested by PHC doctors or nurses. If the FOBT was positive and a colonoscopy was offered, 84.9% of participants indicated that they would undergo the procedure, and no significant difference by gender was apparent. Fear of having cancer was the main reason for performance of an FOBT, and also for not performing the FOBT, especially in women. Fear of pain was the main reason for not wishing to undergo colonoscopy. Factors associated with reluctance to perform the FOBT were: <b><it>(i) </it></b>the idea that that many forms of cancer can be prevented by exercise and, <b><it>(ii) </it></b>a reluctance to undergo colonoscopy if an FOBT was positive. Factors associated with reluctance to undergo colonoscopy were: <b><it>(i) </it></b>residence in Barcelona, <b><it>(ii) </it></b>ignorance of the fact that early diagnosis of CRC is associated with better prognosis, <b><it>(iii) </it></b>no previous history of colonoscopy, and <b><it>(iv) </it></b>no intention to perform the FOBT for CRC screening.</p> <p>Conclusion</p> <p>We identified gaps in knowledge about CRC and prevention thereof in PHC patients from the Balearic Islands and the Barcelona region of Spain. If fears about CRC screening, and CRC per se, are addressed, and if it is emphasized that CRC is preventable, participation in CRC screening programs may improve.</p

Relationships between heavy metal concentrations in three different body fluids and male reproductive parameters: a pilot study

<p>Abstract</p> <p>Background</p> <p>Animal studies have shown the reproductive toxicity of a number of heavy metals. Very few human observational studies have analyzed the relationship between male reproductive function and heavy metal concentrations in diverse biological fluids.</p> <p>Methods</p> <p>The current study assessed the associations between seminal and hormonal parameters and the concentration of the 3 most frequent heavy metal toxicants (lead, cadmium and mercury) in three different body fluids. Sixty one men attending infertility clinics that participated in a case-control study to explore the role of environmental toxins and lifestyles on male infertility were analyzed. Concentration of lead, cadmium and mercury were measured in blood and seminal plasma and whole blood using anodic stripping voltammetry and atomic absorption spectrophotometry. Serum samples were analyzed for follicle-stimulating hormone, luteinizing hormone and testosterone. Semen analyses were performed according to World Health Organization criteria. Mann-Whitney test and Spearman's rank correlations were used for unadjusted analyses. Multiple linear regression models were performed controlling for age, body mass index and number of cigarettes per day.</p> <p>Results</p> <p>There were no significant differences between cases and controls in the concentrations of heavy metals in any of the three body fluids. In multivariate analyses using all subjects no significant associations were found between serum hormone levels and metal concentrations. However there was a significant positive association between the percentage of immotile sperms and seminal plasma levels of lead and cadmium.</p> <p>Conclusions</p> <p>Our results suggest that the presence of lead and cadmium in the reproductive tract of men may be related to a moderate alteration of their seminal parameters.</p