Local Magnetic Susceptibility of the Positive Muon in the Quasi 1D S=1/2 Antiferromagnet KCuF3_3

We report muon spin rotation measurements of the local magnetic susceptibility around a positive muon in the paramagnetic state of the quasi one-dimensional spin 1/2 antiferromagnet KCuF$_3$. Signals from two distinct sites are resolved which have a temperature dependent frequency shift which is different than the magnetic susceptibility. This difference is attributed to a muon induced perturbation of the spin 1/2 chain.Comment: 13 pages, 4 figures, The 2002 International Conference on Muon Spin Rotation, Relaxation and Resonance, Virginia. US

Hyperfine Fields in an Ag/Fe Multilayer Film Investigated with 8Li beta-Detected Nuclear Magnetic Resonance

Low energy $\beta$-detected nuclear magnetic resonance ($\beta$-NMR) was used to investigate the spatial dependence of the hyperfine magnetic fields induced by Fe in the nonmagnetic Ag of an Au(40 \AA)/Ag(200 \AA)/Fe(140 \AA) (001) magnetic multilayer (MML) grown on GaAs. The resonance lineshape in the Ag layer shows dramatic broadening compared to intrinsic Ag. This broadening is attributed to large induced magnetic fields in this layer by the magnetic Fe layer. We find that the induced hyperfine field in the Ag follows a power law decay away from the Ag/Fe interface with power $-1.93(8)$, and a field extrapolated to $0.23(5)$ T at the interface.Comment: 5 pages, 4 figure. To be published in Phys. Rev.

Muonium as a hydrogen analogue in silicon and germanium; quantum effects and hyperfine parameters

We report a first-principles theoretical study of hyperfine interactions, zero-point effects and defect energetics of muonium and hydrogen impurities in silicon and germanium. The spin-polarized density functional method is used, with the crystalline orbitals expanded in all-electron Gaussian basis sets. The behaviour of hydrogen and muonium impurities at both the tetrahedral and bond-centred sites is investigated within a supercell approximation. To describe the zero-point motion of the impurities, a double adiabatic approximation is employed in which the electron, muon/proton and host lattice degrees of freedom are decoupled. Within this approximation the relaxation of the atoms of the host lattice may differ for the muon and proton, although in practice the difference is found to be slight. With the inclusion of zero-point motion the tetrahedral site is energetically preferred over the bond-centred site in both silicon and germanium. The hyperfine and superhyperfine parameters, calculated as averages over the motion of the muon, agree reasonably well with the available data from muon spin resonance experiments.Comment: 20 pages, including 9 figures. To appear in Phys. Rev.

Spin Echo Decay in a Stochastic Field Environment

We derive a general formalism with which it is possible to obtain the time dependence of the echo size for a spin in a stochastic field environment. Our model is based on ``strong collisions''. We examine in detail three cases where: (I) the local field is Ising-like, (II) the field distribution is continuous and has a finite second moment, and (III) the distribution is Lorentzian. The first two cases show a T2 minimum effect and are exponential in time cubed for short times. The last case can be approximated by a phenomenological stretched exponential.Comment: 11 pages + 3 postscript figure

Giant Vortices Below the Surface of NbSe2_2 Detected Using Low Energy β\beta-NMR

A low energy radioactive beam of polarized $^8$Li has been used to observe the vortex lattice near the surface of superconducting NbSe$_2$. The inhomogeneous magnetic field distribution associated with the vortex lattice was measured using depth-resolved $\beta$-detected NMR. Below $T_c$ one observes the characteristic lineshape for a triangular vortex lattice which depends on the magnetic penetration depth and vortex core radius. The size of the vortex core varies strongly with magnetic field. In particular in a low field of 10.8 mT the core radius is much larger than the coherence length. The possible origin of these giant vortices is discussed.Comment: 5 pages, 3 figures. Submitted to Phys. Rev. Let

Temporal mapping of photochemical reactions and molecular excited states with carbon specificity

Photochemical reactions are essential to a large number of important industrial and biological processes. A method for monitoring photochemical reaction kinetics and the dynamics of molecular excitations with spatial resolution within the active molecule would allow a rigorous exploration of the pathway and mechanism of photophysical and photochemical processes. Here we demonstrate that laser-excited muon pump-probe spin spectroscopy (photo-μSR) can temporally and spatially map these processes with a spatial resolution at the single-carbon level in a molecule with a pentacene backbone. The observed time-dependent light-induced changes of an avoided level crossing resonance demonstrate that the photochemical reactivity of a specific carbon atom is modified as a result of the presence of the excited state wavefunction. This demonstrates the sensitivity and potential of this technique in probing molecular excitations and photochemistry