678 research outputs found
Graphitization of amorphous carbon by swift heavy ion impacts: Molecular dynamics simulation
Stable C-C bonds existing in several sp hybridizations place carbon thin films of different structural compositions amongst the materials most tolerant to radiation damage, for applications in extreme environments. One of such applications, solid state electron stripper foils for heavy-ion accelerators, requires the understanding of the structural changes induced by high-energy ion irradiation. Tolerance of carbon structure to radiation damage, thermal effects and stress waves due to swift heavy ion impacts defines the lifetime and operational efficiency of the foils. In this work, we analyze the consequences of a single swift heavy ion impact on two different amorphous carbon structures by means of molecular dynamic simulations. The structures are constructed by using two different recipes to exclude the correlation of the evolution of sp2-to-sp3 hybridization with the initial condition. Both initial structures contain approximately 60% of sp2-bonded carbon atoms, however, with different degree of clustering of atoms with sp3 hybridization. We simulate the swift heavy ion impact employing an instantaneous inelastic thermal spike model. The analysis of changes in density, bonding content and the number and size of carbon primitive rings reveals graphitization of the material within the ion track, with higher degree of disorder in the core and more order in the outer shell. Simulated track dimensions are comparable to those observed in small angle x-ray scattering measurements of evaporation-deposited amorphous carbon stripper foils irradiated by 1.14 GeV U ions.Katharina Kupka gratefully acknowledges support by BMBF (contract No.
05P12RDRBL) and HGS-HIRe Graduate School. W.R., H.V. and K.N. acknowledge
funding from the Academy of Finland project HISCON. We also thank the CSC-IT
Center for Science Ltd for generous grants of computer time. PK acknowledges the
Australian Research Council for financial support. Part of this research was undertaken
on the SAXS/WAXS beamline at the Australian Synchrotron
Electronic States in Diffused Quantum Wells
In the present study we calculate the energy values and the spatial
distributions of the bound electronic states in some diffused quantum wells.
The calculations are performed within the virtual crystal approximation, spin dependent empirical tight-binding model and the surface Green
function matching method. A good agreement is found between our results and
experimental data obtained for AlGaAs/GaAs quantum wells with thermally induced
changes in the profile at the interfaces. Our calculations show that for
diffusion lengths {\AA} the transition (C3-HH3) is not
sensitive to the diffusion length, but the transitions (C1-HH1), (C1-LH1),
(C2-HH2) and (C2-LH2) display large "blue shifts" as L_{D} increases. For
diffusion lengths {\AA} the transitions (C1-HH1) and (C1-LH1)
are less sensitive to the L_{D} changes than the (C3-HH3) transition. The
observed dependence is explained in terms of the bound states spatial
distributions.Comment: ReVTeX file, 7pp., no macros, 4 figures available on the reques
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Predictors of Stunting, Wasting and Underweight among Tanzanian Children Born to HIV-Infected Women.
Children born to human immunodeficiency virus (HIV)-infected women are susceptible to undernutrition, but modifiable risk factors and the time course of the development of undernutrition have not been well characterized. The objective of this study was to identify maternal, socioeconomic and child characteristics that are associated with stunting, wasting and underweight among Tanzanian children born to HIV-infected mothers, followed from 6 weeks of age for 24 months. Maternal and socioeconomic characteristics were recorded during pregnancy, data pertaining to the infant's birth were collected immediately after delivery, morbidity histories and anthropometric measurements were performed monthly. Multivariate Cox proportional hazards methods were used to assess the association between potential predictors and the time to first episode of stunting, wasting and underweight. A total of 2387 infants (54.0% male) were enrolled and followed for a median duration of 21.2 months. The respective prevalence of prematurity (<37 weeks) and low birth weight (<2500 g) was 15.2% and 7.0%; 11.3% of infants were HIV-positive at 6 weeks. Median time to first episode of stunting, wasting and underweight was 8.7, 7.2 and 7.0 months, respectively. Low maternal education, few household possessions, low infant birth weight, child HIV infection and male sex were all independent predictors of stunting, wasting and underweight. In addition, preterm infants were more likely to become wasted and underweight, whereas those with a low Apgar score at birth were more likely to become stunted. Interventions to improve maternal education and nutritional status, reduce mother-to-child transmission of HIV, and increase birth weight may lower the risk of undernutrition among children born to HIV-infected women
Serum hyaluronic acid as a potential marker with a predictive value for further radiographic progression of hand osteoarthritis
SummaryObjectiveTo compare serum levels of hyaluronic acid (HA) between patients with erosive and non-erosive hand osteoarthritis (HOA), and investigate its association with morphological changes and radiographic progression over 2 years.MethodsFifty-five women with erosive and 33 women with non-erosive HOA were included in this study. All underwent clinical examination, which included assessment of pain, swelling, deformity and deviation of small hand joints and completed health assessment questionnaires. Serum levels of HA were measured by ELISA. Three-phase bone scintigraphy was performed at baseline. Radiographs of both hands were performed at baseline and after 2 years and scored according Kallman grading scale.ResultsSerum levels of HA were significantly higher in patients with erosive than with non-erosive HOA (P<0.01). It correlated significantly with the number of hand joints with deviations and deformities. HA adjusted for age and disease duration significantly correlated with radiographs at baseline and after 2 years in all patients with HOA (r=0.560 and r=0.542, P<0.01 for both correlations). Although there was an association between HA and radiographic score in erosive disease, after adjustment for confounders it remained no longer significant. HA adjusted for confounders correlated significantly with the late phase in all patients with HOA (r=0.412, P<0.01) and in patients with erosive disease (r=0.320, P<0.05).ConclusionHA is increased in patients with erosive HOA and could be proposed as a surrogate marker with a predictive value for further radiographic progression of HOA in general. Further investigation is necessary to confirm these results
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