2,440 research outputs found
Viscosity and density of methanol/water mixtures at low temperatures
Viscosity and density are measured at low temperatures for three methanol/water mixtures. Viscosity is determined by a modified falling cylinder method or a calibrated viscometer. Density is determined by the volume of each mixture contained in a calibrated glass cell placed in a constant-temperature bath
A new class of highly efficient exact stochastic simulation algorithms for chemical reaction networks
We introduce an alternative formulation of the exact stochastic simulation
algorithm (SSA) for sampling trajectories of the chemical master equation for a
well-stirred system of coupled chemical reactions. Our formulation is based on
factored-out, partial reaction propensities. This novel exact SSA, called the
partial propensity direct method (PDM), is highly efficient and has a
computational cost that scales at most linearly with the number of chemical
species, irrespective of the degree of coupling of the reaction network. In
addition, we propose a sorting variant, SPDM, which is especially efficient for
multiscale reaction networks.Comment: 23 pages, 3 figures, 4 tables; accepted by J. Chem. Phy
Threshold electronic structure at the oxygen K edge of 3d transition metal oxides: a configuration interaction approach
It has been generally accepted that the threshold structure observed in the
oxygen K edge X-ray absorption spectrum in 3d transition metal oxides
represents the electronic structure of the 3d transition metal. There is,
however, no consensus about the correct description. We present an
interpretation, which includes both ground state hybridization and electron
correlation. It is based on a configuration interaction cluster calculation
using a MO6 cluster. The oxygen K edge spectrum is calculated by annihilating a
ligand hole in the ground state and is compared to calculations representing
inverse photoemission experiments in which a 3d transition metal electron is
added. Clear differences are observed related to the amount of ligand hole
created in the ground state. Two "rules" connected to this are discussed.
Comparison with experimental data of some early transition metal compounds is
made and shows that this simple cluster approach explains the experimental
features quite well.Comment: 10 pages, submitted to Phys. Rev. B, tried to make a better PS file
Bacillus anthracis Bioterrorism Incident, Kameido, Tokyo, 1993
In July 1993, a liquid suspension of Bacillus anthracis was aerosolized from the roof of an eight-story building in Kameido, Tokyo, Japan, by the religious group Aum Shinrikyo. During 1999 to 2001, microbiologic tests were conducted on a liquid environmental sample originally collected during the 1993 incident. Nonencapsulated isolates of B. anthracis were cultured from the liquid. Multiple-locus, variable-number tandem repeat analysis found all isolates to be identical to a strain used in Japan to vaccinate animals against anthrax, which was consistent with the Aum Shinrikyo members’ testimony about the strain source. In 1999, a retrospective case-detection survey was conducted to identify potential human anthrax cases associated with the incident, but none were found. The use of an attenuated B. anthracis strain, low spore concentrations, ineffective dispersal, a clogged spray device, and inactivation of the spores by sunlight are all likely contributing factors to the lack of human cases
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Regional-scale chemical transport modeling in support of the analysis of observations obtained during the TRACE-P experiment
Data obtained during the TRACE-P experiment is used to evaluate how well the CFORS/STEM-2K1 regional-scale chemical transport model is able to represent the aircraft observations. Thirty-one calculated trace gas and aerosol parameters are presented and compared to the in situ data. The regional model is shown to accurately predict many of the important features observed. The mean values of all the model parameters in the lowest 1 km are predicted within ±30% of the observed values. The correlation coefficients (R) for the meteorological parameters are found to be higher than those for the trace species. For example, for temperature, R \u3e 0.98. Among the trace species, ethane, propane, and ozone show the highest values (0.8 \u3c R \u3c 0.9), followed by CO, SO2, and NOy, NO and NO2 had the lowest values (R \u3c 0.4). Analyses of pollutant transport into the Yellow Sea by frontal events are presented and illustrate the complex nature of outflow. Biomass burning from SE Asia is transported in the warm conveyor belt at altitudes above ∼2 km and at latitudes below 30N. Outflow of pollution emitted along the east coast of China in the postfrontal regions is typically confined to the lower ∼2 km and results in high concentrations with plume-like features in the Yellow Sea. During these situations the model underpredicts CO and black carbon (among other species). An analysis of ozone production in this region is also presented. In and around the highly industrialized regions of East Asia, where fossil fuel usage dominates, ozone is NMHC-limited. South of ∼30-35N, ozone production is NOx-limited, reflecting the high NMHC/NOx ratios due to the large contributions to the emissions from biomass burning, biogenics sources, and biofuel usage in central China and SE Asia. Copyright 2003 by the American Geophysical Union
Acceleration effect of coupled oscillator systems
We have developed a curved isochron clock (CIC) by modifying the radial
isochron clock to provide a clean example of the acceleration (deceleration)
effect. By analyzing a two-body system of coupled CICs, we determined that an
unbalanced mutual interaction caused by curved isochron sets is the minimum
mechanism needed for generating the acceleration (deceleration) effect in
coupled oscillator systems. From this we can see that the Sakaguchi and
Kuramoto (SK) model which is a class of non-frustrated mean feild model has an
acceleration (deceleration) effect mechanism. To study frustrated coupled
oscillator systems, we extended the SK model to two oscillator associative
memory models, one with symmetric and one with asymmetric dilution of coupling,
which also have the minimum mechanism of the acceleration (deceleration)
effect. We theoretically found that the {\it Onsager reaction term} (ORT),
which is unique to frustrated systems, plays an important role in the
acceleration (de! celeration) effect. These two models are ideal for evaluating
the effect of the ORT because, with the exception of the ORT, they have the
same order parameter equations. We found that the two models have identical
macroscopic properties, except for the acceleration effect caused by the ORT.
By comparing the results of the two models, we can extract the effect of the
ORT from only the rotation speeds of the oscillators.Comment: 35 pages, 10 figure
MOA 2003-BLG-37: A Bulge Jerk-Parallax Microlens Degeneracy
We analyze the Galactic bulge microlensing event MOA-2003-BLG-37. Although
the Einstein timescale is relatively short, t_e=43 days, the lightcurve
displays deviations consistent with parallax effects due to the Earth's
accelerated motion. We show that the chi^2 surface has four distinct local
minima that are induced by the ``jerk-parallax'' degeneracy, with pairs of
solutions having projected Einstein radii, \tilde r_e = 1.76 AU and 1.28 AU,
respectively. This is the second event displaying such a degeneracy and the
first toward the Galactic bulge. For both events, the jerk-parallax formalism
accurately describes the offsets between the different solutions, giving hope
that when extra solutions exist in future events, they can easily be found.
However, the morphologies of the chi^2 surfaces for the two events are quite
different, implying that much remains to be understood about this degeneracy.Comment: 19 pages, 3 figures, 1 table, ApJ, in press, 1 July 200
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