Polymers pushing Polymers: Polymer Mixtures in Thermodynamic Equilibrium with a Pore

We investigate polymer partitioning from polymer mixtures into nanometer size cavities by formulating an equation of state for a binary polymer mixture assuming that only one (smaller) of the two polymer components can penetrate the cavity. Deriving the partitioning equilibrium equations and solving them numerically allows us to introduce the concept of "polymers-pushing-polymers" for the action of non-penetrating polymers on the partitioning of the penetrating polymers. Polymer partitioning into a pore even within a very simple model of a binary polymer mixture is shown to depend in a complicated way on the composition of the polymer mixture and/or the pore-penetration penalty. This can lead to enhanced as well as diminished partitioning, due to two separate energy scales that we analyse in detail.Comment: 10 pages, 6 figure

All particle energy spectrum of cosmic rays in 10 to the 15th power - 10 to the 20th power eV region

Average estimations of the shower energy components are presented and their sum gives E sub 0 (Rho sub 600) - an average function of the relation of E sub 0 with the shower size parameter Rho sub 600 measured at the Yakutsk extensive air showers (EAS) array. Using this relation to the EAS spectrum obtained at the Akeno and Yakutsk arrays the energy spectrum of the cosmic ray total flux within 15 lg (E sub 0,eV) 20 by the EAS methods is recovered