3,495 research outputs found
Many-body Green's function theory for thin ferromagnetic films: exact treatment of the single-ion anisotropy
A theory for the magnetization of ferromagnetic films is formulated within
the framework of many-body Green's funtion theory which considers all
components of the magnetization. The model Hamiltonian includes a Heisenberg
term, an external field, a second- and fourth-order uniaxial single-ion
anisotropy, and the magnetic dipole-dipole coupling. The single-ion anisotropy
terms can be treated exactly by introducing higher-order Green's functions and
subsequently taking advantage of relations between products of spin operators
which leads to an automatic closure of the hierarchy of the equations of motion
for the Green's functions with respect to the anisotropy terms. This is an
improvement on the method of our previous work, which treated the corresponding
terms only approximately by decoupling them at the level of the lowest-order
Green's functions. RPA-like approximations are used to decouple the exchange
terms in both the low-order and higher-order Green's functions. As a first
numerical example we apply the theory to a monolayer for spin S=1 in order to
demonstrate the superiority of the present treatment of the anisotropy terms
over the previous approximate decouplings.Comment: 23 pages, 5 figure
Degradation of epoxy coatings under gamma irradiation
Epoxy networks based on Diglycidyl ether of bisphenol A (DGEBA) and cured with Jeffamines (POPA) or polyamidoamine (PAA) were gamma irradiated at 25 1C in air. Dose rates of 50, 200 or 2000 Gy h- 1 for doses up 100 kGy were used. Structural changes were monitored by IR spectrophotometry, DSC and sol–gel analysis. Both networks display some common features: for I Z 200 Gy h- 1, reaction products grow proportionally to time and the rate is a decreasing function of dose rate. The simplest explanation is that peroxy radicals are the main precursors of these products (in the dose rate domain under study), through a unimolecular rearrangement of which an hypothetical mechanism is proposed. DGEBA–POPA are more reactive then DGEBA–PAA networks (according to IR criteria), that can be attributed to the high reactivity of tertiary CH bands in polyoxypropylene segments. The oxidation of these sites leads to methyl ketones. A simple kinetic model in which methyl ketones result from rearrangements of tertiary peroxyls and from tertiary alkoxyls was proposed. It leads to an expression of the radiochemical yield of methyl ketones (G(MK)) of the form GðMKÞ¼ a þ bI-1=2 where a and b are parameters depending of elementary rate constants. Experimental G(MK) values are reasonably well fitted by this equation. In DGEBA–PAA networks, a wide variety of oxidation products, among which amides predominate, can be observed. In these networks, chain scissions predominate over crosslinking, whereas a slight predominance of crosslinking was observed, at least for the lowest dose rate, in DGEBA–POPA
Деякі особливості інноваційного розвитку Західного регіону України в контексті конкурентноспроможності
Головною метою державної інноваційної політики визначено створення соціально-економічних, організаційних і правових умов для ефективного відтворення, розвитку й використання науково-технічного потенціалу країни, забезпечення впровадження, виробництва і реалізації нових видів конкурентноздатної продукці
Thermo-oxidative aging of epoxy coating systems
tThe thermo-oxidative behavior of unformulated (unfilled) samples of epoxy coatings has been studiedat five temperatures ranging from 70◦C to 150◦C. Two epoxy networks based on diglycidyl ether ofbisphenol A (DGEBA), respectively, cured by jeffamine (POPA) or polyamidoamine (PAA) were compared.Infrared spectrophotometry (IR), differential scanning (DSC) and sol–gel analysis (SGA) were used tomonitor structural changes.Thermal oxidation leads to carbonyl and amide formation in both systems. POPA systems appear moresensitive to oxidation than PAA ones. Thermal oxidation leads to predominant chain scission as evidencedby the decrease of glass transition temperatures (Tg) and increase of sol fraction
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A Catalog of Galaxy Clusters Observed by XMM-Newton
Aims: We present a uniform catalog of the images and radial profiles of the
temperature, abundance, and brightness for 70 clusters of galaxies observed by
XMM-Newton.
Methods: We use a new "first principles" approach to the modeling and removal
of the background components; the quiescent particle background, the cosmic
diffuse emission, the soft proton contamination, and the solar wind charge
exchange emission. Each of the background components demonstrate significant
spectral variability, several have spatial distributions that are not described
by the photon vignetting function, and all except for the cosmic diffuse
emission are temporally variable. Because these backgrounds strongly affect the
analysis of low surface brightness objects, we provide a detailed description
our methods of identification, characterization, and removal.
Results: We have applied these methods to a large collection of XMM-Newton
observations of clusters of galaxies and present the resulting catalog. We find
significant systematic differences between the Chandra and XMM-Newton
temperatures.Comment: Accepted for publication in A&A, 55 pages with 42 figure
The X-ray Properties of M101 ULX-1 = CXOKM101 J140332.74+542102
We report our analysis of X-ray data on M101 ULX-1, concentrating on high
state Chandra and XMM-Newton observations. We find that the high state of M101
ULX-1 may have a preferred recurrence timescale. If so, the underlying clock
may have periods around 160 or 190 days, or possibly around 45 days. Its
short-term variations resemble those of X-ray binaries at high accretion rate.
If this analogy is correct, we infer that the accretor is a 20-40 Msun object.
This is consistent with our spectral analysis of the high state spectra of M101
ULX-1, from which we find no evidence for an extreme (> 10^40 ergs/s)
luminosity. We present our interpretation in the framework of a high mass X-ray
binary system consisting of a B supergiant mass donor and a large stellar-mass
black hole.Comment: 23 pages, 7 figures, accepted for publication in the Astrophysical
Journa
Introducing the microbiome into Precision Medicine
© The Author(s), 2016. This is the author's version of the work and is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Trends in Pharmacological Sciences 38 (2017): 81-91, doi:10.1016/j.tips.2016.10.001.Understanding how individual people respond to medical therapy is a key facet of improving the odds ratio that interventions will have a positive impact. Reducing the non-responder rate for an intervention or reducing complications associated with a particular treatment or surgery is the next stage of medical advance. The Precision Medicine Initiative, launched in January 2015, set the stage for enhanced collaboration between researchers and medical professionals to develop next-generation techniques to aid patient treatment and recovery, and increased the opportunities for impactful pre-emptive care. The microbiome plays a crucial role in health and disease, as it influences endocrinology, physiology, and even neurology, altering the outcome of many different disease states, and it augments drug responses and tolerance. We review the implications of the microbiome on precision health initiatives and highlight excellent examples, whereby precision microbiome health has been implemented.2017-11-0
Fragmentation Phase Transition in Atomic Clusters II - Coulomb Explosion of Metal Clusters -
We discuss the role and the treatment of polarization effects in many-body
systems of charged conducting clusters and apply this to the statistical
fragmentation of Na-clusters. We see a first order microcanonical phase
transition in the fragmentation of for Z=0 to 8. We can
distinguish two fragmentation phases, namely evaporation of large particles
from a large residue and a complete decay into small fragments only. Charging
the cluster shifts the transition to lower excitation energies and forces the
transition to disappear for charges higher than Z=8. At very high charges the
fragmentation phase transition no longer occurs because the cluster
Coulomb-explodes into small fragments even at excitation energy .Comment: 19 text pages +18 *.eps figures, my e-mail adress: [email protected]
submitted to Z. Phys.
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