539 research outputs found

    RXJ 0921+4529: a binary quasar or gravitational lens?

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    We report the new spectroscopic observations of the gravitational lens RXJ 021+4529 with the multi-mode focal reducer SCORPIO of the SAO RAS 6-m telescope. The new spectral observations were compared with the previously observed spectra of components A and B of RXJ 0921+4529, i.e. the same components observed in different epochs. We found a significant difference in the spectrum between the components that cannot be explained with microlensing and/or spectral variation. We conclude that RXJ 0921+4529 is a binary quasar system, where redshifts of quasars A and B are 1.6535 +/- 0.0005 and 1.6625 +/- 0.0015, respectively.Comment: 6 pages, 5 figures, accepted for publication in The Astrophysical Journal Letter

    Geometry of Molecules. Part 4. Iterative Maximum Overlap Calculations of lnteratomic Distances, Bond Angles and Strain Energies in Some Rotanes and Related Spiro-Compounds

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    The iterative maximum overlap approximation (IMOA) is applied to a series of [n]-rotanes and some related spiro-compounds of unusual topology. The properties of these molecules were discussed in terms of the local hybrid orbitals and extent of their overlapping. Necessity of a clear distinction between bond length and interatomic distance in strained systems is pointed out. Considerableshortening of the C-C interatomic distance of the central carbocycles in [n]-rotanes was established. It was rationalized by the bent bond concept. The delocalization of the pseudo-pi electrons around the central ring in [n]-rotanes is briefly discussed. Angular strain energy and its distribution over the molecular fragments was quantitatively considered in the studied compounds. The strain and heat of formation of spiro (3.3) heptane are favourably compared with available ab initio results

    Estimating residual value of heavy construction equipment using ensemble learning

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    Knowing the right moment for the sale of used heavy construction equipment is important information for every construction company. The proposed methodology uses ensemble machine learning techniques to estimate the price (residual value) of used heavy equipment in both the present and the near future. Each machine in the model is represented with four groups of attributes: age and mechanical (describing the machine) and geographical and economic (describing the target market). The research suggests that the ensemble model based on random forest, light gradient boosting, and neural network members, as well as support vector regression as a decision unit, gives better estimates than the traditional regression or individual machine learning models. The model is built and verified on a large data set of 500,000 machines advertised in 50 US states from 1989 to 2012

    Geometry of Molecules. Part 4. Iterative Maximum Overlap Calculations of lnteratomic Distances, Bond Angles and Strain Energies in Some Rotanes and Related Spiro-Compounds

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    The iterative maximum overlap approximation (IMOA) is applied to a series of [n]-rotanes and some related spiro-compounds of unusual topology. The properties of these molecules were discussed in terms of the local hybrid orbitals and extent of their overlapping. Necessity of a clear distinction between bond length and interatomic distance in strained systems is pointed out. Considerableshortening of the C-C interatomic distance of the central carbocycles in [n]-rotanes was established. It was rationalized by the bent bond concept. The delocalization of the pseudo-pi electrons around the central ring in [n]-rotanes is briefly discussed. Angular strain energy and its distribution over the molecular fragments was quantitatively considered in the studied compounds. The strain and heat of formation of spiro (3.3) heptane are favourably compared with available ab initio results

    Carbonized Jute Sorbent for Oil Cleanup

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    Over 90 million tons of textile waste is produced every year. A large share of waste comes from the goods made of cellulose fibers. Recently, special attention has been directed towards the use of textile cellulose waste for clean-up of oil spills. The major problem relies on their relatively small oil capacity and complex separation of individual cellulose fibers from the treated spills. In an attempt to overcome this drawback, a non-woven sorbent based on recycled jute fibers obtained from the carpet industry was manufactured. Improvement of porosity and hydrophobicity/oleophilicity of the sorbent was achieved by carbonization process in an inert atmosphere. FESEM analysis revealed the fiber reduction of almost 40% induced by fiber degradation while EDX analysis confirmed the increase in the carbon content by 75% after carbonization. Oil capacity in water medium, buoyancy, oil retention and reusability of non-carbonized and carbonized sorbents were evaluated by testing four different oils (crude oil, diesel oil, two motor oils). After carbonization process, the oil sorption capacity was doubled in comparison with noncarbonized sorbent independent of oil viscosity. Carbonized sorbent not only remained afloat after 24 h of staying in water, but it sorbed a negligible amount of water unlike non-carbonized sorbent. in addition to good buoyancy, oil retention on carbonized sorbents ranged from 64-80% after 30 min of draining. Larger uptake was achieved with oils of higher viscosity, but their retention was worse. Oil sorption capacity after 5 repeated sorption/desorption trials was significantly larger in the case of carbonized sorbent since it retained 80-88% of its initial oil sorption capacity depending on tested oil

    Spectral Optical Monitoring of the Narrow Line Seyfert 1 galaxy Ark 564

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    We present the results of a long-term (1999--2010) spectral optical monitoring campaign of the active galactic nucleus (AGN) Ark 564, which shows a strong Fe II line emission in the optical. This AGN is a narrow line Seyfert 1 (NLS1) galaxies, a group of AGNs with specific spectral characteristics. We analyze the light curves of the permitted Ha, Hb, optical Fe II line fluxes, and the continuum flux in order to search for a time lag between them. Additionally, in order to estimate the contribution of iron lines from different multiplets, we fit the Hb and Fe II lines with a sum of Gaussian components. We found that during the monitoring period the spectral variation (F_max/F_min) of Ark 564 was between 1.5 for Ha to 1.8 for the Fe II lines. The correlation between the Fe II and Hb flux variations is of higher significance than that of Ha and Hb (whose correlation is almost absent). The permitted-line profiles are Lorentzian-like, and did not change shape during the monitoring period. We investigated, in detail, the optical Fe II emission and found different degrees of correlation between the Fe II emission arising from different spectral multiplets and the continuum flux. The relatively weak and different degrees of correlations between permitted lines and continuum fluxes indicate a rather complex source of ionization of the broad line emission region.Comment: Accepted for publication in ApJ
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