6,408 research outputs found
Specific Heat of the Ca-Intercalated Graphite Superconductor CaC
The superconducting state of Ca-intercalated graphite CaC6 has been
investigated by specific heat measurements. The characteristic anomaly at the
superconducting transition (Tc = 11.4 K) indicates clearly the bulk nature of
the superconductivity. The temperature and magnetic field dependence of the
electronic specific heat are consistent with a fully-gapped superconducting
order parameter. The estimated electron-phonon coupling constant is lambda =
0.60 - 0.74 suggesting that the relatively high Tc of CaC6 can be explained
within the weak-coupling BCS approach.Comment: 4 pages, 4 figs, submitted to Phys. Rev. Let
Normal origamis of Mumford curves
An origami (also known as square-tiled surface) is a Riemann surface covering
a torus with at most one branch point. Lifting two generators of the
fundamental group of the punctured torus decomposes the surface into finitely
many unit squares. By varying the complex structure of the torus one obtains
easily accessible examples of Teichm\"uller curves in the moduli space of
Riemann surfaces. The p-adic analogues of Riemann surfaces are Mumford curves.
A p-adic origami is defined as a covering of Mumford curves with at most one
branch point, where the bottom curve has genus one. A classification of all
normal non-trivial p-adic origamis is presented and used to calculate some
invariants. These can be used to describe p-adic origamis in terms of glueing
squares.Comment: 21 pages, to appear in manuscripta mathematica (Springer
Superconductivity in Heavy Alkaline-Earths Intercalated Graphites
We report the discovery of superconductivity below 1.65(6) K in
Sr-intercalated graphite SrC6, by susceptibility and specific heat (Cp)
measurements. In comparison with CaC6, we found that the anisotropy of the
upper critical fields for SrC6 is much reduced. The Cp anomaly at Tc is smaller
than the BCS prediction indicating an anisotropic superconducting gap for SrC6
similar to CaC6. The significantly lower Tc of SrC6 as compared to CaC6 can be
understood in terms of "negative" pressure effects, which decreases the
electron-phonon coupling for both in-plane intercalant and the out-of-plane C
phonon modes. We observed no superconductivity for BaC6 down to 0.3 K.Comment: 4 pages, 4 figures, submitted to Phys. Rev. Let
Revealing the pure confinement effect in glass-forming liquids by dynamic mechanical analysis
Many molecular glass forming liquids show a shift of the glass transition Tg
to lower temperatures when the liquid is confined into mesoporous host
matrices. Two contrary explanations for this effect are given in literature:
First, confinement induced acceleration of the dynamics of the molecules leads
to an effective downshift of Tg increasing with decreasing pore size. Secondly,
due to thermal mismatch between the liquid and the surrounding host matrix,
negative pressure develops inside the pores with decreasing temperature, which
also shifts Tg to lower temperatures. Here we present novel dynamic mechanical
analysis measurements of the glass forming liquid salol in Vycor and Gelsil
with pore sizes of d = 2.6, 5.0 and 7.5 nm. The dynamic complex elastic
susceptibility data can be consistently described with the assumption of two
relaxation processes inside the pores: A surface induced slowed down relaxation
due to interaction with rough pore interfaces and a second relaxation within
the core of the pores. This core relaxation time is reduced with decreasing
pore size d, leading to a downshift of Tg in perfect agreement with recent DSC
measurements
Soil quality improvement under an ecologically based farming system in northwest Missouri
Ecologically based farming conserves and improves the soil resource and protects environmental quality by using organic or natural resources without the application of synthetic chemicals. Soil quality assessment indicates the ability of management systems to optimize soil productivity and to maintain its structural and biological integrity. Our objective was to evaluate the effect of ecologically based management on biochemical characteristics of soil [soil quality indicators (SQI)] as an assessment of soil quality. The study was conducted on an ecologically based farming enterprise established on gently sloping soils of Sharpsburg silt loam (fine montmorillonitic, mesic Typic Argiudolls) in Clay County, Missouri, which was previously under conventional corn and soybean production. The transition to organic farming began in 1995, which included a primary management strategy to restore soil organic matter consisting of the establishment of native prairie plants and the application of composted vegetative residues and litter from horse and laying hen operations. Soils were collected at 0–10cm depths from sites under organic production (orchard and vegetable), managed prairie/pasture and from adjacent unmanaged fields during 2003–2008 for soil quality assessment. Soil organic carbon (SOC) and waterstable soil aggregates were considerably increased by up to 60 and 72%, respectively, in organic production sites compared with tilled cropland by the fifth year of assessment. Organically managed systems and restored prairie sites significantly increased (P\u3c0.05) soil enzyme activities compared with unmanaged grass and tilled cropland. For example, dehydrogenase and glucosaminidase activities increased by 60 and 73%, respectively, under organic vegetables compared with tilled cropland. Soil enzyme activities were significantly correlated with SOC content (r values up to 0.90, P\u3c0.001). The results of the soil quality assessment suggest that ecologically based management successfully restored biological activity of silt loam soils previously under intensive conventional agriculture. The system practiced at the study sites illustrates how resources internal to the farm (i.e., composts) can be used to manage soil productivity
Plastic-crystalline solid-state electrolytes: Ionic conductivity and orientational dynamics in nitrile mixtures
Many plastic crystals, molecular solids with long-range, center-of-mass
crystalline order but dynamic disorder of the molecular orientations, are known
to exhibit exceptionally high ionic conductivity. This makes them promising
candidates for applications as solid-state electrolytes, e.g., in batteries.
Interestingly, it was found that the mixing of two different
plastic-crystalline materials can considerably enhance the ionic dc
conductivity, an important benchmark quantity for electrochemical applications.
An example is the admixture of different nitriles to succinonitrile, the latter
being one of the most prominent plastic-crystalline ionic conductors. However,
until now only few such mixtures were studied. In the present work, we
investigate succinonitrile mixed with malononitrile, adiponitrile, and
pimelonitrile, to which 1 mol% of Li ions were added. Using differential
scanning calorimetry and dielectric spectroscopy, we examine the phase behavior
and the dipolar and ionic dynamics of these systems. We especially address the
mixing-induced enhancement of the ionic conductivity and the coupling of the
translational ionic mobility to the molecular reorientational dynamics,
probably arising via a "revolving-door" mechanism.Comment: 9 pages, 7 figures; revised version as accepted for publication in J.
Chem. Phy
Confinement effects on glass forming liquids probed by DMA
Many molecular glass forming liquids show a shift of the glass transition T-g
to lower temperatures when the liquid is confined into mesoporous host
matrices. Two contrary explanations for this effect are given in literature:
First, confinement induced acceleration of the dynamics of the molecules leads
to an effective downshift of T-g increasing with decreasing pore size. Second,
due to thermal mismatch between the liquid and the surrounding host matrix,
negative pressure develops inside the pores with decreasing temperature, which
also shifts T-g to lower temperatures. Here we present dynamic mechanical
analysis measurements of the glass forming liquid salol in Vycor and Gelsil
with pore sizes of d=2.6, 5.0 and 7.5 nm. The dynamic complex elastic
susceptibility data can be consistently described with the assumption of two
relaxation processes inside the pores: A surface induced slowed down relaxation
due to interaction with rough pore interfaces and a second relaxation within
the core of the pores. This core relaxation time is reduced with decreasing
pore size d, leading to a downshift of T-g proportional to 1/d in perfect
agreement with recent differential scanning calorimetry (DSC) measurements.
Thermal expansion measurements of empty and salol filled mesoporous samples
revealed that the contribution of negative pressure to the downshift of T-g is
small (<30%) and the main effect is due to the suppression of dynamically
correlated regions of size xi when the pore size xi approaches
Effect of Pressure on Superconducting Ca-intercalated Graphite CaC
The pressure effect on the superconducting transition temperature () of
the newly-discovered Ca-intercalated graphite compound CaC has been
investigated up to 16 kbar. is found to increase under pressure
with a large relative ratio / of +0.4 %/kbar. Using
first-principles calculations, we show that the large and positive effect of
pressure on can be explained in the scope of electron-phonon theory due
to the presence of a soft phonon branch associated to in-plane vibrations of Ca
atoms. Implications of the present findings on the current debate about the
superconducting mechanism in graphite intercalation compounds are discussed.Comment: 6 pages, 5 figs, final PRB versio
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