624 research outputs found
Heralded photonic interaction between distant single ions
We establish heralded interaction between two remotely trapped single 40Ca+
ions through the exchange of single photons. In the sender ion, we release
single photons with controlled temporal shape on the P_3/2 to D_5/2 transition
and transmit them to the distant receiver ion. Individual absorption events in
the receiver ion are detected by quantum jumps. For continuously generated
photons, the absorption reduces significantly the lifetime of the long-lived
D_5/2 state. For triggered single-photon transmission, we observe coincidence
between the emission at the sender and quantum jump events at the receiver.Comment: 5 pages, 4 figures. v2: number on p. 3, bottom, correcte
alkaline earth cations influence catalytic activity in a photosystem II-like fashion
In reaction sequences for light driven water-splitting into H2 and O2, water-
oxidation is a crucial reaction step. In vivo, the process is catalysed within
a photoenzyme called photosystem II (PSII) by a ÎĽ-oxido CaMn4 cluster, the
oxygen-evolving complex (OEC). The OEC is known to be virtually inactive if
Ca2+ is removed from its structure. Activity can be restored not only by the
addition of Ca2+ but also Sr2+ ions. We have recently introduced layered
calcium manganese oxides of the birnessite mineral family as functional
synthetic model compounds for the OEC. Here, we present the syntheses of
layered manganese oxides where we varied the interlayer cations, preparing a
series of K-, Ca-, Sr- and Mg-containing birnessites. Structural motifs within
these materials were determined using X-ray absorption spectroscopy (XAS)
showing that all materials have similar atomic structures despite their
different elemental compositions. Water-oxidation experiments were carried out
to elucidate structure-reactivity relations. These experiments demonstrated
that the oxides — like the OEC — require the presence of calcium in their
structures to reach maximum catalytic activity. As another similarity to the
OEC, Sr2+ is the “second best choice” for the secondary cation. The results
thus support mechanistic proposals which involve an important catalytic role
for Ca2+ in biological water-oxidation. Additionally, they offer valuable
hints for the development of synthetic, manganese-based water-oxidation
catalysts for artificial photosynthesis
Phantoms of Innovation: Disciplined Simulation for Ex-ante Evaluation in Design Science Research
For years, there has been an emphasis on how to efficiently and effectively identify, evaluate, and implement innovative information systems in both design science research (DSR) and practice. Nonetheless, still today, these efforts continue to be hampered by the temporal gap between ideation and evaluation. Usually, innovative ideas are implemented at a late stage of maturity (e.g., prototypes) to test their viability in practice. This widespread approach results in waste of resources and time if the viability of an idea fails outside the lab environment. This paper discusses an ex-ante evaluation approach derived from “pretotyping” that allows innovative ideas to be tested in naturalistic settings even before they have been implemented. Thus, we call them “phantoms”. We show how this approach reduces temporal and relevance gaps, and we provide a preliminary assessment of its practicability by presenting and discussing three case studies conducted with real organizations and prospective users
DoubleML -- An Object-Oriented Implementation of Double Machine Learning in R
The R package DoubleML implements the double/debiased machine learning
framework of Chernozhukov et al. (2018). It provides functionalities to
estimate parameters in causal models based on machine learning methods. The
double machine learning framework consist of three key ingredients: Neyman
orthogonality, high-quality machine learning estimation and sample splitting.
Estimation of nuisance components can be performed by various state-of-the-art
machine learning methods that are available in the mlr3 ecosystem. DoubleML
makes it possible to perform inference in a variety of causal models, including
partially linear and interactive regression models and their extensions to
instrumental variable estimation. The object-oriented implementation of
DoubleML enables a high flexibility for the model specification and makes it
easily extendable. This paper serves as an introduction to the double machine
learning framework and the R package DoubleML. In reproducible code examples
with simulated and real data sets, we demonstrate how DoubleML users can
perform valid inference based on machine learning methods.Comment: 40 pages, 7 Figure
Syntheses, Electrode Preparations, Electrolytes and Two Fundamental Questions
The efficient catalysis of the four-electron oxidation of water to molecular oxygen is a central challenge for the development of devices for the production of solar fuels. This is equally true for artificial leaf-type structures and electrolyzer systems. Inspired by the oxygen evolving complex of Photosystem II, the biological catalyst for this reaction, scientists around the globe have investigated the possibility to use manganese oxides (“MnOx”) for this task. This perspective article will look at selected examples from the last about 10 years of research in this field. At first, three aspects are addressed in detail which have emerged as crucial for the development of efficient electrocatalysts for the anodic oxygen evolution reaction (OER): (1) the structure and composition of the “MnOx” is of central importance for catalytic performance and it seems that amorphous, MnIII/IV oxides with layered or tunnelled structures are especially good choices; (2) the type of support material (e.g. conducting oxides or nanostructured carbon) as well as the methods used to immobilize the MnOx catalysts on them greatly influence OER overpotentials, current densities and long-term stabilities of the electrodes and (3) when operating MnOx-based water-oxidizing anodes in electrolyzers, it has often been observed that the electrocatalytic performance is also largely dependent on the electrolyte’s composition and pH and that a number of equilibria accompany the catalytic process, resulting in “adaptive changes” of the MnOx material over time. Overall, it thus has become clear over the last years that efficient and stable water-oxidation electrolysis by manganese oxides can only be achieved if at least four parameters are optimized in combination: the oxide catalyst itself, the immobilization method, the catalyst support and last but not least the composition of the electrolyte. Furthermore, these parameters are not only important for the electrode optimization process alone but must also be considered if different electrode types are to be compared with each other or with literature values from literature. Because, as without their consideration it is almost impossible to draw the right scientific conclusions. On the other hand, it currently seems unlikely that even carefully optimized MnOx anodes will ever reach the superb OER rates observed for iridium, ruthenium or nickel-iron oxide anodes in acidic or alkaline solutions, respectively. So at the end of the article, two fundamental questions will be addressed: (1) are there technical applications where MnOx materials could actually be the first choice as OER electrocatalysts? and (2) do the results from the last decade of intensive research in this field help to solve a puzzle already formulated in 2008: “Why did nature choose manganese to make oxygen?”
Comparison of a ceiling-mounted 3D flat panel detector vs. conventional intraoperative 2D fluoroscopy in plate osteosynthesis of distal radius fractures with volar locking plate systems
Methods Using a common volar approach on 12 cadaver forearms, total intraarticular distal radius fractures were induced, manually reduced and internally fixated with a 2.4 distal radius locking compression plate. 2D (anterior-posterior and lateral) and 3D (rotational) fluoroscopic images were taken as well as computed tomographies. Fluoroscopic images, Cone Beam CT (CBCT), 360° rotating sequences (so called "Movies") and CT scans were co-evaluated by a specialist orthopedic surgeon and a specialist radiologist regarding quality of fracture reduction, position of plate, position of the three distal locking screws and position of the three diaphyseal screws. In reference to gold standard CT, sensitivity and specifity were analyzed. Results "Movie" showed highest sensitivity for detection of insufficient fracture reduction (88%). Sensitivity for detection of incorrect position of plate was 100% for CBCT and 90% for "Movie." For intraarticular position of screws, 2D fluoroscopy and CBCT showed highest sensitivity and specifity (100 and 91%, respectively). Regarding detection of only marginal intraarticular position of screws, sensitivity and specifity of 2D fluoroscopy reached 100% (CBCT: 100 and 83%). "Movie" showed highest sensitivity for detection of overlapping position of screws (100%). When it comes to specifity, CBCT achieved 100%. Regarding detection of only marginal overlapping position of screws, 2D fluoroscopy and "Movie" showed highest sensitivity (100%). CBCT achieved highest specifity (100%). Conclusion As for assessment of quality of fracture reduction and detection of incorrect position of plate as well as overlapping position of the three diaphyseal screws CBCT and "Movie" are comparable to CT - especially when combined. Particularly sensitivity is high compared to standard 2D fluoroscopy
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